Superlubricious carbon films derived from natural gas

Patent metadata

Field	Value
Publication number	US-10702862-B2
Application number	US-201815952623-A
Country	US
Kind code	B2
Filing date	Apr 13, 2018
Priority date	Apr 13, 2018
Publication date	Jul 7, 2020
Grant date	Jul 7, 2020

Abstract

A nanocomposite coating that in turn extract self-replenishing (or -healing), superlubricious carbon film directly from natural gas or hydrocarbon gas in mechanical systems. The coating deposits on sealing and sliding surfaces reducing friction and wear. The result is a reduction in inefficiency, machine breakdown, and adverse environmental impact.

First claim

The invention claimed is:

1. A method of extracting lubricious carbon films from a hydrocarbon gas in a mechanical system comprising the steps of:
coating sliding surfaces in a mechanical system with a catalytically active material wherein the catalytically active material is selected from the group consisting of VN—Ni, VN—Cu, MoN—Ni, MoN—Cu, VN—Co, MoN—Co and combinations thereof;
pressurizing the mechanical system to a predetermined pressure;
maintaining the temperature of the mechanical system in a predetermined range;
filling the mechanical system with the hydrocarbon gas, the hydrocarbon gas containing approximately 70-90 percent methane, approximately 0-20% ethane, approximately 0-8% carbon, approximately 0-0.2% oxygen, approximately 0-5% nitrogen and approximately 0-5% hydrogen sulphide; and
operating said mechanical system.

2. The method of claim 1 wherein the step of coating includes using a physical vapor deposition system to form a coating of a predetermined thickness.

3. The method of claim 2 wherein the predetermined thickness is between approximately 3 nanometer to approximately 50 micrometer.

4. The method of claim 2 wherein the physical deposition system includes cathodic arc PVD, High Power Impulse Magnetron Sputtering (HIPIMS), ion plating, diode or triode magnetron sputtering, pulse DC and hybrids of the aforementioned methods.

5. The method of claim 1 wherein the predetermined pressure is approximately 3500 psi.

6. The method of claim 1 wherein the predetermined pressure is greater than approximately 14.7 psi and less than approximately 3500 psi.

7. The method of claim 1 wherein the temperature range is between approximately 18 degrees Celsius to approximately 500 degrees Celsius.

8. A method of extracting lubricious carbon films from a hydrocarbon gas in a mechanical system comprising the steps of:
coating sliding surfaces in a mechanical system with a catalytically active material;
pressurizing the mechanical system to a pressure greater 3500 psi;
maintaining the temperature of the mechanical system in a predetermined range;
filling the mechanical system with the hydrocarbon gas, the hydrocarbon gas containing approximately 70-90 percent methane, approximately 0-20% ethane, approximately 0-8% carbon, approximately 0-0.2% oxygen, approximately 0-5% nitrogen and approximately 0-5% hydrogen sulphide; and
operating said mechanical system.

9. A method of extracting lubricious carbon films from a hydrocarbon gas in a mechanical system comprising the steps of:
coating sliding surfaces in a mechanical system with a catalytically active material;
pressurizing the mechanical system to a predetermined pressure;
maintaining the temperature of the mechanical system in a predetermined range;
filling the mechanical system with the hydrocarbon gas, the hydrocarbon gas containing approximately 70-90 percent methane, approximately 0-20% ethane, approximately 0-8% carbon, approximately 0-0.2% oxygen, approximately 0-5% nitrogen and approximately 0-5% hydrogen sulphide wherein the hydrocarbon gas further includes moisture and sulfur dioxide; and
operating said mechanical system.

Assignees

• Us Energy
• Us Dept Energy

Inventors

• Erdemir Ali
• Eryilmaz Osman
• Ramirez Gonzalez Jair Giovanni

Classifications

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/36

  Mechanical strength · CPC title

• B01J35/38

  Abrasion or attrition resistance · CPC title

• C23C14/0605

  Carbon · CPC title