Polymer / single-walled carbon nanotube composite for gas detection

Patent metadata

Field	Value
Publication number	US-10697918-B2
Application number	US-201715586466-A
Country	US
Kind code	B2
Filing date	May 4, 2017
Priority date	May 4, 2016
Publication date	Jun 30, 2020
Grant date	Jun 30, 2020

Abstract

A sensor can include a conductive region in electrical communication with at least two electrodes, the conductive region can include a composite of a polymer and SWCNTs immobilized onto a substrate. In certain embodiment, a linker can be grafted on the substrate. The linker can connect the substrate and the composite of the polymer and SWCNTs. In certain embodiments, the linker can covalently bond the polymer to the substrate. In certain embodiments, metal nanoparticles or ions can be incorporated as a metal sensitizer to confer further selectivity or sensitivity to the device. In certain embodiments, the polymer can act as a ligand for a variety of metal ions. By incorporating a specific metal ion, the sensor can selectively detect a specific analyte. In certain embodiments, the composite of the polymer and SWCNTs can be functionalized. In certain embodiments, the composite can further include a sensing element.

First claim

What is claimed is:

1. A sensor for detecting an analyte comprising:
a substrate; and
a conductive region in electrical communication with at least two electrodes on the substrate, the conductive region including a composite, wherein the composite includes a carbon nanotube associated with a polymer covalently linked to a surface of the substrate via a linker.

2. The sensor of claim 1 , wherein the polymer includes a nitrogenous group available to form a covalent bond with the linker.

3. The sensor of claim 2 , wherein the polymer includes poly(4-vinylpyridine) (P4VP).

4. The sensor of claim 1 , wherein the linker includes a quaternary nitrogen bond with the polymer.

5. The sensor of claim 4 , wherein the linker is from an alkyl halide group.

6. The sensor of claim 5 , wherein the linker is from 3-bromopropyltrichlorosilane.

7. The sensor of claim 1 , wherein the polymer is further associated with a metal particle or a metal ion.

8. The sensor of claim 7 , wherein the metal ion is a soft Lewis acidic cation.

9. The sensor of claim 7 , wherein the metal ion is Cu2+, Cu+, Pd2+, Ru+, Rh3+, Ag+, Cd2+, Ru3+, Os+, Ir3+, Pt4+, Au3+, Au+, Hg2+, Hg+ or Tl+.

10. The sensor of claim 7 , wherein the metal ion is an oxidizing agent.

11. The sensor of claim 7 , wherein the metal ion is permanganate.

12. The sensor of claim 1 , wherein a second polymer is incorporated into the sensor.

13. The sensor of claim 12 , wherein the second polymer is a conducting polymer.

14. The sensor of claim 12 , wherein the second polymer is a polydiacetylene.

15. The sensor of claim 1 , wherein the carbon nanotube is a single-walled carbon nanotube.

16. The sensor of claim 1 , wherein the substrate is glass, paper or plastic.

17. The sensor of claim 1 , wherein the substrate is a resonant circuit.

18. The sensor of claim 1 , further comprising a metal sensitizer.

19. The sensor of claim 1 , wherein the composite is functionalized.

20. The sensor of claim 19 , wherein the metal sensitizer includes silver nanoparticles.

21. The sensor of claim 1 , wherein the composite further comprises a sensing element.

22. The sensor of claim 19 , wherein the composite is functionalized with 2-bromoethanol.

23. The sensor of claim 1 , wherein the analyte is glucose.

24. The sensor of claim 21 , wherein the sensing element is glucose oxidase.

25. A method of sensing an analyte comprising:
exposing a sensor to a sample, the sensor including:
a substrate; and
a conductive region in electrical communication with at least two electrodes on the substrate, the conductive region including a composite, wherein the composite includes a carbon nanotube associated with a polymer covalently linked to a surface of the substrate via a linker; and
measuring an electrical property at the electrodes.

26. The method of claim 25 , further comprising detecting an amine, a thioether, a volatile organic compound, an environmental stimulus, or glucose.

27. The method of claim 25 , further comprising detecting the analyte wirelessly.

28. The method of claim 25 , further comprising detecting the analyte through a wireless radio frequency communication.

29. The method of claim 25 , further comprising detecting an output from a radio frequency identification tag including the sensor.

30. The method of claim 25 , wherein the polymer includes a nitrogenous group available to form a covalent bond with the linker.

31. The method of claim 25 , wherein the polymer includes poly(4-vinylpyridine) (P4VP).

32. The method of claim 25 , wherein the linker includes a quaternary nitrogen bond with the polymer.

33. The method of claim 32 , wherein the linker is derived from an alkyl halide group.

34. The method of claim 32 , wherein the linker is derived from 3-bromopropyltrichlorosilane.

35. The method of claim 25 , wherein the polymer is further associated with a metal particle or a metal ion.

36. A method of preparing a sensor for detecting an analyte comprising:
preparing a substrate;
forming a conductive region on the substrate, the conductive region including a composite, wherein the composite includes a carbon nanotube and a polymer;
grafting a linker on the substrate;
forming a covalent bond between the substrate and the polymer via the linker; and
placing the conductive region in electrical communication with at least two electrodes.

Assignees

• Massachusetts Inst Technology

Inventors

• Swager Timothy Manning
• Liu Sophie
• Yoon Bora

Classifications

• C08F126/06

  by a heterocyclic ring containing nitrogen · CPC title

• C08L39/08

  Homopolymers or copolymers of vinyl-pyridine · CPC title

• C01B32/168

  After-treatment · CPC title

• C08F8/44

  Preparation of metal salts or ammonium salts · CPC title

• C08F38/02

  Acetylene · CPC title