Synthesis of zeolite with the CHA crystal structure, synthesis process and use thereof for catalytic applications

Patent metadata

Field	Value
Publication number	US-10703640-B2
Application number	US-201916396971-A
Country	US
Kind code	B2
Filing date	Apr 29, 2019
Priority date	Dec 17, 2014
Publication date	Jul 7, 2020
Grant date	Jul 7, 2020

Abstract

Disclosed is a synthesis process of a crystalline material with the CHA structure, which comprises the following steps: i) Preparation of a mixture that comprises one source of water, one source of a tetravalent element Y, one source of an alkaline or alkaline earth cation (A), one source of a trivalent element X, and one organic molecule (OSDA1) with the structure [R1R2R3R4N+]Q−, being the molar composition: nX2O3:YO2:aA:mOSDA1:zH2O, ii) crystallisation of the mixture obtained in i) in a reactor, iii) recovery of the crystalline material obtained in ii).

First claim

The invention claimed is:

1. A crystalline material with the CHA zeolite structure made by a process comprising, at least, the following steps:
i) Preparation of a mixture that comprises at least one source of water, at least one source of a tetravalent element Y, at least one source of an alkaline or alkaline earth cation A, at least one source of a trivalent element X, and at least one organic molecule (OSDA1) with the structure [R 1 R 2 R 3 R 4 N + ]Q − ,
wherein R 1 , R 2 , R 3 and R 4 are selected from linear alkyl groups, and wherein R 1 , R 2 , R 3 and R 4 each have between 1 and 4 carbon atoms, but at least two of them must have at least two carbon atoms, and wherein Q − is an anion, being the molar composition:
n X 2 O 3 :YO 2 :a A: m OSDA1: z H 2 O

wherein
n ranges between 0.01 and 0.1;
a ranges between 0 and 0.8;
m ranges between 0.1 and 0.6;
z ranges between 2 and 20;

ii) Crystallization of the mixture obtained in i) in a reactor, and
iii) Recovery of the crystalline material obtained in ii).

2. The crystalline material according to claim 1 , wherein the source of the tetravalent element Y is selected from silicon, tin, titanium, germanium, and combinations thereof.

3. The crystalline material according to claim 2 , wherein the source of the tetravalent element Y is a source of silicon selected from silicon oxide, silicon halide, colloidal silica, fumed silica, tetraalkyl orthosilicate, silicate, silicic acid, a previously synthesised crystalline material, a previously synthesised amorphous material, and combinations thereof.

4. The crystalline material according to claim 3 , wherein the source of silicon is selected from a previously synthesised crystalline material, a previously synthesised amorphous material and combinations thereof.

5. The crystalline material according to claim 4 , wherein the previously synthesised materials contain other heteroatoms in their structure.

6. The crystalline material according to claim 1 , wherein the source of the trivalent element X is selected from aluminium, boron, iron, indium, gallium, and combinations thereof.

7. The crystalline material according to claim 6 , wherein the source of the trivalent element X is aluminium.

8. The crystalline material according to claim 1 , wherein the OSDA1 is selected from tetraethylammonium, methyl triethylammonium, propyl triethylammonium, diethyl dipropylammonium, diethyl dimethylammonium, and combinations thereof.

9. The crystalline material according to claim 8 , wherein said OSDA1 is tetraethylammonium.

10. The crystalline material according to claim 1 , wherein the crystallization process described in ii) is performed in autoclaves, under static or dynamic conditions.

11. The crystalline material according to claim 1 , wherein the crystallization process described in ii) is performed at a temperature ranging between 100° C. and 200° C.

12. The crystalline material according to claim 1 , wherein the crystallization time of the process described in ii) ranges between 6 hours and 50 days.

13. The crystalline material according to claim 1 , further comprising the addition of CHA crystals to the synthesis mixture, as seeds, in a quantity of up to 25% by weight with respect to the total quantity of oxides.

14. The crystalline material according to claim 13 , wherein the CHA crystals are added before the crystallization process or during the crystallization process.

15. The crystalline material according to claim 1 , wherein recovery step iii) is performed by means of a separation technique selected from decantation, filtration, ultrafiltration, centrifugation, and combinations thereof.

16. The crystalline material according to claim 1 , wherein it further comprises the elimination of the organic content retained inside the material by means of an extraction process.

17. The crystalline material according to claim 1 , wherein it further comprises the elimination of the organic content retained inside the material by means of a heat treatment at temperatures ranging between 100° C. and 1000° C. for a period of time ranging between 2 minutes and 25 hours.

18. The crystalline material according to claim 1 , wherein the material obtained is pelletized.

19. The crystalline material according to claim 1 , wherein any cation present in the material may be exchanged with other cations by means of ion exchange.

20. The crystalline material according to claim 19 , wherein the exchanged cation is selected from metals, protons, proton precursors, and mixtures thereof.

21. The crystalline material according to claim 20 , wherein the exchanged cation is a metal selected from rare earths, metals of groups IIA, IIIA, IVA, VA, IB, IIB, IIIB, IVB, VB, VIB, VIIB, and VIII, and combinations thereof.

22. The crystalline material according to claim 21 , wherein the metal is copper.

23. A method for converting, eliminating, or separating feeds formed by organic compounds in a high-added-value product, which comprises bringing said feed into contact with a crystalline material with the CHA structure according to claim 1 .

24. A method of producing an olefin, which comprises contacting an oxygenated organic compound with a crystalline material with the CHA structure according to claim 1 .

25. A method of selective catalytic reduction (SCR) of NOx (nitrogen oxides) in a gas stream, which comprises contacting the gas stream with a crystalline material with the CHA structure according to claim 1 .

Assignees

• Consejo Superior Investigacion
• Univ Valencia Politecnica
• Consejo Superioer De Investig Cientificas

Inventors

• Corma Canós Avelino
• Moliner Marín Manuel
• Martín García Nuria

Classifications

• C07C2529/70

  of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 · CPC title

• C01B39/026 Primary

  After-treatment · CPC title

• C01B39/48 Primary

  using at least one organic template directing agent · CPC title

• B01D53/9418

  for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas · CPC title

• B01D2258/01

  Engine exhaust gases · CPC title