Preparation and feed apparatus of standard sample for calibration of trace-analysis instrument

Patent metadata

Field	Value
Publication number	US-10699887-B2
Application number	US-201715786389-A
Country	US
Kind code	B2
Filing date	Oct 17, 2017
Priority date	Dec 7, 2016
Publication date	Jun 30, 2020
Grant date	Jun 30, 2020

Abstract

Embodiments of the present disclosure relate to a preparation and feed apparatus of a standard sample for calibration of a trace-analysis instrument, and especially to a preparation and feed apparatus of a standard sample for calibration of a gas chromatograph-ion mobility spectrometer. When the trace-analysis instrument is being calibrated by taking advantage of the preparation and feed apparatus according to embodiments of the disclosure, it is unnecessary to use an additional dedicated tool and steps to prepare the sample for testing and to use an organic solvent or a dedicated sample application/dispensing tool, resulting in that the trace-analysis instrument is simple and convenient to carry and use, and the substance for calibration is also convenient to store and exchange; moreover, the trace-analysis instrument is also safe, reliable and environmentally friendly.

First claim

What is claimed is:

1. A preparation and feed apparatus of a standard sample for calibration of a trace-analysis instrument, wherein the preparation and feed apparatus comprises: a piston assembly, comprising: a piston cylinder; a piston rod which is received within the piston cylinder and the piston rod is provided with a storage chamber penetrating radially therethrough; and a diffusion chamber defined inside the piston cylinder and between an inner wall of the piston cylinder and the piston rod, and a steam channel which is arranged outside the piston assembly and is provided with a steam inlet port and a steam outlet port both being in communication with the piston cylinder, and wherein the piston rod is configured to be displaceable longitudinally within the piston cylinder, such that the storage chamber is communicable with the steam channel via the steam inlet port, and a condition of communication from the steam outlet port to the diffusion chamber within the piston cylinder is changeable continuously between a completely unobstructed condition and a completely occluded condition via the piston rod.

2. The preparation and feed apparatus according to claim 1 , wherein the piston assembly further comprises peripheral sealing rings mounted onto the piston rod, and wherein the peripheral sealing rings are configured to abut in an airtight manner against both the inner wall of the piston cylinder and the piston rod so as to be disposed therebetween, and also configured to be displaceable longitudinally inside the piston cylinder with a displacement of the piston rod.

3. The preparation and feed apparatus according to claim 2 , wherein the peripheral sealing rings comprises an upper sealing ring and a lower sealing ring which are respectively configured to be disposed at both upper and lower sides of the storage chamber, longitudinally within the piston cylinder.

4. The preparation and feed apparatus according to claim 3 , wherein the diffusion chamber is delimited between the inner wall of the piston cylinder and the piston rod by the lower sealing ring, and is provided with a volume which is continuously variable with the displacement of the piston rod.

5. The preparation and feed apparatus according to claim 1 , further comprising a air channel which is provided outside the piston assembly and in communication with the piston cylinder and an external environment, and is provided with a first-level air-tight valve which is opened unidirectionally towards the piston cylinder.

6. The preparation and feed apparatus according to claim 5 , wherein the air channel comprises a gas filter device provided upstream of the first-level airtight valve.

7. The preparation and feed apparatus according to claim 6 , wherein the gas filter device comprises a filter cartridge which is filled with activated carbon and a molecular sieve.

8. The preparation and feed apparatus according to claim 5 , wherein the first-level airtight valve which is opened unidirectionally is constructed to be of a valve core construction, comprising: a hollow valve core body, comprising: a trailing connection portion at a trailing portion of the valve core body; a pagoda-shaped connection head provided at a leading portion of the valve core body; and a valve core middle portion provided between the trailing connection portion and the pagoda-shaped connection head, and an elastic sealing sleeve within which the pagoda-shaped connection head is encapsulated circumferentially, and wherein the pagoda-shaped connection head is provided with a valve core exhaust port, which is located laterally at a front end of the pagoda-shaped connection head.

9. The preparation and feed apparatus according to claim 1 , further comprising a hollow feed syringe needle which is removably mounted at a bottom portion of the piston cylinder and comprises:
a needle inlet end which is in fluid communication with the bottom portion of the piston cylinder; and
a needle outlet end which extends outwards from the piston cylinder.

10. The preparation and feed apparatus according to claim 9 , wherein the feed syringe needle is threadedly connected with the bottom portion of the piston cylinder.

11. The preparation and feed apparatus according to claim 9 , wherein the feed syringe needle is in communication with the bottom portion of the piston cylinder via a second-level airtight valve which is opened unidirectionally from the piston cylinder towards the needle inlet end of the feed syringe needle.

12. The preparation and feed apparatus according to claim 11 , wherein the second-level airtight valve which is opened unidirectionally is constructed to be of a valve core construction, comprising: a hollow valve core body, comprising: a trailing connection portion at a trailing portion of the valve core body; a pagoda-shaped connection head provided at a leading portion of the valve core body; and a valve core middle portion provided between the trailing connection portion and the pagoda-shaped connection head, and an elastic sealing sleeve within which the pagoda-shaped connection head is encapsulated circumferentially, and wherein the pagoda-shaped connection head is provided with a valve core exhaust port, which is located laterally at a front end of the pagoda-shaped connection head.

13. The preparation and feed apparatus according to claim 1 , wherein the storage chamber is configured to accommodate a sample vessel which is removably mounted herein.

14. The preparation and feed apparatus according to claim 13 , wherein the sample vessel comprises:
a hollow housing, which comprises a through-hole in an axial direction thereof and a pair of stepped counter bores recessed axially at both ends thereof, each stepped counter bore comprising a first counter bore and a second counter bore which are arranged co-axially, and the first counter bore having a smaller cross section dimension and a larger depth recessed inwards axially as compared with those of the second counter bore;
at least one sample storage device, each of which is provided within the first counter bore and comprises:
a sample receptacle which is hollow and arranged axially, and
a pair of micro-pore filtration membranes which abut axially against both ends of the sample receptacle, and

a vessel cover, configured to press one of the pair of micro-pore filtration membrane which is located outside axially, against the sample receptacle.

15. The preparation and feed apparatus according to claim 14 , wherein the vessel cover is provided with a recess at an inner end thereof, the inner end is arranged to face the sample storage device, the recess being further provided with tooth-shaped projections at an inner surface thereof facing the micro-pore filtration membrane.

16. The preparation and feed apparatus according to claim 1 , further comprising a blowing device provided within or adjacent to the storage chamber in the piston rod.

17. The preparation and feed apparatus according to claim 16 , wherein the blowing device is located opposite to a side of the storage chamber at which side the storage chamber is in communication with the steam channel, and is in communication with the storage chamber so as to blow inwards a sample vessel which is removably mounted in the storage chamber.

18. The preparation and feed apparatus according to claim 1 , further comprising a heater provided within or adjacent to the storage chamber in the piston rod.

19. A gas chromatograph-ion mobility spectrometer, comprising the preparation and feed apparatus according claim 1 .

Assignees

• Nuctech Co Ltd

Inventors

• Zhang Qingjun
• Li Yuanjing
• Zhao Ziran
• Zhu Weiping
• Bai Nan
• Ma Qiufeng

Classifications

• G01N33/0013 Primary

  by a chemical reaction (a chemical reaction taking place or a gas being eliminated in one or more analysing channels G01N33/0024) · CPC title

• G01N35/1095

  for supplying the samples to flow-through analysers (for a specific analyser see relevant groups, e.g. under G01N15/00, G01N21/00, G01N27/00, G01N30/00, H01J49/00) · CPC title

• B01L2300/06

  Auxiliary integrated devices, integrated components · CPC title

• B01L3/523

  with means for closing or opening · CPC title

• G01N2030/009

  Extraction · CPC title