Polyester adhesive composition and adhesive sheet

Patent metadata

Field	Value
Publication number	US-10696880-B2
Application number	US-201515300966-A
Country	US
Kind code	B2
Filing date	Jan 16, 2015
Priority date	Apr 3, 2014
Publication date	Jun 30, 2020
Grant date	Jun 30, 2020

Abstract

Provided are a polyester-based pressure-sensitive adhesive composition having high wetting ability and superior adherability and light peelability, and a pressure-sensitive adhesive sheet produced with such a pressure-sensitive adhesive composition. The polyester-based pressure-sensitive adhesive composition includes a polyester obtained by polycondensation of a difunctional or polyfunctional carboxylic acid and a diol; a fatty acid ester; and a crosslinking agent, wherein the polyester has a weight average molecular weight of 8,500 to 50,000, and the fatty acid ester has no additional functional group and has a molecular weight of 200 to 700. The polyester-based pressure-sensitive adhesive composition contains 10 to 150 parts by weight of the fatty acid ester based on 100 parts by weight of the polyester.

First claim

The invention claimed is:

1. A polyester-based pressure-sensitive adhesive sheet, comprising:
a support; and
a pressure-sensitive adhesive layer formed on at least one side of the support through crosslinking of a polyester-based pressure-sensitive adhesive composition,
wherein said a polyester-based pressure-sensitive adhesive composition comprises:
a polyester obtained by polycondensation of a difunctional or polyfunctional carboxylic acid and a diol;
a fatty acid ester; and
a crosslinking agent, wherein
the fatty acid ester does not react with the crosslinking agent,
the polyester has a weight average molecular weight of 9,000 to 42,000,
the fatty acid ester has a molecular weight of 200 to 700,
the polyester-based pressure-sensitive adhesive composition containing 10 to 150 parts by weight of the fatty acid ester based on 100 parts by weight of the polyester, and
the pressure-sensitive adhesive layer has a gel fraction of 40 to 80% by weight,
wherein the polyester-based pressure-sensitive adhesive sheet has an adhesive strength of 0.08 N/25 mm or less to a glass surface,
wherein the polyester contains less than 3% by weight of a monocarboxylic acid component,
wherein molar ratio (OH/COOH) of hydroxyl groups of the diol to carboxyl groups of the carboxylic acid is from 1.28 to 3, and
wherein the crosslinking agent is present in an amount of 15 to 30 parts by weight per 100 parts by weight of the polyester.

2. The pressure-sensitive adhesive sheet according to claim 1 , which has a wetting speed of 9 cm 2 /second or more on a glass surface.

3. The polyester-based pressure-sensitive adhesive sheet according to claim 1 , wherein the crosslinking agent is an isocyanate crosslinking agent.

4. The pressure-sensitive adhesive sheet according to claim 3 , which has a wetting speed of 9 cm 2 /second or more on a glass surface.

Assignees

• Nitto Denko Corp

Inventors

• Yoshie Satomi
• Ishiguro Shigeki
• Tanaka Akiko

Classifications

• C08J7/046

  Forming abrasion-resistant coatings; Forming surface-hardening coatings · CPC title

• C08J7/043

  Improving the adhesiveness of the coatings per se, e.g. forming primers (adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50) · CPC title

• C08J7/0427

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title

• C09J2301/312

  parameters being the characterizing feature · CPC title

• C09J2301/308

  the adhesive tape or sheet losing adhesive strength when being stretched, e.g. stretch adhesive · CPC title