Method of preparing a single-phase oxide for hydrogen storage having a TiO2 crystal phase

Patent metadata

Field	Value
Publication number	US-10696548-B2
Application number	US-201816157576-A
Country	US
Kind code	B2
Filing date	Oct 11, 2018
Priority date	Mar 27, 2018
Publication date	Jun 30, 2020
Grant date	Jun 30, 2020

Abstract

Disclosed is a method of preparing an oxide for hydrogen storage, including (a) mixing and calcining vanadium oxide and titanium oxide to provide an oxide, (b) impregnating the oxide obtained in step (a) with a noble metal precursor aqueous solution, and (c) subjecting the oxide obtained in step (b) to heat treatment in a reducing atmosphere, wherein the oxide obtained in step (a) has the composition of Chemical Formula (1) below and is composed of a single-phase TiO 2 crystal phase:

V 1-x Ti x O 2 ,  Chemical Formula (1)
where 0.05≤x≤0.95.

First claim

What is claimed is:

1. A method of preparing an oxide for hydrogen storage, comprising:
(a) mixing and calcining vanadium oxide and titanium oxide to provide an oxide;
(b) impregnating the oxide obtained in step (a) with a noble metal precursor aqueous solution; and
(c) subjecting the oxide obtained in step (b) to heat treatment in a reducing atmosphere,
wherein the oxide obtained in step (a) has a composition of Chemical Formula (1) below and is composed of a single-phase TiO 2 crystal phase:
V 1-x Ti x O 2 ,  Chemical Formula (1)

where 0.05≤x≤0.95.

2. The method of claim 1 , wherein the vanadium oxide is at least one oxide selected from the group consisting of VO, VO 2 , V 2 O 3 and V 2 O 5 .

3. The method of claim 1 , wherein the calcining in step (a) is performed at a temperature ranging from 400 to 1300° C.

4. The method of claim 1 , wherein the noble metal precursor aqueous solution in step (b) includes a water-soluble salt of at least one salt selected from the group consisting of platinum, palladium and rhodium.

5. The method of claim 1 , wherein the heat treatment in step (c) is performed at a temperature ranging from 400 to 700° C.

6. The method of claim 1 , wherein the oxide for hydrogen storage is loaded with 0.1 to 2 wt % of a noble metal, after step (c).

7. The method of claim 1 , wherein the TiO 2 crystal phase has a rutile crystal structure.

8. The method of claim 1 , wherein step (a) comprises:
mixing vanadium oxide and titanium oxide and performing primary calcination in air; and
cooling the primarily calcined oxide and then performing secondary calcination in air or in a reducing atmosphere.

9. The method of claim 8 , wherein the primary calcination is performed at 400 to 700° C.

10. The method of claim 8 , wherein the secondary calcination is performed at 400 to 700° C.

Assignees

• Korea Res Inst Standards & Sci

Inventors

• Baek Seung Wook
• Kim Jung Hyun
• Ahn Chang Ho
• Kim Mee Kyung
• Park Gyo Ri
• Song Sun Woong
• Jung Ki Chae

Classifications

• C01G31/00 Primary

  Compounds of vanadium · CPC title

• C01B3/001 Primary

  characterised by the uptaking media; Treatment thereof · CPC title

• C01P2004/80

  Particles consisting of a mixture of two or more inorganic phases · CPC title

• Y02E60/32

  Hydrogen storage · CPC title

• C01P2006/40

  Electric properties · CPC title