Binder containing polyvinylidene fluoride capable of fixing to a metal and associated lithium-ion battery electrode

Patent metadata

Field	Value
Publication number	US-10717890-B2
Application number	US-201615778466-A
Country	US
Kind code	B2
Filing date	Nov 17, 2016
Priority date	Nov 24, 2015
Publication date	Jul 21, 2020
Grant date	Jul 21, 2020

Abstract

The present invention relates to a binder which can be used in a lithium-ion battery, comprising at least one polyvinylidene fluoride and at least one acrylic copolymer including monomers having functional groups which have an affinity for metals or are capable of fixing to the metals. According to the invention, in a characteristic manner, said polyvinylidene fluoride is such that a solution of N-methyl-2-pyrrolidone containing 5 wt % of said polyvinylidene fluoride has a viscosity, measured at 23° C. with an imposed shear rate of 30 rpm, of 125 mPa·s to 1500 mPa·s.

First claim

The invention claimed is:

1. A binder for a lithium-ion battery comprising at least one vinylidene fluoride polymer and at least one acrylic copolymer, said acrylic copolymer comprising monomers comprising functional groups exhibiting an affinity for metals or which are capable of becoming fixed to metals, characterized in that said acrylic copolymer comprises monomers including at least one type of functional group chosen from among the following groups: carboxyl, carboxylic acid anhydride, epoxy, mercapto, sulfide and phenolic and wherein a 5% by weight solution of said vinylidene fluoride polymer in N-methyl-2-pyrrolidone exhibits a viscosity, measured at 23° C. with a controlled shear rate of 30 revolutions/min, equal to or greater than 125 millipascal-seconds, and less than 1500 millipascal-seconds.

2. The binder as claimed in claim 1 , wherein said vinylidene fluoride polymer is such that said viscosity of said solution of N-methyl-2-pyrrolidone containing 5% by weight of said vinylidene fluoride polymer is about 150 millipascal-seconds or about 700 millipascal-seconds.

3. The binder as claimed in claim 1 , wherein said acrylic copolymer comprises monomers comprising at least one type of functional group chosen from the following groups: carboxyl, carboxylic anhydride, epoxy, mercapto, sulfide, phenolic and ester.

4. The binder as claimed in claim 1 , wherein said acrylic copolymer contains 10 mol % of monomers bearing functional groups exhibiting an affinity for metals or capable of becoming fixed to metals and in particular 10 mol % of methacrylic acid groups.

5. The binder as claimed in claim 1 , wherein said binder contains, by weight, a content of acrylic copolymer equal to or greater than 0.1% and equal to or less than 25%.

6. An electrode for a lithium-ion battery of the type comprising a metal collector, at least one face of which is covered with a layer of substrate containing an active substance and a binder, characterized in that wherein said binder is the binder of claim 1 .

7. The electrode as claimed in claim 6 , wherein said substrate contains, by weight, a content of said binder of equal to or greater than 1% and of equal to or less than 5% and in particular of equal to 3%.

8. The electrode as claimed in claim 6 , wherein said substrate contains, as active substance, a lithium metal oxide and optionally carbon black.

9. The electrode as claimed in claim 6 , wherein said substrate contains, as active substance, at least one ingredient chosen from coke, carbon black, graphite, activated carbon and carbon fibers.

10. The electrode as claimed in claim 1 , wherein said solution of N-methyl-2-pyrrolidone containing 5% by weight of said vinylidene fluoride polymer exhibits a viscosity, measured at 23° C. with a controlled shear rate of 30 revolutions/min, is equal to or greater than 300 millipascal-seconds.

11. The electrode as claimed in claim 1 , wherein said solution of N-methyl-2-pyrrolidone containing 5% by weight of said vinylidene fluoride polymer exhibits a viscosity, measured at 23° C. with a controlled shear rate of 30 revolutions/min, is equal to or greater than 700 millipascal-seconds, and less than 1200 millipascal-seconds.

12. The binder as claimed in claim 5 wherein said binder contains, by weight, a content of acrylic copolymer equal to or less than 20%.

13. The binder as claimed in claim 12 wherein said binder contains, by weight, a content of acrylic copolymer equal to or less than 10%.

14. The electrode as claimed in claim 7 , wherein said substrate contains, by weight, a content of said binder equal to or greater than 1% and of equal to or less than 3%.

15. The binder as claimed in claim 1 , wherein the 5% by weight solution of said vinylidene fluoride polymer in N-methyl-2-pyrrolidone exhibits a viscosity, measured at 23° C. with a controlled shear rate of 30 revolutions/min, equal to or greater than 300 millipascal-seconds, and less than 1200 millipascal-seconds.

16. The binder as claimed in claim 1 , wherein said acrylic copolymer is a copolymer of methyl methacrylate and methacrylic acid.

Assignees

• Arkema France

Inventors

• Bizet Stéphane
• Bonnet Anthony
• Chauveau Jérôme G
• Rivas Nadine

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• C08K2003/2203

  of lithium · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M4/622 Primary

  being polymers · CPC title

• C08L27/16

  Homopolymers or copolymers or vinylidene fluoride · CPC title