Heat-insulating transparent polyvinyl chloride sheet having excellent weatherability and process for producing the same

Patent metadata

Field	Value
Publication number	US-10696030-B2
Application number	US-201916409198-A
Country	US
Kind code	B2
Filing date	May 10, 2019
Priority date	Aug 25, 2016
Publication date	Jun 30, 2020
Grant date	Jun 30, 2020

Abstract

A heat-insulating transparent PVC sheet is formed from a PVC substrate having a thickness of 0.02-2.0 mm and contains heat-insulation pastes evenly distributed over the PVC substrate, since the heat-insulation paste contains an essential component of wolfram cesium powder (WCs) with a chemical formula of Cs X N Y WO 3-Z Cl C and having a particle size of 0.005-2 μm, the heat-insulating transparent PVC sheet has an excellent weatherability, and particularly before and after tested in 300-hour service life in line with ASTM G-154 specification, has a physical property of weatherability decay rate (%) small than 4%.

First claim

What is claimed is:

1. A heat-insulating transparent polyvinyl chloride sheet, having a thickness of ranging from 0.02 mm to 2.0 mm, before and after tested in 300-hour service life in line with ASTM G-154 specification, having a physical property of weatherability decay rate (%) smaller than 4%, and formed from a PVC mixture including (a) 100 PHR of a polyvinyl chloride resin; (b) 0.1-60 PHR of a plasticizer; (c) 1-10 PHR of epoxidized soybean oil; (d) 0.1-10 PHR of a stabilizer; (e) 0.05-5.0 PHR of an ultraviolet absorber; (f) 0.05-0.2 PHR of a coupling agent; (g) 5.5-7.5 PHR of a heat-insulation paste; (h) 0.05-0.5 PHR of a light conversion agent; and (i) 0.01-1 PHR of an antifogging agent;
wherein the heat-insulation paste has a particle size ranged from 40 nm to 110 nm and contains the following components summed up to 100 wt %:
(g1) a wolfram cesium powder (WCs) with a chemical formula of Cs X N Y WO 3-Z Cl C of 10-18 wt %; where Cs is cesium; N is tin (Sn) or antimony (Sb) or bismuth (Bi); W is wolfram; O is oxygen; and X, Y, Z, C are all positive numbers, with the following relationship satisfied:
X≤ 1.0; Y≤ 1.0; Y/X≤ 1.0; Z≤ 0.6; and C≤ 0.1;

(g2) a dispersant of 2-5 wt %; and
(g3) a plasticizer of 77-88 wt %;
wherein the light conversion agent is europium-doped yttrium oxysulfide (Y 2 O 2 S:Eu).

2. The heat-insulating transparent polyvinyl chloride sheet as claimed in claim 1 , wherein the wolfram cesium powder (WCs) having a particle size ranged from 0.005 μm to 2 μm.

3. The heat-insulating transparent polyvinyl chloride sheet as claimed in claim 1 , wherein the plasticizer is at least one selected from the group consisting of C9-C11 dialkyl phthalate, di-isononyl phthalate (DINP), di-2-ethylhexyl phthalate (DEHP), di-butyl phthalate (DBP), di-iso-decyl phthalate (DIDP), di-2-ethylhexyl terephthalate (DOTP), di-isononyl adipate (DINA) or dioctyl adipate (DOA), tris (2-ethylhexyl) trimellitate (TOTM) 1,2-cyclohexanedicarboxylic acid diisononyl ester (DHIN) and bis(2-ethylhexyl) cyclohexane-1,2-dicarboxylate (DHEH).

4. The heat-insulating transparent polyvinyl chloride sheet as claimed in claim 1 , wherein the stabilizer is at least one selected from Ba—Zn stabilizers, Ca—Zn stabilizers or organic tin stabilizers.

5. The heat-insulating transparent polyvinyl chloride sheet as claimed in claim 1 , wherein the ultraviolet absorber is at least one selected from a hydroxy-phenyl benzotriazole ultraviolet absorber or a hydroxybenzophenone ultraviolet absorber.

6. The heat-insulating transparent polyvinyl chloride sheet as claimed in claim 1 , wherein the coupling agent is at least one selected from an organic silane compound coupling agent, an organic Zr—Al compound coupling agent or an organic titanium aluminide.

7. The heat-insulating transparent polyvinyl chloride sheet as claimed in claim 1 , wherein the dispersant is at least one selected from a polymeric co-polymer dispersant, a silicon-containing dispersant or a fluorine-containing dispersants.

8. The heat-insulating transparent polyvinyl chloride sheet as claimed in claim 1 , wherein the antifogging agent is at least one selected from glycerol fatty acid esters, sorbitol fatty acid esters, monoglyceride or ethylene oxide adduct of sorbitan monoester.

9. The heat-insulating transparent polyvinyl chloride sheet as claimed in claim 1 , wherein the sheet is produced by the following steps:
a) introducing the PVC mixture into a banbury mixer for kneading;
b) controlling the mixture temperature at 150-190° C., heating and shearing the mixture in a roller machine for well-gelation, and proceeding one of the following processes:
b1) calendering the mixture by a calender to form a heat-melting sheet having a thickness of 0.05 mm-1.0 mm, drawing water at 20˜85° C. therein for cooling, and entering step c) after dehydration;
b2) processing the mixture by a T-Die machine to form a heat-melting sheet of thickness of 0.05-2.0 mm, and entering step c) after forming; or
b3) processing the mixture by a blow-molding machine to form a heat-melting sheet of thickness of 0.02-0.8 mm, and entering step c) after forming; and
c) introducing the sheet into a cooling wheel for cooling and shaping, and then rolling up the sheet to obtain the heat-insulating transparent polyvinyl chloride sheet.

10. A multi-layered heat-insulating transparent polyvinyl chloride sheet, formed from having two or more of the heat-insulating transparent polyvinyl chloride sheets of claim 1 stacked together.

11. A complex-layered heat-insulating transparent polyvinyl chloride sheet, formed from laminating one layer of the heat-insulating transparent polyvinyl chloride sheets of claim 1 with a plastic matrix together.

Assignees

• Nanya Plastics Corp

Inventors

• Liao Te-Chao
• Huang Ying-Te
• Lai Chen-Ho
• Lin Chao-Hsien
• Yuan Ching-Yao
• Ma Teng-Ko

Classifications

• B29C49/0006

  for heating or cooling · CPC title

• B29C2049/4825

  for cooling moulds or mould parts (B29C2049/5889 takes precedence) · CPC title

• B29C49/0691

  using sheet like material, e.g. sheet blow-moulding from joined sheets · CPC title

• C08K5/12

  of cyclic polycarboxylic acids · CPC title

• B29K2027/06

  PVC, i.e. polyvinylchloride · CPC title