Aqueous dispersion of at least two polymeric resins and aqueous coating composition comprising same for applying a topcoat

Patent metadata

Field	Value
Publication number	US-10717110-B2
Application number	US-201515310640-A
Country	US
Kind code	B2
Filing date	May 13, 2015
Priority date	May 14, 2014
Publication date	Jul 21, 2020
Grant date	Jul 21, 2020

Abstract

The present invention relates to an aqueous dispersion (P) of at least two polymeric resins (P1) and (P2) which are different from one another, (P1) being a copolymer obtainable by copolymerizing ethylenically unsaturated monomers in the presence of at least one polyurethane resin having polymerizable carbon double bonds, and (P2) being a polyester having functional hydroxyl groups, which has an acid number of <25 mg of KOH per g of polyester, and (P) being obtainable by a process encompassing at least four steps (1), (2), (3), and (4), to an aqueous coating composition comprising the aqueous dispersion (P), to a process for at least partly coating at least one substrate metal surface, coated with at least one primer coat, with a topcoat, using the aqueous coating composition, and to an at least partly coated substrate obtainable by such a process.

First claim

The invention claimed is:

1. An aqueous dispersion (P), comprising:
a polymeric resin (P1), and
a polymeric resin (P2) which is different from the polymeric resin (P1), wherein
the polymeric resin (P1) is a copolymer obtained by a copolymerization of ethylenically unsaturated monomers in the presence of at least one polyurethane resin comprising polymerizable carbon double bonds,
and
the polymeric resin (P2) is a polyester comprising functional hydroxyl groups and which has an acid number of <20 mg of KOH per g of the polymeric resin (P2), the polymeric resin (P2) being obtained from: at least one polycarboxylic acid and/or an anhydride thereof; and at least one alcohol which consists of at least one polyol, and
wherein the aqueous dispersion (P) is obtained by a process comprising:
(1) preparing a dispersion or a solution comprising the polymeric resin (P1) in at least one organic solvent,
(2) preparing a mixture of the dispersion or the solution comprising the polymeric resin (P1) and a melt or a solution comprising the polymeric resin (P2),
(3) adding water to the mixture, and
(4) removing the organic solvent from the mixture, to obtain the aqueous dispersion (P).

2. The aqueous dispersion (P) according to claim 1 , wherein the relative weight ratio of the polymeric resin (P1) to the polymeric resin (P2), based on the solids content thereof, in the dispersion (P) is in a range from 2:1 to 1:2.

3. The aqueous dispersion (P) according to claim 1 , wherein the polymeric resin (P2) has an acid number of <18 mg of KOH per g of the polymeric resin (P2).

4. The aqueous dispersion (P) according to claim 1 , wherein the polymeric resin (P2) has a hydroxyl number of <50 mg of KOH per g of the polymeric resin (P2).

5. The aqueous dispersion (P) according to claim 1 which has a solids content in the range from 35 to 75 wt %, based on the total weight of the aqueous dispersion (P).

6. The aqueous dispersion (P) according to claim 1 , wherein the polymeric resin (P1) has a weight-average molecular weight (M w ) in a range from 15000 to 60000 g/mol and the polymeric resin (P2) has a weight-average molecular weight (M w ) in a range from 5000 to 40000 g/mol.

7. An aqueous coating composition, comprising:
(A1) the aqueous dispersion (P) according to claim 1 ,
(A2) at least one crosslinking agent,
(A3) at least one pigment, and
(A4) optionally at least one additive.

8. The aqueous coating composition according to claim 7 , which has a combined solids content of the polymeric resin (P1) and the polymeric resin (P2) in a range from 20 to 35 wt %, based on the total weight of the aqueous coating composition.

9. The aqueous coating composition according to claim 7 , wherein the crosslinking agent (A2) is a melamine-formaldehyde condensation product.

10. The aqueous coating composition according to claim 7 , which comprises the at least one pigment (A3) in an amount in a range from 25 to 45 wt %, based on the total weight of the aqueous coating composition.

11. A topcoat comprising the aqueous coating composition according to claim 7 in a cured form.

12. A process, comprising partially or fully coating a substrate metal surface, coated with at least one primer coat, with the aqueous coating composition according to claim 7 as a topcoat.

13. A topcoat obtained by the process according to claim 12 .

14. A partially or fully coated substrate metal surface obtained by the process according to claim 12 .

15. The aqueous coating composition according to claim 7 , wherein the at least one additive (A4) is present.

16. The aqueous coating composition according to claim 7 , wherein the crosslinking agent (A2) is an alkylated melamine-formaldehyde condensation product.

17. A process for partially or fully coating a substrate metal surface, the process comprising:
(a) optionally cleaning the substrate metal surface to remove soiling,
(b) optionally applying at least single-sidedly a pretreatment coat to the substrate metal surface,
(c) applying at least single-sidedly a primer coat to the substrate metal surface or to the optionally applied pretreatment coat, and optionally curing the primer coat,
(d) partially or fully coating the substrate metal surface, coated with the primer coat, with the aqueous coating composition according to claim 7 as a topcoat
(e) curing the applied topcoat.

18. The process according to claim 17 , wherein at least one selected from the group consisting of
cleaning the substrate metal surface,
applying at least single-sidedly a pretreatment coat,
applying at least single-sidedly a primer coat to the applied pretreatment coat, and curing the primer coat
is performed.

19. A topcoat obtained by the process according to claim 17 .

20. A partially or fully coated substrate metal surface obtained by the process according to claim 17 .

Assignees

• Basf Coatings Gmbh

Inventors

• Joege Frank
• Vollmann Dominik
• Ressel Joerg
• Schwarzenberg Lara

Classifications

• C09D167/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C09D167/06 takes precedence) · CPC title

• C09D151/08 Primary

  grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C08G18/68 Primary

  Unsaturated polyesters · CPC title

• C08G18/10

  Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step · CPC title

• C08F283/008

  on to unsaturated polymers · CPC title