Low density carbon fibers filled materials

Patent metadata

Field	Value
Publication number	US-10717832-B2
Application number	US-201615571782-A
Country	US
Kind code	B2
Filing date	May 20, 2016
Priority date	May 22, 2015
Publication date	Jul 21, 2020
Grant date	Jul 21, 2020

Abstract

The present invention refers to a fiber reinforced polymer composition comprising a polypropylene, carbon fibers and a polar modified polypropylene as coupling agent as well as to an article comprising the fiber reinforced polymer composition.

First claim

The invention claimed is:

1. A fiber reinforced polymer composition comprising:
(a) from 65 to 98.9 wt. %, based on the total weight of the fiber reinforced polymer composition, of a polypropylene (PP);
(b) from 1 to 10 wt. %, based on the total weight of the fiber reinforced polymer composition, of carbon fibers (CF); and
(c) from 0.1 to 10 wt. %, based on the total weight of the fiber reinforced polymer composition, of a polar modified polypropylene (PMP) as coupling agent,
wherein the polar modified polypropylene (PMP) comprises groups derived from polar groups in an amount of from 1 to 5 wt. %, based on the total weight of the polar modified polypropylene (PMP); and
wherein the carbon fibers (CF) are in the form of a non-woven fabric.

2. The fiber reinforced polymer composition according to claim 1 , wherein the polypropylene (PP) has:
(a) a melt flow rate MFR 2 (230° C., 2.16 kg) measured according to ISO 1133 of not more than 100 g/10 min; and/or
(b) a melting temperature T m of at least 130° C.

3. The fiber reinforced polymer composition according to claim 1 , wherein the polypropylene (PP) is a propylene homopolymer (H-PP1) and/or a propylene copolymer (C-PP1).

4. The fiber reinforced polymer composition according to claim 3 , wherein the propylene copolymer (C-PP1) is a heterophasic propylene copolymer (HECO).

5. The fiber reinforced polymer composition according to claim 1 , wherein the non-woven fabric comprises at least 50 wt. % carbon fibers (CF), based on the total weight of the non-woven fabric.

6. The fiber reinforced polymer composition according to claim 1 , wherein the carbon fibers (CF) comprise a sizing agent.

7. The fiber reinforced polymer composition according to claim 1 , wherein the fiber reinforced polymer composition is free of fibers (F) being selected from the group comprising glass fibers, metal fibers, mineral fibers, ceramic fibers and mixtures thereof.

8. The fiber reinforced polymer composition according to claim 1 , wherein the polar modified polypropylene (PMP) comprises groups derived from polar groups selected from the group consisting of acid anhydrides, carboxylic acids, carboxylic acid derivatives, primary and secondary amines, hydroxyl compounds, oxazoline and epoxides, and also ionic compounds.

9. The fiber reinforced polymer composition according to claim 1 , wherein the polar modified polypropylene (PMP) is a propylene polymer grafted with maleic anhydride.

10. The fiber reinforced polymer composition according to claim 9 , wherein the polar modified polypropylene (PMP) is a propylene copolymer grafted with maleic anhydride comprising ethylene as comonomer units.

11. The fiber reinforced polymer composition according to claim 1 , wherein the fiber reinforced polymer composition further comprises at least one additive in an amount of up to 20 wt. %, based on the total weight of the fiber reinforced polymer composition.

12. The fiber reinforced polymer composition according to claim 1 , wherein the fiber reinforced polymer composition has:
(a) a density of equal or less than 0.985 g/cm 3 ; and/or
(b) a tensile modulus according to ISO 527-2 of at least 2500 MPa; and/or
(c) a tensile strength according to ISO 527-2 of at least 20 MPa.

13. An article comprising a fiber reinforced polymer composition according to claim 1 .

14. The article according to claim 13 , wherein the article is a molded article.

15. The article according to claim 13 , wherein the article is a part of washing machines or dishwashers or automotive articles.

Assignees

• Borealis Ag

Inventors

• Boragno Luca
• Stockreiter Wolfgang
• Jerabek Michael

Classifications

• C08L23/12 Primary

  Polypropene · CPC title

• C08L51/06

  grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond · CPC title

• C08K7/06

  Elements · CPC title

• C08L23/10 Primary

  Homopolymers or copolymers of propene · CPC title

• C08L2205/08

  containing additives to improve the compatibility between two polymers · CPC title