Grease and method for manufacturing grease

Patent metadata

Field	Value
Publication number	US-10704010-B2
Application number	US-201615549036-A
Country	US
Kind code	B2
Filing date	Feb 4, 2016
Priority date	Feb 5, 2015
Publication date	Jul 7, 2020
Grant date	Jul 7, 2020

Abstract

A grease of the invention contains a base oil and a thickener, where, when the volumetric-based arithmetic mean particle size of particles contained in the grease measured using laser diffraction/scattering method is A (unit: μm), a formula A≤3 (1) is satisfied.

First claim

The invention claimed is:

1. A grease, comprising:
a base oil; and
a thickener comprising a urea,
wherein:
A (unit: μm) representing a volumetric-based arithmetic mean particle size of particles of the urea comprised in the grease calculated using laser diffraction/scattering method satisfies a formula (1):
A≤ 1.6  (1).

2. The grease according to claim 1 , wherein the thickener comprises a polyurea compound.

3. The grease according to claim 1 , wherein:
the thickener is a urea;
the urea is a reaction product of a monoamine and a diisocyanate; and
the monoamine is composed of a single amine compound or is a mixture of a plurality of amine compounds.

4. The grease according to claim 1 , wherein the grease is prepared by mixing the thickener or a precursor of the thickener in the base oil to provide a mixture solution, and applying a minimum shear rate of 10 2 s −1 or more to the mixture solution.

5. The grease according to claim 1 , wherein the grease is prepared by mixing a first base oil comprising a first thickener precursor and a second base oil comprising a second thickener precursor to prepare a mixture solution, and applying a minimum shear rate of 10 2 s −1 or more to the mixture solution.

6. A manufacturing method of a grease, the method comprising:
applying a minimum shear rate of 10 2 s −1 or more to at least one of a first base oil comprising a first thickener precursor and a second base oil comprising a second thickener precursor;
mixing the first base oil and the second base oil while keeping the minimum shear rate to prepare a mixture solution; and
forming a thickener in the mixture solution.

7. The grease manufacturing method according to claim 6 , wherein:
in a single reactor, the minimum shear rate of 10 2 s −1 or more is applied to the first base oil comprising the first thickener precursor, and the minimum shear rate of 10 2 s −1 or more is applied to the second base oil comprising the second thickener precursor;
the first base oil and the second base oil are mixed while keeping the minimum shear rate for each of the first and second base oils to prepare the mixture solution; and
the thickener is formed in the mixture solution.

8. The grease manufacturing method according to claim 6 , wherein:
the minimum shear rate of 10 2 s −1 or more is applied to the first base oil comprising the first thickener precursor;
while keeping the minimum shear rate, the second base oil comprising the second thickener precursor is added to the first base oil to prepare the mixture solution; and
the thickener is formed in the mixture solution.

9. The grease manufacturing method according to claim 6 , wherein a time for keeping the minimum shear rate for the mixture solution comprising the first base oil and the second base oil at 10 2 s −1 or more is at least 0.002 seconds.

10. The grease manufacturing method according to claim 6 , wherein the minimum shear rate for the mixture solution is 10 7 s −1 or less.

11. The grease manufacturing method according to claim 6 , wherein a ratio (Max/Min) of a maximum shear rate (Max) to the minimum shear rate (Min) in a shear rate applied to the mixture solution is 50 or less.

12. The grease manufacturing method according to claim 6 , wherein:
the first thickener precursor is a monoamine and the second thickener precursor is a diisocyanate; or
the first thickener precursor is a diisocyanate and the second thickener precursor is a monoamine.

13. The grease manufacturing method according to claim 6 , wherein the minimum shear rate is applied to the mixture solution by introducing the mixture solution into a reactor configured to generate shearing by a relative motion between facing wall surfaces.

14. The grease manufacturing method according to claim 6 , further comprising:
heating the grease to a temperature of 80 degrees C. or more.

15. A grease, comprising a thickener formed by shearing a mixture solution of a monoamine compound and a diisocyanate compound at a minimum shear rate of 10 2 s −1 or more,
wherein:
the monoamine compound is at least one of an aliphatic monoamine and an aromatic monoamine; and
A (unit: μm) representing a volumetric-based arithmetic mean particle size of particles comprised in the grease calculated using laser diffraction/scattering method satisfies a formula (1):
A≤ 1.6  (1).

16. The grease according to claim 15 , wherein a ratio of a value (V S ) of measurements of a Level High32-64s of the urea grease according to a FAG method, and a value (V N ) of measurements of a Level High32-64s of the urea grease obtained by shearing the mixture solution at a minimum shear rate of less than 10 2 s −1 satisfies:
V S /V N ≤0.9.

17. The grease according to claim 15 , wherein a ratio of a value (V S ) of measurements of a Level High32-64s of the urea grease according to a FAG method, and a value (V N ) of measurements of a Level High32-64s of the urea grease obtained by a reaction, in which a ratio (Max/Min) of a maximum shear rate (Max) to the minimum shear rate (Min) applied to the mixture solution is controlled to be 70 or more, satisfies:
V S /V N ≤0.9.

18. The grease according to claim 15 , wherein the mixture solution is prepared by mixing a first base oil comprising the monoamine compound and a second base oil comprising the diisocyanate compound.

19. The grease according to claim 15 , wherein the monoamine compound comprises a chain aliphatic monoamine having 6 to 20 carbon atoms.

20. The grease according to claim 15 , wherein the monoamine compound comprises octyl amine.

21. The grease according to claim 15 , wherein the monoamine compound comprises tolyl amine.

22. The grease according to claim 15 , wherein the minimum shear rate is 10 7 s −1 or less.

Assignees

• Idemitsu Kosan Co

Inventors

• Suetsugu Yoshiyuki
• KUMAGAI Hiromu

Classifications

• B01F27/2722

  provided with ribs, ridges or grooves on one surface · CPC title

• B01J19/0066

  Stirrers (mixing per se B01F) · CPC title

• C10N2070/00

  Specific manufacturing methods for lubricant compositions · CPC title

• C10M2219/0445

  used as thickening agents · CPC title

• C10N2030/76

  Reduction of noise, shudder, or vibrations · CPC title