Scandium purification method

Patent metadata

Field	Value
Publication number	US-10697043-B2
Application number	US-201716082384-A
Country	US
Kind code	B2
Filing date	Mar 1, 2017
Priority date	Mar 14, 2016
Publication date	Jun 30, 2020
Grant date	Jun 30, 2020

Abstract

In separating scandium and thorium from a leachate obtained by adding sulfuric acid to a nickel oxide ore containing scandium and thorium, scandium is recovered from only one system. The method according to the invention comprises: an extraction step S1 for treating a nickel oxide ore containing scandium and thorium with sulfuric acid to give an acidic solution (a feed solution for extraction), and then solvent-extracting the feed solution with the use of a scandium extractant containing an amide derivative to thereby divide the feed solution into an organic extract (a first organic phase) containing scandium and thorium and a liquid extract (a first aqueous phase) containing impurities; and a washing step S2 for adding sulfuric acid to the organic extract (the first organic phase) and thus dividing the same into washed organic matters (a second organic phase) containing thorium and a washed liquid (a second aqueous phase) containing scandium.

First claim

The invention claimed is:

1. A scandium purification method comprising:
an extraction step of subjecting an acidic solution obtained by treating nickel oxide ore containing scandium and thorium with sulfuric acid to solvent extraction using a scandium extractant containing an amide derivative to separate the acidic solution into a first organic phase containing scandium and thorium and a first aqueous phase containing impurities; and
a washing step of adding sulfuric acid to the first organic phase to separate the first organic phase into a second organic phase containing thorium and a second aqueous phase containing scandium, wherein
a pH is adjusted to 1.0 or more and 3.0 or less in the extraction step, and
a pH is adjusted to 1.0 or more and 2.5 or less in the washing step, and a volume ratio (O/A ratio) of the first organic phase (O) to the sulfuric acid (A) in the washing step is 0.1 or more and 0.5 or less.

2. The scandium purification method according to claim 1 , wherein
the amide derivative is represented by the following general formula (I):

In the formula (I), R 1 and R 2 each represent the same alkyl group or different alkyl groups wherein the alkyl group may be linear or branched; R 3 represents a hydrogen atom or an alkyl group; R 4 represents a hydrogen atom or any group other than an amino group, which is bonded to an a carbon as an amino acid.

Assignees

• Sumitomo Metal Mining Co

Inventors

• SENBA Yusuke
• Matsuoka Itsumi
• Kobayashi Hiroshi

Classifications

• Y02P10/20

  Recycling · CPC title

• C22B3/26

  by liquid-liquid extraction using organic compounds · CPC title

• C22B3/08

  Sulfuric acid {, other sulfurated acids or salts thereof} · CPC title

• C22B59/00 Primary

  Obtaining rare earth metals · CPC title

• B01D11/0492

  Applications, solvents used · CPC title