Non-oriented silicon steel and method for producing the same
US-2024279782-A1 · Aug 22, 2024 · US
US10704116B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10704116-B2 |
| Application number | US-201615579406-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 7, 2016 |
| Priority date | Jun 5, 2015 |
| Publication date | Jul 7, 2020 |
| Grant date | Jul 7, 2020 |
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A high-strength thin steel sheet having excellent drawability and bake hardenability, and a method of manufacturing the same are provided. The high-strength thin steel sheet includes 0.0005 to 0.003 wt % of carbon (C); 0.5 wt % or less (excluding 0 wt %) of silicon (Si); 1.2 wt % or less (excluding 0 wt %) of manganese (Mn); 0.005 to 0.12 wt % of phosphorous (P); 0.008 wt % or less of sulfur (S); 0.005 wt % or less of nitrogen (N); 0.1 wt % or less (excluding 0 wt %) of acid-soluable aluminum (Al); 0.01 to 0.04 wt % of titanium (Ti); iron (Fe) as a remainder thereof; and unavoidable impurities. The high-strength thin steel sheet has BH of 4 MPa or more and P of 80% or more in Equation 1: P (%)={N in /(N in +N gb )}×100, N in being the number of carbides having a size of 20 nm or less within a crystal grain, and N gb being the number of carbides having a size of 20 nm or less at a grain boundary.
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The invention claimed is: 1. A comprising: 0.0005 wt % to 0.003 wt % of carbon (C); 0.5 wt % or less excluding 0 wt % of silicon (Si); 1.2 wt % or less excluding 0 wt % of manganese (Mn); 0.005 wt % to 0.12 wt % of phosphorous (P); 0.008 wt % or less of sulfur (S); 0.005 wt % or less of nitrogen (N); 0.1 wt % or less excluding 0 wt % of acid-soluable aluminum (Al); 0.01 wt % to 0.04 wt % of titanium (Ti); iron (Fe) as a remainder thereof, and unavoidable impurities; P (%) of 80% or more, P (%) being defined by Equation 1: P (%)=({N in /(N in +N gb )}×100, where N in denotes the number of carbides present within a crystal grain having a size of 20 nm or less, and N gb denotes the number of carbides present at a grain boundary of the crystal grain; and a bake hardenability (BH) of 4 MPa or more. 2. The steel sheet of claim 1 , further comprising: 0.005 wt % to 0.04 wt % of niobium (Nb). 3. The steel sheet of claim 1 , further comprising: 0.002 wt % or less excluding 0 wt % of boron (B). 4. The steel sheet of claim 1 , further comprising: 0.2 or less of FeTiP precipitates per unit area (μm 2 ). 5. The steel sheet of claim 1 , wherein, in a region of the steel sheet from a steel sheet surface to t/4 (t: thickness of the steel sheet) in a thickness direction of the steel sheet, an average random strength ratio of {111}<011> to {111}<112> orientation groups with respect to an alpha (α)-fiber texture in which a <110> direction and a rolling direction are parallel to each other is 5 or more. 6. The steel sheet of claim 1 , further comprising: a lankford value (r value) of 2.2 or more. 7. The steel sheet of claim 1 , further comprising a hot-dip galvanized layer formed on a surface of the steel sheet. 8. The steel sheet of claim 1 , further comprising an alloyed hot-dip galvanized layer formed on a surface of the steel sheet. 9. A method of manufacturing a steel sheet, the method comprising: hot-rolling a steel slab to obtain a hot-rolled steel sheet, the steel slab including 0.0005 wt % to 0.003 wt % of carbon (C), 0.5 wt % or less excluding 0 wt % of silicon (Si), 1.2 wt % or less excluding 0 wt % of manganese (Mn), 0.005 wt % to 0.12 wt % of phosphorous (P), 0.008 wt % or less of sulfur (S), 0.005 wt % or less of nitrogen (N), 0.1 wt % or less excluding 0 wt % of acid-soluable aluminum (Al), 0.01 wt % to 0.04 wt % of titanium (Ti), iron (Fe) as a remainder thereof, and unavoidable impurities, and obtaining a hot-rolled steel sheet; winding the hot-rolled steel sheet at a temperature of 450° C. to 750° C. to obtain a coiled steel sheet; cold-rolling the coiled steel sheet under conditions of a total reduction ratio of 75% to 85% and a ratio of a final rolling reduction ratio to the total reduction ratio of 6.5% to 14.1%, to obtain a cold-rolled steel sheet; continuously annealing the cold-rolled steel sheet by heating the cold-rolled steel sheet to an annealing temperature of 830° C. to 880° C. at a rate of 7° C./sec or lower and then maintaining the annealing temperature for 30 sec. to 80 sec. to obtain an annealed steel sheet; and cooling the annealed steel sheet to 650° C. at an average cooling rate of 2° C./sec to 10° C./sec thereby producing the steel sheet of claim 1 . 10. The method of claim 9 , wherein the steel slab further comprises: 0.005 wt % to 0.04 wt % of niobium (Nb). 11. The method of claim 9 , wherein the steel slab further comprises: 0.002 wt % or less excluding 0 wt % of boron (B). 12. The method of claim 9 , wherein the hot-rolling comprises: a hot-finish rolling at Ar3 or higher. 13. The method of claim 9 , further comprising: hot-dip galvanizing annealed steel sheet. 14. The method of claim 9 , further comprising: hot-dip galvanizing the annealed steel sheet to obtain a galvanized steel sheet; and heat-treating the galvanized steel sheet at a temperature of 450° C. to 600° C.
during manufacturing of plates or strips (C21D8/12 takes precedence) · CPC title
Very low carbon steels, i.e. having a carbon content of less than 0,01% · CPC title
Zinc or cadmium or alloys based thereon · CPC title
Final recrystallisation annealing · CPC title
following hot rolling · CPC title
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