Conductive carbon powder, a method for the manufacturing thereof and use thereof

Patent metadata

Field	Value
Publication number	US-10689256-B2
Application number	US-201715855388-A
Country	US
Kind code	B2
Filing date	Dec 27, 2017
Priority date	Dec 23, 2013
Publication date	Jun 23, 2020
Grant date	Jun 23, 2020

Abstract

The present invention relates to a conductive carbon powder emanating essentially from lignin, a method for the manufacturing thereof and use thereof. Said powder may emanate from an electrically conductive carbon intermediate product, in turn emanating essentially from lignin. Further, uses thereof and compositions comprising said carbon powder are disclosed. Additionally methods for manufacturing said conductive carbon powder, also involving an electrically conductive carbon intermediate product emanating essentially from lignin, are disclosed together with a method for making said compositions.

First claim

The invention claimed is:

1. A method for manufacturing an electrically conductive carbon powder comprising:
i) providing a lignin and at least one additive,
ii) mixing the lignin and the at least one additive to form a mixture,
iii) shaping the mixture to form a shaped body,
iv) performing a thermal treatment of the shaped body in which a first step of the thermal treatment comprises a temperature ramp from room temperature to a temperature of up to 300° C. or less and in which a last step of the thermal treatment comprises a temperature ramp from room temperature to a temperature of up to about 2000° C. or less in an inert atmosphere to provide a conductive carbonized intermediate product, and
v) pulverizing the conductive carbonized intermediate product to provide a conductive carbon powder.

2. A method according to claim 1 wherein the at least one additive comprises a plasticizer, a reactive agent that renders the lignin melt extrudable, an aliphatic acid, a lignin solvent, an aprotic polar solvent, an aliphatic amide, dimethylformamide (DMF), dimethylacetamide (DMAc), a tertiary amine oxide, N-methylmorpholine-N-oxide (NMMO), dimethylsulfoxide (DMSO), ethylene glycol, di-ethylene glycol, a low-molecular-weight poly ethylene glycol (PEG) having a molecular weight between 150 to 20,000 g/mol, ionic liquids, or combinations thereof.

3. A method according to claim 1 wherein the at least one additive is a poly ethylene glycol.

4. A method according to claim 1 wherein the temperature ramp of the last step is from room temperature up to the temperature of about 1600° C. or less.

5. A method according to claim 1 wherein the temperature ramp of the last step is from room temperature up to the temperature of about 1400° C. or less.

6. A method according to claim 1 wherein the first step takes place in air.

7. A method for manufacturing a conductive carbon powder comprising the following steps:
a) thermal treatment of a lignin comprising compound to increase the carbon content to at least 80% to obtain an electrically conductive carbonized lignin intermediate product wherein a first step of the thermal treatment comprises a temperature ramp from room temperature to a temperature of up to 300° C. or less; and
b) mechanical treatment of the electrically conductive carbonized lignin intermediate product to obtain a carbonized lignin powder which is electrically conductive.

8. A method according to claim 7 wherein a last step of the thermal treatment comprises a temperature ramp from room temperature to a temperature of up to about 2000° C. or less in an inert atmosphere.

9. A method according to claim 7 wherein a last step of the thermal treatment comprises a temperature ramp from room temperature to a temperature of up to about 1600° C. or less.

10. A method according to claim 7 wherein a last step of the thermal treatment comprises a temperature ramp from room temperature to a temperature of up to about 1400° C. or less.

11. A method according to claim 7 wherein the lignin comprising compound comprises lignin and at least one additive.

12. A method according to claim 7 wherein the at least one additive comprises a plasticizer, a reactive agent that renders the lignin melt extrudable, an aliphatic acid, a lignin solvent, an aprotic polar solvent, an aliphatic amide, dimethylformamide (DMF), dimethylacetamide (DMAc), a tertiary amine oxide, N-methylmorpholine-N-oxide (NMMO), dimethylsulfoxide (DMSO), ethylene glycol, di-ethylene glycol, a low-molecular-weight poly ethylene glycol (PEG) having a molecular weight between 150 to 20,000 g/mol, ionic liquids, or combinations thereof.

13. A method according to claim 7 wherein the at least one additive is a poly ethylene glycol.

14. A method according to claim 7 wherein the mechanical treatment comprises pulverizing the electrically conductive carbonized lignin intermediate product.

15. A method according to claim 7 wherein the first step takes place in air.

16. A method for manufacturing a carbonized intermediate product in filament form, comprising:
providing a lignin and at least one additive,
mixing the lignin and the at least one additive to form a mixture,
melt spinning the mixture to a monofilament or multifilament bundle component,
performing a thermal treatment of monofilament or multifilament bundle in which a first step of the thermal treatment comprises a temperature ramp from room temperature to a temperature of up to 300° C. or less and a last step comprises a temperature ramp from room temperature to a temperature of up to about 2000° C. or less in an inert atmosphere to provide a conductive carbonized intermediate product in filament form.

17. A method according to claim 16 wherein the at least one additive comprises a plasticizer, a reactive agent that renders the lignin melt extrudable, an aliphatic acid, a lignin solvent, a aprotic polar solvent, an aliphatic amide, dimethylformamide (DMF), dimethylacetamide (DMAc), a tertiary amine oxide, N-methylmorpholine-N-oxide (NMMO), dimethylsulfoxide (DMSO), ethylene glycol, di-ethylene glycol, a low-molecular-weight poly ethylene glycol (PEG) having a molecular weight between 150 to 20,000 g/mol, ionic liquids, or combinations thereof.

18. A method according to claim 16 wherein the at least one additive is a poly ethylene glycol.

19. A method according to claim 16 wherein the temperature ramp of the last step is from room temperature up to the temperature of about 1600° C. or less.

20. A method according to claim 16 wherein the first step takes place in air.

Assignees

• Stora Enso Oyj

Inventors

• Garoff Niklas
• Walter Stephan
• Seide Gunnar
• Gries Thomas
• Steinmann Wilhelm
• De Palmenaer Andreas

Classifications

• C08L97/005

  Lignin · CPC title

• C07G1/00 Primary

  Low-molecular-weight derivatives of lignin (high-molecular-weight derivatives of lignin {C08H6/00}) · CPC title

• D01F1/10

  Other agents for modifying properties · CPC title

• C08K7/06

  Elements · CPC title

• H01B1/04

  mainly consisting of carbon-silicon compounds, carbon or silicon · CPC title