Hierarchical oxygen containing carbon anode for lithium ion batteries with high capacity and fast charging capability

Patent metadata

Field	Value
Publication number	US-10714752-B2
Application number	US-201616069813-A
Country	US
Kind code	B2
Filing date	Jan 13, 2016
Priority date	Jan 13, 2016
Publication date	Jul 14, 2020
Grant date	Jul 14, 2020

Abstract

An anode material for a lithium ion battery, comprising an oxygen-containing carbon where oxygen is in the form of functional groups, the oxygen being distributed gradient from the surface to the inside of the carbon, and the carbon having an interlayer space d 002 larger than 0.3357 nm; and a porous graphene layer covering the oxygen-containing carbon, the graphene being in the form of monolayer or few-layer graphene.

First claim

The invention claimed is:

1. An anode material for a lithium ion battery, comprising a carbon particle,
wherein the carbon particle contains oxygen in the form of functional groups and a content of oxygen is hierarchically distributed in a surface region from the outermost surface of the carbon particle to 15 nm depth with 8.5 wt % to 13.0 wt % and in a remaining inner region with 6.0 wt % to 12.0 wt %, the oxygen content in the surface region is larger than the oxygen content in the inner region; and
wherein the carbon particle includes graphite phase with an interlayer space d 002 larger than 0.3357 nm.

2. The anode material according to claim 1 , where the functional groups include O—C═O group and a content of the O—C═O group in the surface region is in a range from 0.3 wt % to 3 wt % and the content of the O—C═O group in the remaining inside region is lower than the content in the surface region.

3. The anode material according to claim 1 , further comprising porous graphene covering on the surface of the carbon particle, the porous graphene being in a form of monolayer or few-layer graphenes.

4. The anode material according to claim 3 , wherein the porous graphene is formed as a layer with a thickness from 1 nm to 50 nm the porous graphene has 5 to 500 pores per μm 2 , and the size of the pore is in a range from 5 nm to 500 nm.

5. The anode material according to claim 3 , wherein the carbon particle covered with the porous graphene has a particle size of 10 μm to 25 μm.

6. The anode material according to claim 1 , wherein the anode material does not generate LiCx (6≤x≤12) when lithium ions are full intercalated.

7. The anode material according to claim 1 , further comprising a thin layer of carbon on the outermost surface of the anode material.

8. The anode material according to claim 1 , wherein the content of the functional groups attached on in-plane of an aromatic skeleton constituting graphene in the graphite phase is less than 1 mol % per the aromatic skeleton.

9. A lithium ion battery comprising positive and negative electrodes, where the negative electrode comprises the anode material according to claim 1 .

10. A process for fabricating an anode material for a lithium ion battery, which the process comprises:
(a) preparing a starting carbon particle;
(b) wet oxidizing the starting carbon particle by acid treatment and alkaline compound treatment;
(c) heat treating the carbon particle oxidized in (b) at 500-1000° C. for 1-24 hours under an inert atmosphere;
(d) injecting air with flow rate of 1 to 10 L/min into the atmosphere in (c) so as to cool down to room temperature; and
(e) mixing the carbon particle cooled in (d) with porous graphenes to obtain a porous graphene covered carbon material.

11. A lithium ion battery comprising positive and negative electrodes, where the negative electrode comprises the anode material according to claim 2 .

12. A lithium ion battery comprising positive and negative electrodes, where the negative electrode comprises the anode material according to claim 3 .

13. A lithium ion battery comprising positive and negative electrodes, where the negative electrode comprises the anode material according to claim 4 .

14. A lithium ion battery comprising positive and negative electrodes, where the negative electrode comprises the anode material according to claim 5 .

15. A lithium ion battery comprising positive and negative electrodes, where the negative electrode comprises the anode material according to claim 6 .

16. A lithium ion battery comprising positive and negative electrodes, where the negative electrode comprises the anode material according to claim 7 .

17. A lithium ion battery comprising positive and negative electrodes, where the negative electrode comprises the anode material according to claim 8 .

Assignees

• Nec Corp
• Univ Hyogo

Inventors

• Cheng Qian
• Tamura Noriyuki
• Matsuo Yoshiaki

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M4/0471

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title

• H01M4/133

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/587 Primary

  for inserting or intercalating light metals · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title