Separator for rechargeable lithium battery

Patent metadata

Field	Value
Publication number	US-10700331-B2
Application number	US-201313907822-A
Country	US
Kind code	B2
Filing date	May 31, 2013
Priority date	Aug 23, 2012
Publication date	Jun 30, 2020
Grant date	Jun 30, 2020

Abstract

A separator for a rechargeable lithium battery includes a backbone polymer, an ion conductive polymer coating the backbone polymer, and an electrolyte solution immersing the backbone polymer, wherein the backbone polymer and the ion conductive polymer are different from each other.

First claim

What is claimed is:

1. A separator for a rechargeable lithium battery comprising:
a backbone polymer; and
a coating layer consisting of an ion conductive polymer and an electrolyte solution, the coating layer surrounding the backbone polymer,
wherein:
the backbone polymer comprises polyvinylidenefluoride (PVdF);
the ion conductive polymer consists of a copolymer of polyvinylidenefluoride and hexafluoropropylene (PVdF-HFP) or the copolymer of polyvinylidenefluoride and hexafluoropropylene (PVdF-HFP) and at least one selected from the group consisting of polyethylene (PE), polypropylene (PP), polyolefin, polyethyleneoxide (PEO), polypropyleneoxide (PPO), polyacrylonitrile (PAN), polymethylmethacrylate (PMMA), and polyvinylchloride (PVC);
the backbone polymer is included in an amount of about 5 wt % to about 70 wt % based on a total weight of the separator;
the ion conductive polymer is included in an amount of about 5 wt % to about 70 wt % based on the total weight of the separator; and
the ion conductive polymer and the electrolyte solution are included in a weight ratio of 1:2 to 1:6.

2. The separator for a rechargeable lithium battery of claim 1 , wherein the backbone polymer further comprises at least one selected from the group consisting of polytetrafluoroethylene (PTFE), polyethylene (PE), polypropylene (PP), polyolefin, polyethyleneoxide (PEO), polypropyleneoxide (PPO), polyacrylonitrile (PAN), polymethylmethacrylate (PMMA), and polyvinylchloride (PVC).

3. The separator for a rechargeable lithium battery of claim 1 , wherein the ion conductive polymer is a gel-type polymer.

4. The separator for a rechargeable lithium battery of claim 1 , wherein the copolymer of polyvinylidenefluoride and hexafluoropropylene (PVdF-HFP) comprises hexafluoropropylene (HFP) in an amount of about 2 to about 70 wt % based on a total weight of the copolymer of polyvinylidenefluoride and hexafluoropropylene (PVdF-HFP).

5. The separator for a rechargeable lithium battery of claim 1 , wherein the copolymer of polyvinylidenefluoride and hexafluoropropylene (PVdF-HFP) comprises the hexafluoropropylene (HFP) in an amount of about 5 to about 15 wt % based on a total weight of the copolymer of polyvinylidenefluoride and hexafluoropropylene (PVdF-HFP).

6. The separator for a rechargeable lithium battery of claim 1 , wherein the electrolyte solution comprises a lithium salt and a non-aqueous organic solvent.

7. The separator for a rechargeable lithium battery of claim 6 , wherein the lithium salt comprises LiClO 4 , and the non-aqueous organic solvent comprises a mixture of propylenecarbonate (PC) and ethylenecarbonate (EC).

8. The separator for a rechargeable lithium battery of claim 1 , wherein the electrolyte solution is included in an amount of about 5 wt % to about 90 wt % based on the total weight of the separator.

9. The separator for a rechargeable lithium battery of claim 1 , wherein the backbone polymer comprises a film.

10. The separator for a rechargeable lithium battery of claim 1 , wherein the backbone polymer further comprises at least one selected from the group consisting of polytetrafluoroethylene (PTFE), polyethylene (PE), polypropylene (PP), polyolefin, polyethyleneoxide (PEO), polypropyleneoxide (PPO), polyacrylonitrile (PAN), polymethylmethacrylate (PMMA), and polyvinylchloride (PVC), and the ion conductive polymer consists of the copolymer of polyvinylidenefluoride and hexafluoropropylene (PVdF-HFP) and the at least one selected from the group consisting of polyethylene (PE), polypropylene (PP), polyolefin, polyethyleneoxide (PEO), polypropyleneoxide (PPO), polyacrylonitrile (PAN), polymethylmethacrylate (PMMA), and polyvinylchloride (PVC).

11. The separator for a rechargeable lithium battery of claim 1 , wherein the ion conductive polymer surrounds top and bottom surfaces and side surfaces of the backbone polymer.

12. A separator for a rechargeable lithium battery comprising:
a backbone polymer; and
a coating layer consisting of an ion conductive polymer and an electrolyte solution, the coating layer surrounding the backbone polymer,
wherein:
the backbone polymer comprises polyvinylidenefluoride (PVdF);
the ion conductive polymer consists of a copolymer of polyvinylidenefluoride and hexafluoropropylene (PVdF-HFP) or the copolymer of polyvinylidenefluoride and hexafluoropropylene (PVdF-HFP) and at least one selected from the group consisting of polyethylene (PE), polypropylene (PP), polyolefin, polyethyleneoxide (PEO), polypropyleneoxide (PPO), polyacrylonitrile (PAN), polymethylmethacrylate (PMMA), and polyvinylchloride (PVC);
a weight ratio of the ion conductive polymer to the backbone polymer in the separator is from 5/90 to 90/5;
a weight ratio of the ion conductive polymer to the electrolyte solution is from 1/6 to 1/2;
the backbone polymer is included in an amount of about 5 wt % to about 70 wt % based on a total weight of the separator; and
the ion conductive polymer is included in an amount of about 5 wt % to about 70 wt % based on the total weight of the separator.

Assignees

• Samsung Sdi Co Ltd
• Bosch Gmbh Robert

Inventors

• Kim In
• Kim Hyung-Sik
• Kim Duk-Jung
• Park Zin

Classifications

• H01M10/0568 Primary

  characterised by the solutes · CPC title

• H01M50/42

  Acrylic resins · CPC title

• H01M50/417

  Polyolefins · CPC title

• H01M50/426 Primary

  Fluorocarbon polymers · CPC title

• H01M50/414

  Synthetic resins, e.g. thermoplastics or thermosetting resins · CPC title