Apparatus and method for manufacturing aerogel sheet

Patent metadata

Field	Value
Publication number	US-10696557-B2
Application number	US-201715736736-A
Country	US
Kind code	B2
Filing date	Feb 3, 2017
Priority date	Feb 16, 2016
Publication date	Jun 30, 2020
Grant date	Jun 30, 2020

Abstract

The present invention relates to a method for manufacturing an aerogel sheet and comprises: a step (a) of impregnating an acid solution into a fiber sheet to clean the fiber sheet by using the acid solution and impregnating a binder solution into the fiber sheet that is cleaned by using the acid solution to manufacture a pre-processed fiber sheet; a step (b) of impregnating a silica precursor into the pre-processed fiber sheet; and a step (c) of a gelling catalyst into the fiber sheet into which the silica precursor is impregnated to gelate the silica precursor.

First claim

The invention claimed is:

1. A method for manufacturing an aerogel sheet, the method comprising:
a step (a) of impregnating an acid solution into a fiber sheet to clean the fiber sheet yielding a cleaned fiber sheet, and impregnating a binder solution into the cleaned fiber sheet to manufacture a pre-processed fiber sheet, wherein an organic impregnation solution that is poly vinyl alcohol (PVA) and poly vinyl butyral (PVB) or an inorganic impregnation solution that is silica sol is used as the binder solution;
a step (b) of impregnating a silica precursor into the pre-processed fiber sheet; and
a step (c) of injecting a gelling catalyst into the fiber sheet into which the silica precursor is impregnated to gelate the silica precursor.

2. The method of claim 1 , wherein, in the step (a), the fiber sheet is cleaned by using the acid solution while being dipped into a cleaning container in which the acid solution is stored, and the pre-processed sheet is manufactured while the fiber sheet that is cleaned by using the acid solution is dipped into a binder impregnation container in which the binder solution is stored.

3. The method of claim 1 , wherein the step (a) further comprises a step of drying the fiber sheet into which the binder solution is impregnated.

4. The method of claim 1 , wherein, in the step (b), tetraethyl orthosilicate (TEOS) and ethanol are mixed to prepare the silica precursor.

5. The method of claim 4 , wherein the tetraethyl orthosilicate (TEOS) comprises hydrolyzed TEOS.

6. The method of claim 1 , wherein, in the step (c), ethanol and ammonia water (NH 4 OH) are mixed to prepare the gelling catalyst.

7. The method of claim 1 , wherein, in the step (b), the pre-processed fiber sheet is dipped into a precursor impregnation container in which the silica precursor is stored to impregnate the silica precursor into the fiber sheet.

8. The method of claim 1 , wherein the step (c) is performed within a conveyor belt that transfers the fiber sheet, in which the silica precursor is impregnated, from one side to the other side thereof.

9. The method of claim 8 , wherein the conveyor belt comprises a scraper comprising a first scraper adjusting a thickness of the silica precursor injected to the surface of the pre-processed fiber sheet and a second scraper adjusting a thickness of the gelling catalyst injected to the surface of the fiber sheet into which the silica precursor is impregnated.

10. A method for manufacturing an aerogel sheet, the method comprising:
a step (a) of impregnating an acid solution into a fiber sheet to clean the fiber sheet yielding a cleaned fiber sheet, and impregnating a binder solution into the cleaned fiber sheet to manufacture a pre-processed fiber sheet;
a step (b) of impregnating a silica precursor into the pre-processed fiber sheet; and
a step (c) of injecting a gelling catalyst into the surface of the fiber sheet, into which the silica precursor is impregnated, at a rate of 0.035 L/min to 0.012 L/min to leave the gelling catalyst for 8 minutes to 12 minutes and thereby to gelate the silica precursor.

11. A method for manufacturing an aerogel sheet, the method comprising:
a step (a) of impregnating an acid solution into a fiber sheet to clean the fiber sheet yielding a cleaned fiber sheet, and impregnating a binder solution into the cleaned fiber sheet to manufacture a pre-processed fiber sheet;
a step (b) of impregnating a silica precursor into the pre-processed fiber sheet;
a step (c) of injecting a gelling catalyst into the fiber sheet into which the silica precursor is impregnated to gelate the silica precursor; and
a step (d) of aging the fiber sheet in which the silica precursor is gelated for 50 minutes at a temperature of 70° C.

12. The method of claim 11 , wherein, in the sheet aging step (d), the fiber sheet in which the silica precursor is gelated is additionally left at room temperature for 10 minutes to perform the aging.

13. The method of claim 11 , further comprising after the step (d), a step (e) of injecting a coating solution to the aged fiber sheet to modify a surface of the fiber sheet.

14. The method of claim 13 , further comprising after the step (e), a step (f) of drying the fiber sheet of which the surface is modified.

15. The method of claim 14 , wherein the step (f) comprises a first drying step of injecting carbon dioxide at a rate of 70 L/min for ten minutes under environments of a temperature of 28° C. and a pressure of 70 bar to dry the fiber sheet of which the surface is modified, a second drying step of raising to a temperature of 50° C. for 1 hour and 20 minutes to dry the fiber sheet again, a third drying step of injecting carbon dioxide at a rate of 0.7 L/min for 20 minutes under a temperature of 50° C. and a pressure of 150 bar to dry the fiber sheet, and a fourth drying step of injecting carbon dioxide at a rate of 0.7 L/min for 20 minutes after breaking for 20 minutes to dry the fiber sheet.

16. The method of claim 15 , wherein, in the third drying step of the step (f), the ethanol generated from the fiber sheet of which the surface is modified is collected while injecting the carbon dioxide.

17. The method of claim 15 , wherein the step (f) further comprises a step of discharging the carbon dioxide for 2 hours after the fourth drying step.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Ye Hon
• Lee Je Kyun
• Oh Kyoung Shil

Classifications

• B01J31/02

  containing organic compounds or metal hydrides · CPC title

• B01J13/0091

  Preparation of aerogels, e.g. xerogels · CPC title

• B01J37/04

  Mixing {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• B65H37/00

  Article or web delivery apparatus incorporating devices for performing specified auxiliary operations (incorporating cutting or line-perforating devices B65H35/00) · CPC title

• D06M2400/02

  Treating compositions in the form of solgel or aerogel · CPC title