Composition for preparing SAN copolymer, SAN copolymer, preparation method therefore, heat-resistant ABS resin blend comprising same, and heat-resistant ABS pellets

Patent metadata

Field	Value
Publication number	US-10717859-B2
Application number	US-201715815520-A
Country	US
Kind code	B2
Filing date	Nov 16, 2017
Priority date	Dec 24, 2015
Publication date	Jul 21, 2020
Grant date	Jul 21, 2020

Abstract

The present invention relates to a composition for preparing a SAN copolymer, a SAN copolymer, a preparation method therefor, a heat-resistant ABS resin blend comprising the same, and heat-resistant ABS pellets. Specifically, the present invention provides a composition for preparing a SAN copolymer, the composition comprising a monomer mixture, and ethylene glycol dimethacrylate as a chain extender, wherein the monomer mixture comprises 60 to 75 wt % of an α-methylstyrene monomer and 25 to 40 wt % of an acrylonitrile-based monomer based on the total weight of the monomer mixture; and the ethylene glycol dimethacrylate is contained in an amount of 0.001 to 0.15 parts by weight based on 100 parts by weight of the monomer mixture.

First claim

The invention claimed is:

1. A method of preparing a SAN copolymer comprising:
preparing a composition for preparing a SAN copolymer comprising:
a monomer mixture and ethylene glycol dimethacrylate as a chain extender,
wherein the monomer mixture includes an α-methylstyrene monomer in an amount of 60 to 75 wt % and an acrylonitrile-based monomer in an amount of 25 to 40 wt % based on the total weight of the monomer mixture, the ethylene glycol dimethacrylate is included in an amount of 0.105 to 0.15 parts by weight based on 100 parts by weight of the monomer mixture (Step 1); and
polymerizing the composition for preparing a SAN copolymer prepared in step 1 at 100 to 109° C. for 6 to 8 hours (Step 2).

2. The method of claim 1 , wherein the polymerization in step 2 is performed by supplying the composition for preparing a SAN copolymer at a supply rate of 8 to 10 kg/hr.

3. The method of claim 1 , wherein the polymerization in step 2 has a polymerization conversion ratio of 56 to 73%.

4. The method of claim 1 , wherein the polymerization in step 2 is a continuous bulk polymerization.

5. The method of claim 1 , wherein the method of preparing a SAN copolymer further comprises removing an unreacted monomer through volatilization under a temperature of 200 to 250° C. and a degree of vacuum of 25 Torr or less after the polymerization in step 2.

6. A SAN copolymer formed by polymerizing a composition for preparing a SAN copolymer and having a polydispersity index (PDI) of 2.64 to 4 and a weight average molecular weight (Mw) of 90,000 to 150,000,
wherein the composition includes a monomer mixture and ethylene glycol dimethacrylate as a chain extender, and the monomer mixture includes an α-methylstyrene monomer in an amount of 60 to 75 wt % and an acrylonitrile-based monomer in an amount of 25 to 40 wt % based on the total weight of the monomer mixture, and the ethylene glycol dimethacrylate is included in an amount of 0.0010.105 to 0.15 parts by weight based on 100 parts by weight of the monomer mixture.

7. A heat-resistant ABS resin blend comprising an ABS resin and the SAN copolymer of claim 6 .

8. The heat-resistant ABS resin blend of claim 7 , wherein the ABS resin and the SAN copolymer are included at a weight ratio of 25:75 to 30:70.

9. The heat-resistant ABS resin blend of claim 7 , wherein the ABS resin is a resin prepared by graft-polymerizing a butadiene monomer with a styrene-acrylonitrile polymer and includes the styrene-acrylonitrile polymer in an amount of 30 to 50 wt % and the butadiene monomer in an amount of 50 to 70 wt % based on the total weight of the ABS resin,
wherein the styrene-acrylonitrile polymer includes a unit derived from a styrene-based compound and a unit derived from an acrylonitrile-based compound at a weight ratio of 70:30 to 80:20.

10. The heat-resistant ABS resin blend of claim 7 , wherein the heat-resistant ABS resin blend further comprises a hindered phenol antioxidant, a phosphorus antioxidant, or a mixture thereof.

11. Heat-resistant ABS pellets prepared by mixing the heat-resistant ABS resin blend of claim 7 , followed by extrusion.

12. The heat-resistant ABS pellets of claim 11 , wherein the heat-resistant ABS pellets have an environmental stress cracking resistance (ESCR) of 39 to 63 seconds.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Gyu Sun
• Han Chang Hun
• Lee Dae Woo
• Seo Jae Bum
• Park Jung Tae
• Choi Eun Jung
• Kang Byoung Il
• Sung Da Eun

Classifications

• C08L2201/02

  Flame or fire retardant/resistant · CPC title

• C08L55/02

  ABS [Acrylonitrile-Butadiene-Styrene] polymers · CPC title

• C08L25/12 Primary

  with unsaturated nitriles · CPC title

• C08K5/315

  Compounds containing carbon-to-nitrogen triple bonds · CPC title

• C08K5/01

  Hydrocarbons {(C08K5/0091 takes precedence)} · CPC title