Glass-reinforced PDMS copolycarbonate resins

Patent metadata

Field	Value
Publication number	US-10696803-B2
Application number	US-201615746589-A
Country	US
Kind code	B2
Filing date	Jul 29, 2016
Priority date	Jul 29, 2015
Publication date	Jun 30, 2020
Grant date	Jun 30, 2020

Abstract

A thermoplastic composition including a resin phase and 10% to 55%, especially 25% to 45% of glass fibers by weight of the composition is disclosed. The resin phase includes a polysiloxane block copolymer including polydimethylsiloxane blocks and polycarbonate blocks derived from bisphenol A. The resin phase further includes a polycarbonate and has between 2.0 wt % and 10 wt % by weight of siloxane. The thermoplastic composition has (i) a notched Izod impact strength of at least 150 Joules per meter measured at 23° C. according to ASTM D256, (ii) a tensile strength greater than 95 MPa as determined by ASTM D638, (iii) a tensile modulus greater than 10,900 MPa as determined by ASTM D638 and (iv) an unnotched Izod impact strength greater than 775 Joules per meter measured at 23° C. according to ASTM D256.

First claim

We claim:

1. A thermoplastic composition comprising:
(a) a resin phase comprising a polysiloxane block copolymer including (1) polydimethylsiloxane blocks and bisphenol A polycarbonate blocks, and (2) a bisphenol A homopolycarbonate, wherein the resin phase has between 2.0 wt % and 10 wt % of siloxane; and
(b) 10% to 55% glass fibers by weight of the thermoplastic composition,
wherein the thermoplastic composition comprises from 49.5% to 67.5% of the bisphenol A homopolycarbonate by weight of the thermoplastic composition, and
wherein the composition has
(i) a notched Izod impact strength of from 193 to 206 J/m measured at 23° C. according to ASTM D256,
(ii) a tensile strength between 99 and 126 MPa as determined by ASTM D638,
(iii) a tensile modulus of from 6736 MPa to 10920 MPa as determined by ASTM D638, and
(iv) an unnotched Izod impact strength of from 706 to 797 J/m measured at 23° C. according to ASTM D256.

2. The thermoplastic composition of claim 1 , wherein the resin phase has between 3.0 wt % and 7.5 wt % by weight of siloxane.

3. The thermoplastic composition of claim 1 , wherein the bonding glass fibers comprises S-glass fibers, E-glass fibers or a combination thereof.

4. The thermoplastic composition of claim 1 , wherein the polysiloxane block copolymer contains 6% to 20% by weight of siloxane.

5. The thermoplastic composition of claim 1 , wherein the composition has from 25% to 45% glass fibers by weight, and the resin phase of the composition has between 4% and 10% by weight of siloxane.

6. The thermoplastic composition of claim 1 , wherein the elongation at break of the composition is from 2.45% to 2.65% as determined by ASTM D256.

7. The thermoplastic composition of claim 1 , wherein the melt flow rate of the composition ranges from 9.2 to 25.5 g/10 min and the density of the composition is from 1.3 to 1.5 g/cm 3 .

8. An article comprising the thermoplastic composition of claim 1 .

Assignees

• Sabic Global Technologies Bv

Inventors

• Sun Xiaoyu
• Kung Edward
• Hoover James Franklin

Classifications

• C08K7/14 Primary

  Glass · CPC title

• C08L83/10

  Block- or graft-copolymers containing polysiloxane sequences (obtained by polymerising a compound having a carbon-to-carbon double bond on to a polysiloxane C08L51/08, C08L53/00) · CPC title

• C08J5/005 Primary

  Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials · CPC title

• C08J2369/00

  Characterised by the use of polycarbonates; Derivatives of polycarbonates · CPC title

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title