Coatings for mitigation of coin cell ingestion

Patent metadata

Field	Value
Publication number	US-10700362-B2
Application number	US-201715696947-A
Country	US
Kind code	B2
Filing date	Sep 6, 2017
Priority date	Sep 15, 2016
Publication date	Jun 30, 2020
Grant date	Jun 30, 2020

Abstract

A system and method for mitigating the impact of ingested lithium coin cell batteries is described. A coating is provided on an exterior facing of the cell, preferably within the crimp region, which releases acid and/or other additives. These acids and/or additives are selected to neutralize hydroxide that may evolve from hydrolysis of saliva that occurs if/when the coin cell becomes lodged in the digestive tract.

First claim

That which is claimed:

1. A coin cell, comprising:
an outer surface comprising a positive contact surface and a negative contact surface; and
a coating consisting essentially of an adhesive and a pH reducing substance, wherein the coating is disposed on at least a portion of the outer surface of the coin cell, and
wherein the coating is formulated to release the pH reducing substance from the coating upon being subjected to a predetermined condition of pH and/or temperature.

2. The coin cell according to claim 1 , further comprising a crimp or seal area adjacent the positive contact surface and the negative contact surface, wherein the coating is disposed on at least a portion of the crimp or seal area.

3. The coin cell according to claim 1 , wherein the pH reducing substance is an acidic substance.

4. The coin cell according to claim 3 , wherein the acidic substance is citric acid.

5. The coin cell according to claim 3 , wherein the acidic substance is a food grade acid suitable for human consumption.

6. The coin cell of claim 1 , wherein the pH reducing substance is a catalytic substance that facilitates in situ generation of acid when exposed to saliva.

7. The coin cell of claim 1 , wherein the coating is dissolvable in saliva.

8. The coin cell of claim 1 , wherein the coin cell has an initial voltage potential in an undischarged state and wherein the coin cell causes generation of an alkaline solution when the coin cell has a voltage potential above a thermodynamic voltage level and the coin cell is discharged in saliva, and wherein: the coating comprises an amount of pH reducing substance to neutralize the alkaline solution generated during discharge of the coin cell from the initial voltage potential to the thermodynamic voltage in saliva.

9. A method for mitigating harmful effects of human ingestion of a coin cell, the method comprising:
applying a coating to at least a portion of the outer surface of the coin cell, the coating consisting essentially of an adhesive and a pH reducing substance;
wherein the coating is disposed on at least a portion of the outer surface of the coin cell, and
wherein the coating is formulated to release the pH reducing substance from the coating upon being subjected to a predetermined condition of pH and/or temperature.

10. The method according to claim 9 further comprising dispersing the pH reducing substance in an adhesive prior to or concurrent with applying the coating.

11. The method according to claim 9 , wherein applying the coating to at least a portion of the outer surface of the coin cell comprises: dispersing the pH reducing substance in a solvent-based solution; applying the solvent to at least a portion of the outer surface of the coin cell; curing the solvent-based solution to adhere the pH reducing substance relative to the outer surface of the coin cell.

12. The method according to claim 9 , wherein applying the coating to at least a portion of the outer surface of the coin cell comprises: applying the coating to at least a portion of a crimp or seal area located adjacent the positive contact surface and the negative contact surface.

13. The method according to claim 9 , wherein applying the coating to at least a portion of the outer surface of the coin cell comprises: applying an amount of the coating to neutralize an alkaline solution generated when the coin cell is discharged from an initial voltage potential to a thermodynamic voltage in saliva, wherein the initial voltage potential is the voltage potential of the coin cell in an undischarged state and the thermodynamic voltage is the minimum voltage level for generation of the alkaline solution when the coin cell is discharged in saliva.

14. A coating for mitigating harmful effects of human ingestion of a coin cell, the coating consisting essentially of:
an adhesive, and
a pH reducing substance, wherein the pH reducing substance is dispersed in the coating, and
wherein the coating is formulated to be a food grade coating and wherein the coating is formulated to release the pH reducing substance from the coating upon being subjected to a predetermined condition of pH and/or temperature.

15. The coating of claim 14 , wherein the pH reducing substance is an acidic substance.

16. The coating of claim 15 , wherein the acidic substance is citric acid.

17. The coating of claim 14 , wherein the coating is dissolvable in saliva.

18. The coating of claim 14 , wherein the pH reducing substance is a catalytic substance that facilitates in situ generation of acid when exposed to saliva.

Assignees

• Energizer Brands Llc

Inventors

• Boolish Marc
• Wemple Michael

Classifications

• H01M50/131

  characterised by physical properties, e.g. gas permeability, size or heat resistance · CPC title

• H01M50/124

  having a layered structure · CPC title

• H01M50/109 Primary

  of button or coin shape · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• Y02T10/70

  Energy storage systems for electromobility, e.g. batteries · CPC title