Semiconductor layer sequence having pre- and post-barrier layers and quantum wells

Patent metadata

Field	Value
Publication number	US-10720549-B2
Application number	US-201716319454-A
Country	US
Kind code	B2
Filing date	Sep 4, 2017
Priority date	Sep 16, 2016
Publication date	Jul 21, 2020
Grant date	Jul 21, 2020

Abstract

In an embodiment a semiconductor layer sequence includes a pre-barrier layer including AlGaN, a pre-quantum well including InGaN having a first band gap, a multi-quantum well structure including a plurality of alternating main quantum wells of InGaN having a second band gap and main barrier layers of AlGaN or AlInGaN, wherein the second band gap is smaller than the first band gap and the main quantum wells are configured to generate a radiation having a wavelength of maximum intensity between 365 nm and 490 nm inclusive, a post-quantum well with a third band gap which is larger than the second band gap, a post-barrier layer including AlGaN or AlInGaN and an electron-blocking layer including AlGaN.

First claim

The invention claimed is:

1. A semiconductor layer sequence comprising the following layers in the specified sequence beginning at an n-side:
a pre-barrier layer comprising AlGaN;
a pre-quantum well comprising InGaN having a first band gap;
a multi-quantum well structure comprising a plurality of alternating main quantum wells of InGaN having a second band gap and main barrier layers of AlGaN or AlInGaN, wherein the second band gap is smaller than the first band gap and the main quantum wells are configured to generate a radiation having a wavelength of maximum intensity between 365 nm and 490 nm inclusive;
a post-quantum well with a third band gap which is larger than the second band gap;
a post-barrier layer comprising AlGaN or AlInGaN; and
an electron-blocking layer comprising AlGaN, wherein a product of an aluminum content and a thickness of the pre-barrier layer and a product of an aluminum content and a thickness of the post-barrier layer are greater by at least a factor of 1.3 than a product of an aluminum content and a thickness of the main barrier layers.

2. The semiconductor layer sequence according to claim 1 ,
wherein the wavelength of maximum intensity is between 365 nm and 395 nm inclusive,
wherein the product of the aluminum content and the thickness of the pre-barrier layer is greater by at least a factor of 1.25 and by at most a factor of 5 than the product of the aluminum content and the thickness of the main barrier layers,
wherein the pre-quantum well is not configured for generating radiation, and
wherein an indium content and/or a thickness of the pre-quantum well is/are smaller than an indium content and/or a thickness of the main quantum wells.

3. The semiconductor layer sequence according to claim 1 , wherein an aluminum content of the electron-blocking layer is at least 20% and a thickness of the electron-blocking layer is at least 8 nm and at most 15 nm.

4. The semiconductor layer sequence according to claim 1 , wherein the electron-blocking layer is of multilayer fashion and the aluminum content of the electron-blocking layer decreases monotonically in a direction away from the n-side.

5. The semiconductor layer sequence according to claim 1 ,
wherein, in a direction away from the n-side, the electron-blocking layer follows the post-barrier layer and a spacer layer of GaN or AlGaN or AlInGaN having a thickness of between 5 nm and 15 nm inclusive and an aluminum content of at most 5% and being located directly between the electron-blocking layer and the post-barrier layer,
wherein the electron-blocking layer is a barrier for electrons that is thicker and/or higher by at least a factor of 1.5 than the post-barrier layer.

6. The semiconductor layer sequence according to claim 1 , wherein the aluminum content within the pre-barrier layer, the main barrier layers and the post-barrier layer and an indium content in the pre-quantum well, the main quantum wells and the post quantum well is constant.

7. The semiconductor layer sequence according to claim 1 ,
wherein a conditioning layer is located in each case directly on both sides of the pre-quantum well and directly on both sides of the main quantum wells,
wherein the conditioning layers are each between 1 nm and 2 nm thick, and
wherein in each case a band gap jump between the main barrier layers and the adjoining pre-quantum well or the main quantum wells is divided into two smaller jumps by the conditioning layers.

8. The semiconductor layer sequence according to claim 7 , wherein the conditioning layers have an indium gradient with an indium content increasing in a direction towards the adjoining pre-quantum well or main quantum well and/or have an aluminum gradient with an aluminum content increasing in a direction away from the adjoining pre-quantum well or main quantum well.

9. The semiconductor layer sequence according to claim 1 ,
wherein the main barrier layers have a thickness of between 0.9 nm and 2.3 nm inclusive and an aluminum content between 10% and 20% inclusive, and
wherein the precisely one pre-barrier layer has a thickness of between 2.5 nm and 4 nm inclusive and an aluminum content between 20% and 40% inclusive.

10. The semiconductor layer sequence according to claim 1 ,
wherein the precisely one pre-quantum well has a thickness between 2.2 nm and 3.4 nm inclusive and an indium content between 0.5% and 6% inclusive, and
wherein the at least four and at most 30 main quantum wells each have a thickness between 2.2 nm and 3.4 nm and an indium content between 1% and 7% inclusive.

11. The semiconductor layer sequence according to claim 1 , wherein the second band gap of the main quantum wells is between 80% and 95% inclusive of the first band gap of the pre-quantum well.

12. The semiconductor layer sequence according to claim 1 , wherein all pairs of main barrier layers and main quantum wells in the multi-quantum well structure are of the same design.

13. An optoelectronic semiconductor chip comprising:
the semiconductor layer sequence of claim 1 ; and
a growth substrate for the semiconductor layer sequence,
wherein the optoelectronic semiconductor chip is configured to emit ultraviolet radiation.

14. The optoelectronic semiconductor chip according to claim 13 ,
wherein the substrate is a sapphire substrate having a structured growth surface,
wherein the semiconductor layer sequence is electrically contacted via electrical contacts, and
wherein the semiconductor layer sequence extends over the entire substrate in a constant composition.

15. A semiconductor layer sequence comprising the following layers in the specified sequence beginning at an n-side:
a pre-barrier layer comprising AlGaN;
a pre-quantum well comprising InGaN having a first band gap;
a multi-quantum well structure comprising a plurality of alternating main quantum wells of InGaN having a second band gap and main barrier layers of AlGaN or AlInGaN, wherein the second band gap is smaller than the first band gap and the main quantum wells are configured for generating a radiation having a wavelength of maximum intensity between 365 nm and 490 nm inclusive; and
an electron-blocking layer comprising AlGaN,
wherein a product of an aluminum content and a thickness of the pre-barrier layer is greater by at least a factor of 1.3 than a product of an aluminum content and a thickness of the main barrier layers.

16. The semiconductor layer sequence according to claim 15 , wherein, in a direction away from the n-side, the multi-quantum well structure is followed by a post-quantum well with a third band gap and the third band gap is larger than the second band gap of the main quantum wells.

17. The semiconductor layer sequence according to claim 15 ,
wherein, in a direction away from the n-side, the multi-quantum well structure is followed by a post-barrier layer comprising AlGaN or AlInGaN, and
wherein a product of an aluminum content and a thickness of the post-barrier layer is greater by at least a factor of 1.3 than the product of the aluminum content and the thickness of the main barrier layers.

Assignees

• Osram Oled Gmbh

Inventors

• Bergbauer Werner
• Hertkorn Joachim

Classifications

• H10H20/825

  containing nitrogen, e.g. GaN · CPC title

• H10H20/8162

  Current-blocking structures · CPC title

• H10H20/812 Primary

  within the light-emitting regions, e.g. having quantum confinement structures · CPC title

• H10H20/8215

  characterised by crystalline imperfections, e.g. dislocations; characterised by the distribution of dopants, e.g. delta-doping · CPC title

• H01S5/3408

  characterised by specially shaped wells, e.g. triangular · CPC title