Method for starting up a method for producing kerosene and diesel fuel from hydrocarbon compounds produced by Fischer-Tropsch synthesis

Patent metadata

Field	Value
Publication number	US-10711206-B2
Application number	US-201816169341-A
Country	US
Kind code	B2
Filing date	Oct 24, 2018
Priority date	Oct 24, 2017
Publication date	Jul 14, 2020
Grant date	Jul 14, 2020

Abstract

Method for starting up a method for producing kerosene and diesel fuel from hydrocarbon compounds produced by Fischer-Tropsch synthesis.
The start-up method employs catalytic reaction of Fischer-Tropsch synthesis with a synthesis gas for producing a heavy hydrocarbon fraction and a light hydrocarbon fraction, a reduction (RE) reducing a hydrotreatment catalyst by ensuring contact with a gas comprising hydrogen, bringing the heavy hydrocarbon fraction into contact with the hydrotreatment catalyst (DM). During the step for ensuring contact, the temperature (TEMP) of the catalyst is increased to a temperature of between 260° C. and 360° C. Then, (TR) bringing a mixture comprising the heavy hydrocarbon fraction and the light hydrocarbon fraction into contact with the hydrotreatment catalyst is carried out.

First claim

The invention claimed is:

1. A method for starting up a method for producing kerosene and diesel fuel from hydrocarbon compounds produced by Fischer-Tropsch synthesis, comprising:
a) catalytic Fischer-Tropsch synthesis with a synthesis gas to produce a heavy hydrocarbon fraction and a light hydrocarbon fraction,
b) reduction of a hydrotreatment catalyst by ensuring contact with a gas comprising hydrogen, and then c) is carried out,
c) contacting the heavy hydrocarbon fraction with the hydrotreatment catalyst,
d) during c), the temperature of the hydrotreatment catalyst is increased to a temperature of 260° C. to 360° C., and then e) is carried out,
e) contacting a mixture comprising the heavy hydrocarbon fraction and the light hydrocarbon fraction with the hydrotreatment catalyst.

2. The method according to claim 1 , in which
in b), reduction of the hydrotreatment catalyst and a hydrocracking and hydroisomerization catalyst is carried out by contacting with a gas comprising hydrogen, and then c) is carried out,
in c), the heavy hydrocarbon fraction is brought into contact with the hydrotreatment catalyst and then with the hydrocracking and hydroisomerization catalyst,
in e), the mixture comprising the heavy hydrocarbon fraction and the light hydrocarbon fraction is brought into contact with the hydrotreatment catalyst and then with the hydrocracking and hydroisomerization catalyst.

3. The method according to claim 1 , in which b) is carried out at a temperature of 300° C. to 500° C., and then the hydrotreatment catalyst is cooled to a temperature of 120° C. to 170° C., and then c) is carried out.

4. The method according to claim 1 , in which at the beginning of d), the heavy hydrocarbon fraction is at a temperature of 100° C. to 250° C. and in which in d), the heavy hydrocarbon fraction is heated gradually for a period of 1 to 20 hours to a temperature of 260° C. to 360° C.

5. The method according to claim 1 , in which in e), the light fraction is mixed gradually with the heavy fraction, with the portion of light fraction introduced into the mixture being increased from 0% to 100% by volume of the light fraction obtained from a), over a period of 1 to 20 hours.

6. The method according to claim 1 , in which during c), the light hydrocarbon fraction is evacuated from the start-up method.

7. The method according to claim 1 , in which the hydrotreatment catalyst comprises at least one metal of group VIIIB or group VIB, and at least one substrate.

8. The method according to claim 7 , in which the hydrotreatment catalyst comprises molybdenum and nickel, and a substrate comprising alumina.

9. The method according to claim 2 , in which the hydrocracking and hydroisomerization catalyst comprises at least one metal of group VIIIB or group VIB, and at least one substrate.

10. The method according to claim 9 , in which the hydrocracking and hydroisomerization catalyst comprises platinum and a substrate a silica-alumina or a zeolite.

11. The method according to claim 1 , in which a) is carried out, in the presence of a catalyst comprising a substrate and cobalt or iron, at a total pressure of 0.1 to 15 MPa, at a temperature of 150 to 350° C., and at an hourly volumetric flow rate of 100 to 20,000 volumes of synthesis gas per volume of catalyst and per hour.

12. The method according to claim 1 , further comprising:
f) after e), continuing to contact the mixture comprising the heavy hydrocarbon fraction and the light hydrocarbon fraction with the hydrotreatment catalyst under the operating conditions for producing kerosene and diesel fuel.

13. The method according to claim 12 , in which the contact with the hydrotreatment catalyst is carried out in f) under the following operating conditions:
a temperature of 100 to 450° C.,
a total pressure of 0.5 and to 15 MPa,
a hydrogen flow rate such that the volumetric ratio of hydrogen in relation to the hydrocarbon feedstock is 100 to 3,000 Nl/l/h,
an hourly volumetric flow rate of 0.1 to 10 h −1 .

14. The method according to claim 12 , in which in f), the mixture
comprising the heavy hydrocarbon fraction and the light hydrocarbon fraction continues to be brought into contact with the hydrotreatment catalyst and then with a hydrocracking and hydroisomerization catalyst, with the contact with the hydrocracking and hydroisomerization catalyst being carried out under the following operating conditions:
a temperature of 200 to 450° C.,
a total pressure of 0.2 to 15 MPa,
a hydrogen flow rate such that the volumetric ratio of hydrogen in relation to the hydrocarbon feedstock is 100 to 2,000 Nl/l/h,
an hourly volumetric flow rate is 0.1 and to 10 h −1 .

Assignees

• Ifp Energies Now

Inventors

• Dulot Hugues
• Grezaud Aline
• Heraud Jean-Philippe

Classifications

• Y02P30/20

  using bio-feedstock · CPC title

• C10G2300/1022

  Fischer-Tropsch products · CPC title

• C10L1/08

  for compression ignition · CPC title

• B01J23/883

  and nickel · CPC title

• C10G2/32

  with the use of catalysts · CPC title