Lithium-air battery

Patent metadata

Field	Value
Publication number	US-10693204-B2
Application number	US-201615350258-A
Country	US
Kind code	B2
Filing date	Nov 14, 2016
Priority date	May 15, 2014
Publication date	Jun 23, 2020
Grant date	Jun 23, 2020

Abstract

A lithium-air battery is provided which includes a gas diffusion layer that is at least partially filled with air, having an electrically conducting material as a cathode, an at least partially electrolyte-impregnated filter having an electronically non-conducting material as a separator, and an anode having a lithium metal, a lithium-metal alloy or lithium-oxide-metal mixture. The separator is between the anode and the cathode and the electrolyte includes a hydrophobic, ionic liquid and a lithium salt. The three phases, gaseous air, liquid electrolyte and solid conducting material, are in contact on at least one point of the gas diffusion layer. A method for producing such battery and the use of such battery in a motor vehicle are also provided.

First claim

What is claimed is:

1. A lithium-air battery comprising:
a gas diffusing cathode consisting of a solid electronically conductive material, wherein the gas diffusing cathode is at least partially filled with gaseous air;
a separator comprising an electronically non-conductive material, wherein the separator is at least partially impregnated with a liquid electrolyte; and
an anode comprising a lithium metal, a lithium metal alloy or a lithium oxide-metal mixture,
wherein the separator is present between the cathode and the anode,
wherein the liquid electrolyte comprises a hydrophobic, ionic liquid and a lithium salt,
wherein the solid electronically conductive material comprises a woven carbon fiber fabric or a non-woven carbon fiber fabric, and
wherein on at least one point on the gas diffusing cathode, the gaseous air, the liquid electrolyte and the solid electronically conductive material are in contact.

2. The lithium-air battery according to claim 1 , wherein the liquid electrolyte comprises a quaternary ammonium cation having an asymmetric structure.

3. The lithium-air battery according to claim 2 , wherein the quaternary ammonium cation has an aryl group which is a 5 to 7 membered carbon ring.

4. The lithium-air battery according to claim 2 , wherein nitrogen of the quaternary ammonium cation binds to a methyl and a radical selected from the group consisting of (CH 2 ) n —CH 3 , (CH 2 ) n —O—CH 3 and (CH 2 —CH 2 O) n —CH 3 , wherein n=1-4.

5. The lithium-air battery according to claim 2 , wherein the quaternary ammonium cation is selected from the group consisting of N-butyl-N-methyl pyrrolidinium, N-methoxyethyl-N-methylpyrrolidinium, and mixtures thereof.

6. The lithium-air battery according to claim 1 , wherein the liquid electrolyte comprises an anion.

7. The lithium-air battery according to claim 6 , wherein the anion is fluorinated sulfonyl imides.

8. The lithium-air battery according to claim 6 , wherein the anion is bis(trifluoromethanesulfonyl)imide.

9. The lithium-air battery according to claim 1 , wherein the lithium salt comprises lithium bis(trifluoromethanesulfonyl)imide.

10. The lithium-air battery according to claim 1 , wherein a molar ratio of the lithium salt to the liquid electrolyte is from 1:2 to 1:20.

11. The lithium-air battery according to claim 1 , wherein the gas diffusing cathode is coated with conductive carbon black.

12. The lithium-air battery according to claim 1 , wherein the separator comprises a material selected from the group consisting of glass fibers, cellulose fibers and organic polymer.

13. The lithium-air battery according to claim 1 , wherein the anode comprises a foil composed of lithium metal.

14. The lithium-air battery according to claim 1 , wherein the battery is encapsulated in such a way that air can penetrate into the gas diffusing cathode.

15. A process for producing the lithium-air battery according to claim 1 , comprising:
stacking on top of one another under protective gas: the gas diffusing cathode;
the separator which is at least partially impregnated with the liquid electrolyte; and the anode, and
encapsulating the lithium-air battery so that the gaseous air can penetrate into the gas diffusing cathode.

16. A motor vehicle having the lithium-air battery according to claim 1 .

Assignees

• Bayerische Motoren Werke Ag

Inventors

• Elia Giuseppe Antonio
• Hassoun Jusef
• Mueller Franziska
• Bresser Dominic
• Sun Yang-Kook
• Passerini Stefano
• Scrosati Bruno

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M12/08 Primary

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title

• H01M2300/0045

  Room temperature molten salts comprising at least one organic ion · CPC title

• H01M2220/20

  Batteries in motive systems, e.g. vehicle, ship, plane · CPC title

• H01M10/0566

  Liquid materials · CPC title