Dispersants having biobased compounds

Patent metadata

Field	Value
Publication number	US-10717849-B2
Application number	US-201615345822-A
Country	US
Kind code	B2
Filing date	Nov 8, 2016
Priority date	May 10, 2011
Publication date	Jul 21, 2020
Grant date	Jul 21, 2020

Abstract

The present disclosure is directed to compositions having lecithin and an organic acid and related methods. The disclosed compositions may also include one or more co-surfactants such as anionic surfactants and/or non-ionic surfactants, and may be used as a dispersant.

First claim

What is claimed is:

1. A composition comprising:
a nano-dispersion comprising:
70-95% by weight of the nano-dispersion of a lecithin or a lecithin-cosurfactant blend;
an acid;
an ester of the acid; and
water;
wherein the nano-dispersion has a particle size of less than one micron;
wherein the nano-dispersion has a pH below 6;

wherein the nano-dispersion has a viscosity of less than 1500 centipoise at ambient temperature;
a defoamer; and
a pigment, a colorant, or a combination thereof dispersed in the composition.

2. The composition of claim 1 , wherein the acid is an organic acid.

3. The composition of claim 1 , wherein the acid is selected from the lactic acid, ethyl lactate, sodium lactate, and combinations of any thereof.

4. The composition of claim 1 , wherein the acid is selected from the group consisting of lactic acid, propionic acid, methyl acetic acid, acetic acid, fumaric acid, citric acid, ascorbic acid, gluconic acid, gluconic delta lactone acid, adipic acid, malic acid, tartaric acid, a hydroxyl acid, salts of any thereof, and combinations of any thereof.

5. The composition of claim 2 , wherein the lecithin is selected from the group consisting of crude filtered lecithin, de-oiled lecithin, chemically modified lecithin, enzymatically modified lecithin, standardized lecithin, and combinations of any thereof.

6. The composition of claim 1 , wherein the nano-dispersion comprises:
the acid from 10% to 50% by weight of the nano-dispersion; and
the water from 10% to 30% by weight of the nano-dispersion.

7. The composition of claim 1 , comprising less than 25 g/L of volatile organic compounds.

8. The composition of claim 1 , wherein the co-surfactant is selected from the group consisting of an anionic surfactant, a non-ionic surfactant and combinations of any thereof.

9. The composition of claim 8 , wherein the surfactant has a hydrophilic-lipophilic balance of between 10.0 and 24.0.

10. The composition of claim 8 , wherein the non-ionic surfactant is selected from the group consisting of sorbitan monostearate, polyoxyethylene ester of rosin, polyoxyethylene dodecyl mono ether, polyoxyethylene-polyoxypropylene block copolymer, polyoxyethylene monolaurate, polyoxyethylene monohexadecyl ether, polyoxyethylene monooleate, polyoxyethylene mono(cis-9-octadecenyl)ether, polyoxyethylene monostearate, polyoxyethylene monooctadecyl ether, polyoxyethylene dioleate, polyoxyethylene distearate, polyoxyethylene sorbitan monolaurate polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan trioleate, polyoxyethylene sorbitan tristearate, polyglycerol ester of oleic acid, polyoxyethylene sorbitol hexastearate, polyoxyethylene monotetradecyl ether, polyoxyethylene sorbitol hexaoleate, fatty acids, tall-oil, sorbitol hexaesters, ethoxylated castor oil, ethoxylated soybean oil, rapeseed oil ethoxylate, ethoxylated fatty acids, ethoxylated fatty alcohols, ethoxylated polyoxyethylene sorbitol tetraoleate, glycerol and polyethylene glycol mixed esters, alcohols, polyglycerol esters, monoglycerides, sucrose esters, alkyl polyglycosides, polysorbates, fatty alkanolamides, polyglycol ethers, derivatives of any thereof, and combinations of any thereof.

11. The composition of claim 8 , wherein the anionic surfactant is selected from the group consisting of sodium and potassium salts of straight-chain fatty acids, polyoxyethylenated fatty alcohol carboxylates, linear alkyl benzene sulfonates, alpha olefin sulfonates, sulfonated fatty acid methyl ester, arylalkanesulfonates, sulfosuccinate esters, alkyldiphenylether(di)sulfonates, alkylnaphthalenesulfonates, isoethionates, alkylether sulfates, sulfonated oils, fatty acid monoethanolamide sulfates, polyoxyethylene fatty acid monoethanolamide sulfates, aliphatic phosphate esters, nonylphenolphosphate esters, fluorinated anionics, and combinations of any thereof.

12. The composition of claim 1 , further comprising propylene glycol.

13. A latex paint comprising:
a nano-emulsion comprising:
an organic acid;
an ester of the organic acid;
70-95% by weight of the nano-emulsion of a lecithin or a lecithin-cosurfactant blend;
and
water;
wherein the nano-emulsion has a particle size of less than one micron;
wherein the nano-emulsion has a pH below 5;

a pigment, a colorant, or a combination thereof; and
a defoamer.

14. The latex paint of claim 13 , wherein the organic solvent is selected from the group of acidifiers consisting of a lactic acid, propionic acid, methyl acetic acid, acetic acid, fumaric acid, citric acid, ascorbic acid, gluconic acid, gluconic delta lactone acid, adipic acid, malic acid, tartaric acid, a hydroxy acid, salts of any thereof, and combinations of any thereof.

15. The latex paint of claim 13 , wherein the lecithin is selected from the group consisting of crude filtered lecithin, de-oiled lecithin, chemically modified lecithin, enzymatically modified lecithin, standardized lecithin, and combinations of any thereof.

16. A method of dispersing a compound in a solution, the method comprising:
mixing lecithin with a cosurfactant at a temperature above ambient temperature, thus forming a lecithin-cosurfactant blend;
mixing the lecithin-cosurfactant blend with an ester of acid and water, thus forming a nano-dispersion comprising 70-95% by weight of the lecithin-cosurfactant blend;
mixing the nano-dispersion with the compound in the solution;
wherein the nano-dispersion has a particle size of less than one micron;
wherein the nano-dispersion has a pH of below 6;

wherein the compound is selected from the group consisting of a magnetic particle, a pigment, a colorant, or a combination thereof.

17. The method of claim 16 , wherein the nano-dispersion further comprises an organic solvent selected from the group of acidifiers consisting of a lactic acid, propionic acid, methyl acetic acid, acetic acid, fumaric acid, citric acid, ascorbic acid, gluconic acid, gluconic delta lactone acid, adipic acid, malic acid, tartaric acid, a hydroxy acid, salts of any thereof, and combinations of any thereof.

18. The method of claim 16 , wherein the compound is the pigment, further comprising grinding the pigment.

Assignees

• Archer Daniels Midland Co

Inventors

• Baseeth Shireen S
• Tabuena-Salyers Teodora R
• Sebree Bruce R

Classifications

• C09K23/018

  Mixtures of two or more different organic oxygen-containing compounds · CPC title

• C09D7/40

  Additives · CPC title

• A61K8/361

  Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof · CPC title

• C04B24/003

  Phosphorus-containing compounds · CPC title

• C09D17/003

  containing an organic pigment (process features in the making of dye stuff preparations C09B67/00) · CPC title