Differential viscometer with solvent compressibility correction

Patent metadata

Field	Value
Publication number	US-10697878-B2
Application number	US-201615736291-A
Country	US
Kind code	B2
Filing date	Jul 8, 2016
Priority date	Jul 8, 2015
Publication date	Jun 30, 2020
Grant date	Jun 30, 2020

Abstract

An improved version of the capillary bridge viscometer that compensates for the effect of solvent compressibility is disclosed. A novel, yet simple and inexpensive modification to a conventional capillary bridge viscometer design can improve its ability to reject pump pulses by more than order of magnitude. This improves the data quality and allows for the use of less expensive pumps. A pulse compensation volume is added such that it transmits pressure to the differential pressure transducer without sample flowing there through. The pressure compensation volume enables the cancellation of the confounding effects of pump pulses in a capillary bridge viscometer.

First claim

The invention claimed is:

1. A capillary bridge viscometer comprising:
a bridge to receive a solvent comprising
a first arm comprising a first pair of series connected sensing capillaries,
a second arm comprising
a second pair of series connected sensing capillaries, and
a delay volume connected in series between the second pair of series connected sensing capillaries,
wherein the second arm is connected in parallel with the first arm

a first differential pressure transducer coupled across the first arm and the second arm,
such that the first differential pressure transducer is coupled to the first arm at a first junction between each of the first pair of series connected sensing capillaries, and
such that the first differential pressure transducer is coupled to the second arm at a second junction between one of the second pair of series connected sensing capillaries and the delay volume, and

a pressure compensation volume connected to the first junction and to the first differential pressure transducer,
wherein the pressure compensation volume comprises capillary tubing;

a second differential pressure transducer connected in parallel with the first arm and the second arm; and
wherein as a length of the capillary tubing increases, a suppression ratio grows until it reaches a maximum, thereby eliminating parasitic noise from pump pulses.

2. The capillary bridge viscometer of claim 1 wherein the tubing comprises stainless steel.

3. The capillary bridge viscometer of claim 1 further comprising a valve connected to the pressure compensation volume to permit the volume to be flushed by fluid passing through the first arm.

Assignees

• Wyatt Tech Corp

Inventors

• Trainoff Steven P

Classifications

• G01N30/26

  Conditioning of the fluid carrier; Flow patterns · CPC title

• G01N30/62 Primary

  Detectors specially adapted therefor · CPC title

• G01N2030/626

  calibration, baseline · CPC title

• G01N2030/625

  by measuring reference material, e.g. carrier without sample · CPC title

• G01N11/08 Primary

  by measuring pressure required to produce a known flow · CPC title