Composite gas barrier multilayer body, method for producing the same, and composite electrode

Patent metadata

Field	Value
Publication number	US-10707442-B2
Application number	US-201314428683-A
Country	US
Kind code	B2
Filing date	Sep 20, 2013
Priority date	Sep 28, 2012
Publication date	Jul 7, 2020
Grant date	Jul 7, 2020

Abstract

A composite gas barrier multilayer body, wherein a gas barrier multilayer body (A) having a film (a) of an alicyclic polyolefin resin and an inorganic layer (a) formed on at least one surface of the film (a) and a gas barrier multilayer body (B) having a film (b) of an alicyclic polyolefin resin and an inorganic layer (b) formed on at least one surface of the film (b) are bonded via a layer of a styrene-based thermoplastic elastomer resin so that the inorganic layer (a) and the inorganic layer (b) face to each other.

First claim

The invention claimed is:

1. A composite gas barrier multilayer body, comprising:
a gas barrier multilayer body (A) having a film (a) of an alicyclic polyolefin resin and an inorganic layer (a) formed on at least one surface of the film (a) and
a gas barrier multilayer body (B) having a film (b) of an alicyclic polyolefin resin and an inorganic layer (b) formed on at least one surface of the film (b),
wherein the gas barrier multilayer body (A) and the gas barrier multilayer body (B) are bonded via a layer of a styrene-based thermoplastic elastomer resin so that the inorganic layer (a) and the inorganic layer (b) face to each other,
the styrene-based thermoplastic elastomer resin comprises a hydride of an aromatic vinyl compound-conjugated diene block copolymer that is modified by alkoxysilane
the hydride of the aromatic vinyl compound-conjugated diene block copolymer is obtained by hydrogenation of a carbon-carbon unsaturated bond in a main chain and a side chain and a carbon-carbon unsaturated bond in an aromatic ring of the aromatic vinyl compound-conjugated diene block copolymer, and
each of the gas barrier multilayer body (A) and the gas barrier multilayer body (B) has a moisture vapor transmission rate of 2×10 −2 g/m 2 ·day or less.

2. The composite gas barrier multilayer body according to claim 1 , wherein
the layer of the styrene-based thermoplastic elastomer resin has a thickness of 10 μm to 150 μm, and
the aromatic vinyl compound of the hydride of the aromatic vinyl compound-conjugated diene block copolymer that is modified by alkoxysilane is styrene.

3. The composite gas barrier multilayer body according to claim 1 , wherein
the inorganic layer (a) and the inorganic layer (b) are each a layer that is formed by a chemical vapor deposition method and contains at least Si, and
the inorganic layer (a) and the inorganic layer (b) each have a thickness of 300 nm to 2,000 nm.

4. The composite gas barrier multilayer body according to claim 1 , wherein
the inorganic layer (a) and the inorganic layer (b) are formed of the same material and have the same thickness, and
the film (a) and the film (b) are formed of the same material and have the same thickness.

5. A composite electrode for an organic EL element, comprising the composite gas barrier multilayer body according to claim 1 , and a transparent electrode formed on one outside surface of the composite gas barrier multilayer body by a physical vapor deposition method.

6. A method for producing a composite gas barrier multilayer body, comprising the steps of:
forming an inorganic layer (a) on at least one surface of a film (a) of an alicyclic polyolefin resin to obtain a gas barrier multilayer body (A);
forming an inorganic layer (b) on at least one surface of a film (b) of an alicyclic polyolefin resin to obtain a gas barrier multilayer body (B); and
stacking the gas barrier multilayer body (A), the gas barrier multilayer body (B), and a film (c) of a styrene-based thermoplastic elastomer resin so that the film (a), the inorganic layer (a), the film (c), the inorganic layer (b), and the film (b) are layered in this order, and then thermally compression-bonding the stack, wherein
the styrene-based thermoplastic elastomer resin comprises a hydride of an aromatic vinyl compound-conjugated diene block copolymer that is modified by alkoxysilane,
the hydride of the aromatic vinyl compound-conjugated diene block copolymer is obtained by hydrogenation of a carbon-carbon unsaturated bond in a main chain and a side chain and a carbon-carbon unsaturated bond in an aromatic ring of the aromatic vinyl compound-conjugated diene block copolymer, and
each of the gas barrier multilayer body (A) and the gas barrier multilayer body (B) has a moisture vapor transmission rate of 2×10 −2 g/m 2 ·day or less.

7. The composite gas barrier multilayer body according to claim 1 , wherein
the moisture vapor transmission rate is 1×10 −2 g/m 2 ·day or less.

8. The method according to claim 6 , wherein
the moisture vapor transmission rate is 1×10 −2 g/m 2 ·day or less.

9. The composite gas barrier multilayer body according to claim 1 , wherein
a material for forming either or both of inorganic layer (a) and inorganic layer (b) is a metal; an oxide, a nitride, or a nitride oxide of silicon; an oxide, a nitride, or a nitride oxide of aluminum; a diamond-like carbon; or a mixed material of two or more thereof.

10. The method according to claim 6 , wherein
a material for forming either or both of inorganic layer (a) and inorganic layer (b) is a metal; an oxide, a nitride, or a nitride oxide of silicon; an oxide, a nitride, or a nitride oxide of aluminum; a diamond-like carbon; or a mixed material of two or more thereof.

Assignees

• Zeon Corp

Inventors

• Inoue Hiroyasu
• Ishiguro Atsushi
• Koide Yohei

Classifications

• H10K50/8445

  multilayered coatings having a repetitive structure, e.g. having multiple organic-inorganic bilayers · CPC title

• B32B27/08 Primary

  of synthetic resin · CPC title

• B32B2457/206

  Organic displays, e.g. OLED · CPC title

• B32B37/0015

  to avoid warp or curl · CPC title

• B32B27/325

  comprising polycycloolefins · CPC title