Gas sensor

Patent metadata

Field	Value
Publication number	US-10705052-B2
Application number	US-201715666427-A
Country	US
Kind code	B2
Filing date	Aug 1, 2017
Priority date	Aug 9, 2016
Publication date	Jul 7, 2020
Grant date	Jul 7, 2020

Abstract

A gas sensor offering high gas identification property includes: a first gas detection element having a first oscillator, as well as a first gas-adsorption film which is provided on the first oscillator and constituted by two or more fluorine resins including vinylidene fluoride resin; a second gas detection element having a second oscillator, as well as a second gas-adsorption film which is provided on the second oscillator and constituted by two or more fluorine resins including vinylidene fluoride resin and which has adsorption characteristics different from those of the first adsorption film; and a detection circuitry that detects the resonance frequencies of the first and second gas detection elements.

First claim

I claim:

1. A gas sensor, comprising:
a first gas-detection element having a first oscillator, as well as a first gas-adsorption film which is provided on the first oscillator and made of a copolymer constituted by two or more fluorine resins including vinylidene fluoride resin and trifluoroethylene, wherein a resonance frequency of the first oscillator is changed when the first gas-adsorption film adsorbs gas;
a second gas-detection element having a second oscillator, as well as a second gas-adsorption film which is provided on the second oscillator and made of a copolymer constituted by two or more fluorine resins including vinylidene fluoride resin and trifluoroethylene, wherein a blending ratio of the two or more fluorine resins used for the second gas-detection film is different from that used for the first gas-detection film in a manner that the second gas-adsorption film has gas-adsorption characteristics different from those of the first gas-adsorption film wherein a resonance frequency of the second oscillator is changed when the second gas-adsorption film adsorbs gas; and
a detection circuitry that detects resonance frequencies of the first and second gas-detection elements.

2. A gas sensor according to claim 1 , further comprising:
a third gas-detection element having a third oscillator, as well as a third adsorption film which is provided on the third oscillator and which contains a cyanine pigment wherein a resonance frequency of the third oscillator is changed when the third gas-adsorption film adsorbs gas.

3. A gas sensor according to claim 1 , wherein:
the first gas-adsorption film is made of a copolymer constituted by the vinylidene fluoride resin and trifluoroethylene; and
the second gas-adsorption film is made of a copolymer constituted by the vinylidene fluoride resin, chlorotrifluoroethylene resin, and trifluoroethylene.

4. A gas sensor according to claim 2 , wherein:
the first gas-adsorption film is made of a copolymer constituted by the vinylidene fluoride resin and trifluoroethylene; and
the second gas-adsorption film is made of a copolymer constituted by the vinylidene fluoride resin, chlorotrifluoroethylene resin, and trifluoroethylene.

5. A gas sensor according to claim 3 , further comprising:
a fourth gas-detection element having a fourth oscillator, as well as a fourth gas-adsorption film which is provided on the fourth oscillator and made of a copolymer constituted by vinylidene fluoride resin, chlorotrifluoroethylene resin, and trifluoroethylene at a blending ratio different from that used for the second gas-adsorption film, and which has gas-adsorption characteristics different from those of the first gas-adsorption film and those of the second gas-adsorption film wherein a resonance frequency of the fourth oscillator is changed when the fourth gas-adsorption film adsorbs gas.

6. A gas sensor according to claim 4 , further comprising:
a fourth gas-detection element having a fourth oscillator, as well as a fourth gas-adsorption film which is provided on the fourth oscillator and made of a copolymer constituted by vinylidene fluoride resin, chlorotrifluoroethylene resin, and trifluoroethylene at a blending ratio different from that used for the second gas-adsorption film, and which has gas-adsorption characteristics different from those of the first gas-adsorption film and those of the second gas-adsorption film wherein a resonance frequency of the fourth oscillator is changed when the fourth gas-adsorption film adsorbs gas.

7. A gas sensor according to claim 1 , wherein:
the first gas-adsorption film is made of a copolymer constituted by the vinylidene fluoride resin, chlorotrifluoroethylene resin, and trifluoroethylene; and
the second gas-adsorption film is made of a copolymer constituted by the vinylidene fluoride resin, chlorotrifluoroethylene resin, and trifluoroethylene at a blending ratio different from that used for the first gas-adsorption film.

8. A gas sensor according to claim 2 , wherein:
the first gas-adsorption film is made of a copolymer constituted by the vinylidene fluoride resin, chlorotrifluoroethylene resin, and trifluoroethylene; and
the second gas-adsorption film is made of a copolymer constituted by the vinylidene fluoride resin, chlorotrifluoroethylene resin, and trifluoroethylene at a blending ratio different from that used for the first gas-adsorption film.

9. A gas sensor according to claim 1 , further comprising:
a chamber that houses the respective gas detection elements; and
a computing unit that calculates changes in resonance frequencies of the respective gas detection elements from the detected resonance frequencies, and then specifies a gas inside the chamber based on calculated results.

10. A gas sensor according to claim 1 , wherein a thickness of the first gas-adsorption film and a thickness of the second gas-adsorption film are set differently wherein the resonance frequencies of the films are changed, to values of a same order of magnitude per unit surface area of each film when the films adsorb acetone.

11. A gas sensor according to claim 1 , wherein a film formation area of the first gas-adsorption film and a film formation area of the second gas-adsorption film are substantially the same.

12. A gas sensor according to claim 1 , further comprising a reference gas detection element on which no gas-adsorption film is provided.

Assignees

• Taiyo Yuden Kk

Inventors

• Hattori Masashi

Classifications

• G01N2291/0256

  Adsorption, desorption, surface mass change, e.g. on biosensors · CPC title

• G01N27/00 Primary

  Investigating or analysing materials by the use of electric, electrochemical, or magnetic means (G01N3/00 – G01N25/00 take precedence; measurement or testing of electric or magnetic variables or of electric or magnetic properties of materials G01R) · CPC title

• G01N2291/014

  Resonance or resonant frequency · CPC title

• G01N29/036 Primary

  by measuring frequency or resonance of acoustic waves · CPC title

• G01N33/0047

  Organic compounds · CPC title