Composition for non-aqueous secondary battery functional layer, functional layer for non-aqueous secondary battery, and non-aqueous secondary battery
US-2019319236-A1 · Oct 17, 2019 · US
US10714722B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10714722-B2 |
| Application number | US-201716307252-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 10, 2017 |
| Priority date | Jun 21, 2016 |
| Publication date | Jul 14, 2020 |
| Grant date | Jul 14, 2020 |
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A composition for a non-aqueous secondary battery functional layer contains organic particles having a specific chemical composition and properties, and a binder. The organic particles contained in the composition for a functional layer include an aromatic monovinyl monomer unit in a proportion of at least 20 mass % and not more than 70 mass % and a (meth)acrylic acid alkyl ester monomer unit in a proportion of at least 30 mass % and not more than 70 mass %. The organic particles have a degree of swelling in electrolyte solution of more than a factor of 1.0 and not more than a factor of 4.0, a volume-average particle diameter of at least 0.4 μm and not more than 1.0 μm, and a tetrahydrofuran-insoluble content of at least 20 mass % and not more than 70 mass %.
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The invention claimed is: 1. A composition for a non-aqueous secondary battery functional layer comprising organic particles and a binder, wherein the organic particles include an aromatic monovinyl monomer unit in a proportion of at least 20 mass % and not more than 70 mass %, a (meth)acrylic acid alkyl ester monomer unit in a proportion of at least 30 mass % and not more than 70 mass %, and a crosslinkable monomer unit in a proportion of at least 0.2 mass % and not more than 0.8 mass %, the organic particles have a degree of swelling in electrolyte solution of more than a factor of 1.0 and not more than a factor of 4.0, the organic particles have a volume average particle diameter of at least 0.4 μm and not more than 1.0 μm, the organic particles have a tetrahydrofuran-insoluble content of at least 20 mass % and not more than 70 mass %, and the binder is an acrylic polymer having a volume average particle diameter of at least 0.1 μm and not more than 0.35 μm. 2. The composition for a non-aqueous secondary battery functional layer according to claim 1 , wherein the organic particles are a random copolymer. 3. The composition for a non-aqueous secondary battery functional layer according to claim 1 , further comprising inorganic particles. 4. A functional layer for a non-aqueous secondary battery formed using the composition for a non-aqueous secondary battery functional layer according to claim 1 . 5. A non-aqueous secondary battery comprising the functional layer for a non-aqueous secondary battery according to claim 4 .
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