Redox and ion-adsorption electrodes and energy storage devices

Patent metadata

Field	Value
Publication number	US-10693126-B2
Application number	US-201816218663-A
Country	US
Kind code	B2
Filing date	Dec 13, 2018
Priority date	Feb 1, 2018
Publication date	Jun 23, 2020
Grant date	Jun 23, 2020

Abstract

Provided herein are energy storage devices comprising a first electrode comprising a layered double hydroxide, a conductive scaffold, and a first current collector; a second electrode comprising a hydroxide and a second current collector; a separator; and an electrolyte. In some embodiments, the specific combination of device chemistry, active materials, and electrolytes described herein form storage devices that operate at high voltage and exhibit the capacity of a battery and the power performance of supercapacitors in one device.

First claim

What is claimed is:

1. A method of forming an electrode, the method comprising:
forming a current collector by treating a three-dimensional graphene-based conductive scaffold in an acid;
washing the current collector in a solvent comprising deionized water, acetone, water, or any combination thereof; and
depositing a layered double hydroxide onto the current collector to form an electrode;
wherein the layered double hydroxide comprises a metallic layered double hydroxide.

2. The method of claim 1 , wherein the metallic layered double hydroxide comprises a zinc-based layered double hydroxide, an iron-based layered double hydroxide, an aluminum-based layered double hydroxide, a chromium-based layered double hydroxide, an indium-based layered double hydroxide, a manganese-based layered double hydroxide, or any combination thereof.

3. The method of claim 2 , wherein the zinc-based layered double hydroxide comprises a zinc-bismuth layered double hydroxide.

4. The method of claim 1 , wherein the three-dimensional graphene-based conductive scaffold comprises conductive foam, graphene aerogel, amorphous carbon foam, thin-layer graphite foam, carbon nanotubes, carbon nanosheets, or any combination thereof.

5. The method of claim 1 , wherein the three-dimensional graphene-based conductive scaffold comprises aluminum foam, copper foam, nickel foam, palladium foam, platinum foam, steel foam, or any combination thereof.

6. The method of claim 1 , wherein the acid has a concentration of about 1 M to about 6 M.

7. The method of claim 1 , wherein depositing the layered double hydroxide onto the current collector comprises electrochemical deposition, electrocoating, electrophoretic deposition, microwave synthesis, photothermal deposition, thermal decomposition laser deposition, hydrothermal synthesis, or any combination thereof.

8. The method of claim 7 , wherein the electrochemical deposition comprises applying a constant voltage to the current collector.

9. The method of claim 8 , wherein the constant voltage is about −2.4 V to about −0.3 V.

10. The method of claim 7 , wherein the electrochemical deposition comprises cyclic voltammetry.

11. The method of claim 10 , wherein the cyclic voltammetry comprises applying consecutive potential sweeps to the current collector.

12. The method of claim 11 , wherein the consecutive potential sweeps comprise applying a voltage of about −0.3 V to about −2.4 V at a scan rate of about 50 mV/s to about 175 mV/s to the electrode.

13. The method of claim 11 , wherein applying consecutive potential sweeps to the current collector occurs in a catalyst.

14. The method of claim 13 , wherein the catalyst has a concentration of about 50 mM to about 200 mM.

15. The method of claim 7 , wherein the hydrothermal synthesis comprises submerging the current collector in an aqueous solution.

16. The method of claim 15 , wherein the aqueous solution comprises an acetate, a chloride, a nitrate salt, a reducing agent, or any combination thereof.

17. The method of claim 16 , wherein the acetate comprises, aluminum acetate, aluminum acetotartrate, aluminum diacetate, aluminum sulfacetate, aluminum triacetate, ammonium acetate, antimony(III) acetate, barium acetate, basic beryllium acetate, bismuth(III) acetate, cadmium acetate, cesium acetate, calcium acetate, calcium magnesium acetate, camostat, chromium acetate hydroxide, chromium(II) acetate, clidinium bromide, cobalt(II) acetate, copper(II) acetate, Dess-Martin periodinane (diacetoxyiodo) benzene, iron(II) acetate, iron(III) acetate, lead(II) acetate, lead(IV) acetate, lithium acetate, magnesium acetate, manganese(II) acetate, manganese(III) acetate, mercury(II) acetate, methoxyethylmercuric acetate, molybdenum(II) acetate, nexeridine, nickel(II) acetate, palladium(II) acetate, paris green, platinum(II) acetate, potassium acetate, propanidid, rhodium(II) acetate, satraplatin, silver acetate, sodium acetate, sodium chloroacetate, sodium diacetate, sodium triacetoxyborohydride, thallous acetate, tilapertin, triamcinolone hexacetonide, triethylammonium acetate, uranyl acetate, uranyl zinc acetate, white catalyst, zinc acetate, or any combination thereof.

18. The method of claim 17 , wherein the acetate consists of bismuth(III) acetate.

19. The method of claim 1 , wherein the three-dimensional graphene-based conductive scaffold is treated for a period of time of about 1 minute to about 30 minutes.

20. The method of claim 1 , wherein depositing the layered double hydroxide onto the current collector comprises electrochemical deposition of the layered double hydroxide onto the current collector.

Assignees

• Univ California

Inventors

• El-Kady Maher F
• Kaner Richard B
• Mousavi Mir Fazlollah

Classifications

• Y02P70/50

  Manufacturing or production processes characterised by the final manufactured product · CPC title

• H01G11/46

  Metal oxides · CPC title

• H01G11/28

  arranged or disposed on a current collector; Layers or phases between electrodes and current collectors, e.g. adhesives · CPC title

• H01G11/50

  specially adapted for lithium-ion capacitors, e.g. for lithium-doping or for intercalation · CPC title

• H01M4/521

  of iron for aqueous cells · CPC title