Halogen-free flame retardant thermoplastic compositions for wire and cable applications
US-9321912-B2 · Apr 26, 2016 · US
US10706990B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10706990-B2 |
| Application number | US-201615781842-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 30, 2016 |
| Priority date | Dec 11, 2015 |
| Publication date | Jul 7, 2020 |
| Grant date | Jul 7, 2020 |
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The present invention relates to a fire-resistant cable comprising at least one electrically insulating composite layer based on at least one cementitious material and at least one starch, and the process for manufacturing same.
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The invention claimed is: 1. Power and/or telecommunications cable comprising: at least one elongated conductive element; and at least one electrically insulating composite layer surrounding said elongated conductive element, wherein the electrically insulating composite layer comprises at least one starch, at least one plasticizer for starch and at least one cementitious material, and wherein the cementitious material represents from 10 to 50% by weight relative to the total weight of said electrically insulating composite layer. 2. Cable according to claim 1 , wherein the cementitious material comprises silicon (Si), aluminium (Al) or magnesium (Mg), oxygen (O), and at least one element selected from potassium (K), sodium (Na), lithium (Li), caesium (Cs) and calcium (Ca). 3. Cable according to claim 1 , wherein the cementitious material is a geopolymer cement or is derived from a mixture consisting of a conventional anhydrous cement and water or a mixture consisting of a magnesium silicate, an alkali metal silicate, an alkaline base and water. 4. Cable according claim 1 , wherein the electrically insulating composite layer has a thickness ranging from 0.5 to 5 mm. 5. Cable according to claim 1 , wherein the starch is a native starch or a modified starch. 6. Cable according to claim 1 , wherein the plasticizer for starch is a metal stearate, a polyethylene glycol, an ethylene glycol, a polyol, a sucrose, a plasticizer containing amide groups, any type of plasticizer based on modified polysaccharide(s) or a mixture thereof. 7. Cable according to claim 1 , wherein the starch and the plasticizer for starch represent from 50 to 90% by weight relative to the total weight of said electrically insulating composite layer. 8. Cable according to claim 1 , wherein the electrically insulating composite layer is an inner layer of the cable. 9. Cable according to claim 1 , wherein said cable also comprises an outer protective sheath surrounding the composite layer(s). 10. Process for manufacturing the cable as defined in claim 1 , wherein said process comprises at least the following steps: i) a step of preparing a composite composition comprising the cementitious material, the starch and the plasticizer for starch, ii) a step of applying the composite composition obtained in step i) around the elongated conductive element, iii) a step of hardening the composite composition in order to form the electrically insulating composite layer. 11. Process according to claim 10 , wherein the cementitious material of step i) comprises water, silicon (Si), aluminium (Al) or magnesium (Mg), oxygen (O), and at least one element selected from potassium (K), sodium (Na), lithium (Li), caesium (Cs) and calcium (Ca). 12. Process according to claim 10 , wherein the cementitious material is a geopolymer composition, a mixture consisting of a conventional anhydrous cement and water or a mixture consisting of a magnesium silicate, an alkali metal silicate, an alkaline base and water. 13. Process according to claim 10 , wherein step i) is carried out by separately preparing the starch according to a step i-1) and the cementitious material according to a step i-2) then by mixing the starch and cementitious material according to a step i-3) in order to form the composite composition. 14. Process according to claim 10 , wherein step ii) is carried out by hot extrusion of said composite composition. 15. Power and/or telecommunications cable comprising at least one elongated conductive element; and at least one electrically insulating composite layer surrounding said elongated conductive element, and wherein the electrically insulating composite layer comprises at least one starch, at least one plasticizer for starch and at least one cementitious material, and wherein the starch and the plasticizer for starch represent from 50 to 90% by weight relative to the total weight of said electrically insulating composite layer. 16. Power and/or telecommunications cable comprising at least one elongated conductive element; and at least one electrically insulating composite layer surrounding said elongated conductive element, wherein the electrically insulating composite layer comprises at least one starch, at least one plasticizer for starch and at least one cementitious material, and wherein the cementitious material comprises silicon (Si), aluminium (Al) or magnesium (Mg), oxygen (O), and at least one element selected from potassium (K), sodium (Na), lithium (Li), caesium (Cs) and calcium (Ca).
Production of cement, e.g. improving or optimising the production methods; Cement grinding · CPC title
Other inhomogeneous material · CPC title
Silicates of the alkali metals · CPC title
Portland cements · CPC title
for electronic applications · CPC title
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