Hydrogel liquid precursor, liquid set for three-dimensional modeling, hydrogel modeling object, and method of manufacturing three-dimensional object

Patent metadata

Field	Value
Publication number	US-10699599-B2
Application number	US-201816011159-A
Country	US
Kind code	B2
Filing date	Jun 18, 2018
Priority date	Mar 20, 2015
Publication date	Jun 30, 2020
Grant date	Jun 30, 2020

Abstract

A hydrogel liquid precursor includes an inorganic mineral and a monomer, wherein the inorganic mineral accounts for 15 percent by mass or more of the hydrogel liquid precursor, wherein the hydrogel liquid precursor has an initial viscosity of 20 mPa·s or less at 25 degrees C., and wherein the hydrogel liquid precursor has a ratio of a two-week viscosity to the initial viscosity of from 0.90 to 1.10, the two-week viscosity representing a viscosity of the hydrogel liquid precursor at 25 degrees C. after being left at 50 degrees C. for two weeks.

First claim

What is claimed is:

1. A hydrogel modeling object comprising:
an inorganic mineral;
a phosphonic acid compound; and
a polymer,
wherein the inorganic mineral accounts for 15 percent by mass or more of the hydrogel modeling object, and
wherein the hydrogel modeling object has an 80 percent compressive stress-strain of 1.0 MPa or more.

2. The hydrogel modeling object according to claim 1 , wherein the inorganic mineral includes a laminate mineral.

3. The hydrogel modeling object according to claim 1 used as an internal organ model.

4. The hydrogel modeling object according to claim 1 , wherein the phosphonic acid compound is represented by the following Chemical formula 1,

where R represents a substituted or non-substituted divalent substitution group.

5. The hydrogel modeling object according to claim 4 , wherein R in the Chemical formula 1 includes —(R 1 )C(R 2 )—, where R 1 and R 2 each, independently represent substituted or non-substituted alkyl groups.

6. The hydrogel modeling object according to claim 4 , wherein R in the Chemical formula 1 includes —(OH)C(CH 3 )—.

7. A hydrogel modeling object comprising:
a first modeled portion including the hydrogel modeling object of claim 1 ; and
a second modeled portion including a second hydrogel modeling object having a different modulus of compressive elasticity from a compressive elasticity of the hydrogel modeling object of claim 1 ,
wherein the first modeled portion includes the second modeling portion or the second modeled portion includes the first modeled portion.

Assignees

• Norikane Yoshihiro
• Iwata Hiroshi
• Ricoh Co Ltd

Inventors

• Norikane Yoshihiro
• Iwata Hiroshi

Classifications

• B33Y70/10

  Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials · CPC title

• B29C64/112

  using individual droplets, e.g. from jetting heads · CPC title

• C08K5/5317

  Phosphonic compounds, e.g. R—P(:O)(OR')2 · CPC title

• C08J3/075

  Macromolecular gels · CPC title

• B33Y80/00

  Products made by additive manufacturing · CPC title