Polyolefin composition with improved thoughness

Patent metadata

Field	Value
Publication number	US-10696834-B2
Application number	US-201716069392-A
Country	US
Kind code	B2
Filing date	Jan 27, 2017
Priority date	Jan 29, 2016
Publication date	Jun 30, 2020
Grant date	Jun 30, 2020

Abstract

A polyolefin composition comprising a heterophasic propylene copolymer and a polar modified α-polyolefin.

First claim

The invention claimed is:

1. A polyolefin composition (PO) comprising a heterophasic propylene copolymer (HECO) and a polar modified α-polyolefin (PMP), wherein said heterophasic propylene copolymer (HECO) comprises:
(a) a (semi)crystalline polypropylene (PP) that is a (semi)crystalline propylene homopolymer (H-PP); and
(b) an elastomeric propylene copolymer (EPC) dispersed in said (semi)crystalline polypropylene (PP);
wherein said polyolefin composition (PO) has:
(i) a xylene cold soluble (XCS) fraction in the range of 28 to 45 wt. %;
wherein further the xylene cold soluble (XCS) fraction of said polyolefin composition has:
(ii) an intrinsic viscosity (IV) in the range of 1.80 to 3.30 dl/g.

2. The polyolefin composition (PO) according to claim 1 , wherein:
(a) the intrinsic viscosity (IV) of the xylene cold insoluble (XCI) fraction of the heterophasic propylene copolymer (HECO) is in the range of 1.00 to 1.30 dl/g; and/or
(b) the melt flow rate MFR 2 (230° C.) measured according to ISO 1133 of the (semi)crystalline polypropylene (PP) of the heterophasic propylene copolymer (HECO) is in the range of 45 to 150 g/10 min; and/or
(c) the comonomer content of the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO) is in the range of 21 to 55 mol %; and/or
(d) the intrinsic viscosity (IV) of the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO) is in the range of 1.50 to 3.00 dl/g.

3. A polyolefin composition (PO) comprising a heterophasic propylene copolymer (HECO) and a polar modified α-polyolefin (PMP), wherein said heterophasic propylene copolymer (HECO) comprises:
(a) a (semi)crystalline polypropylene (PP) having a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 45 to 150 g/10 min, wherein the (semi)crystalline polypropylene (PP) is a (semi)crystalline propylene homopolymer (H-PP); and
(b) an elastomeric propylene copolymer (EPC) dispersed in said (semi)crystalline polypropylene (PP);
wherein said heterophasic propylene copolymer (HECO) has:
(i) a xylene cold soluble (XCS) fraction in the range of 25 to 40 wt. %;
wherein further the xylene cold soluble (XCS) fraction of said heterophasic propylene copolymer (HECO) has:
(ii) a comonomer content in the range of 21 to 55 mol %; and
(iii) optionally an intrinsic viscosity (IV) in the range of 1.50 to 3.00 dl/g,
and optionally still further,
(iv) the intrinsic viscosity (IV) of the xylene cold insoluble (XCI) fraction of the heterophasic propylene copolymer (HECO) is in the range of 1.00 to 1.30 dl/g.

4. A polyolefin composition (PO) comprising a heterophasic propylene copolymer (HECO) and a polar modified α-polyolefin (PMP), wherein said heterophasic propylene copolymer (HECO) comprises:
(a) a (semi)crystalline polypropylene (PP) optionally having a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 45 to 150 g/10 min, wherein the (semi)crystalline polypropylene (PP) is a (semi)crystalline propylene homopolymer (H-PP); and
(b) an elastomeric propylene copolymer (EPC) dispersed in said (semi)crystalline polypropylene (PP);
wherein said heterophasic propylene copolymer (HECO) has:
(i) a xylene cold soluble (XCS) fraction in the range of 25 to 40 wt. %;
wherein further the xylene cold soluble (XCS) fraction of said heterophasic propylene copolymer (HECO) has:
(ii) a comonomer content in the range of 21 to 55 mol %; and
(iii) optionally an intrinsic viscosity (IV) in the range of 1.50 to 3.00 dl/g,
and still further;
(iv) the intrinsic viscosity (IV) of the xylene cold insoluble (XCI) fraction of the heterophasic propylene copolymer (HECO) is in the range of 1.00 to 1.30 dl/g.

5. The polyolefin composition (PO) according to claim 3 , wherein:
(a) said polyolefin composition (PO) has a xylene cold soluble (XCS) fraction in the range of 28 to 45 wt. %; and/or
(b) the xylene cold soluble (XCS) fraction of said polyolefin composition (PO) has an intrinsic viscosity (IV) in the range of 1.80 to 3.30 dl/g.

6. The polyolefin composition (PO) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) has:
(a) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 15 to 55 g/10 min; and/or
(b) a comonomer content in the range of 10.0 to 28.0 mol %.

7. The polyolefin composition (PO) according to claim 1 , wherein:
(a) the xylene cold soluble (XCS) fraction of said polyolefin composition (PO) has a comonomer content in the range of 21 to 55 mol %; and/or
(b) said polyolefin composition (PO) has a comonomer content in the range of 25 to 60 mol %.

8. The polyolefin composition (PO) according claim 1 , having a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 5 to 30 g/10 min.

9. The polyolefin composition (PO) according to claim 1 , wherein the weight ratio between the (semi)crystalline polypropylene (PP) and the elastomeric propylene copolymer (EPC) of the heterophasic propylene copolymer (HECO) [(PP)/(EPC)] is in the range of 50/50 to 85/15.

10. The polyolefin composition (PO) according to claim 1 , wherein:
(a) the (semi)crystalline polypropylene (PP) of the heterophasic propylene copolymer (HECO) is a (semi)crystalline propylene homopolymer (H-PP) having a xylene cold soluble (XCS) fraction of less than 4.5 wt. %; and/or
(b) the elastomeric propylene copolymer (EPC) of the heterophasic propylene copolymer (HECO) is an ethylene propylene rubber (EPR).

11. The polyolefin composition (PO) according to claim 1 , wherein:
(a) the weight ratio between the heterophasic propylene copolymer (HECO) and the polar modified α-polyolefin (PMP) is in the range of 4/1 to 85/1; and/or
(b) said polyolefin composition (PO) comprises:
(i) 60 to 99 wt. %, based on the total weight of the polyolefin composition (PO), of the heterophasic propylene copolymer (HECO); and
(ii) at least 1 wt. %, based on the total weight of the polyolefin composition (PO), of the polar modified α-polyolefin (PMP).

12. The polyolefin composition (PO) according to claim 1 , wherein the polar modified α-polyolefin (PMP) has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 0.5 to 10 g/10 min.

13. The polyolefin composition (PO) according to claim 1 , wherein the polar modified α-polyolefin (PMP) is a polar modified α-polyolefin (PMP) grafted with maleic anhydride.

14. The polyolefin composition (PO) according to claim 1 , wherein the α-polyolefin (pre-PMP) to be modified is an elastomeric ethylene copolymer (EEC).

15. The polyolefin composition (PO) according to claim 1 , wherein the polyolefin composition (PO) has:
(a) a tensile modulus of at least 700 MPa, and/or
(b) an impact strength at 23° C. of at least 40 kJ/m 2 , and/or
(c) a shrinkage in flow (sector, radius 300 mm, opening angle 20°) of below 1.50%.

16. An automotive article comprising a polyolefin composition (PO) according to claim 1 , wherein the automotive article is an exterior automotive article.

17. A process for the preparation of the polyolefin composition (PO) according to claim 1 , by extruding the heterophasic propylene copolymer (HECO) and the polar modified α-polyolefin (PMP) in an extruder.

18. The process according to claim 17 , wherein the heterophasic propylene copolymer (HECO) is obtained by producing the (semi)crystalline polypropylene (PP) in a first reaction zone comprising at least one reactor, transferring said (semi)crystalline polypropylene (PP) in a subsequent reaction zone comprising at least

Assignees

• Borealis Ag

Inventors

• Grestenberger Georg
• Mileva Daniela
• Kahlen Susanne
• Jerabek Michael

Classifications

• C08L23/12 Primary

  Polypropene · CPC title

• C08L23/14

  Copolymers of propene (C08L23/16 takes precedence) · CPC title

• C08L2205/22

  Mixtures comprising a continuous polymer matrix in which are dispersed crosslinked particles of another polymer · CPC title

• C08L2207/02

  Heterophasic composition · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title