Materials, methods, and devices for siloxane contaminant removal

Patent metadata

Field	Value
Publication number	US-10688433-B2
Application number	US-201816179145-A
Country	US
Kind code	B2
Filing date	Nov 2, 2018
Priority date	May 7, 2012
Publication date	Jun 23, 2020
Grant date	Jun 23, 2020

Abstract

Adsorbent materials are disclosed, along with filter elements containing the adsorbent materials methods of using adsorbents to remove siloxane contaminants from a gas stream. The method includes providing an adsorbent material that has been washed with an acid and passing a gas through the adsorbent material so as to reduce siloxane levels in the gas. A filter element for reducing siloxane levels in a gas includes a first adsorbent material, the first adsorbent material comprising an acid-washed adsorbent; and a second adsorbent material, the second adsorbent material comprising an acid-impregnated adsorbent.

First claim

We claim:

1. A method of filtering a gas comprising siloxane and ammonia, the method comprising:
providing a filter element comprising:
a first adsorbent material, the first adsorbent material comprising an acid gas remover;
a second adsorbent material, wherein the second adsorbent material is impregnated with a strong acid;
a third adsorbent material, wherein the third adsorbent material has been acid-washed; and

passing the gas through the filter element to reduce siloxane and ammonia levels in the gas, wherein the gas passes sequentially through the first adsorbent material, then the second adsorbent material, and then the third adsorbent material.

2. The method of claim 1 , wherein each adsorbent material comprises activated carbon, silica gel, activated alumina, zeolites, or a nanoporous support, or a combination thereof.

3. The method of claim 1 , wherein the pH of the third adsorbent material is from 3 to 7.

4. The method of claim 1 , wherein the third adsorbent material comprises an activated carbon that has been acid-washed with nitric acid.

5. The method of claim 1 , wherein the strong acid comprises phosphoric acid, nitric acid, sulfuric acid, malonic acid, or citric acid, or a combination thereof.

6. The method of claim 1 , wherein the filter element further comprises a fourth adsorbent material, wherein the fourth adsorbent material is impregnated with a strong acid, and wherein the gas passes through the first adsorbent material, the second adsorbent material, and the third adsorbent material and then subsequently passes through the fourth adsorbent material.

7. The method of claim 6 , wherein the fourth adsorbent material comprises activated carbon, silica gel, activated alumina, zeolites, or a nanoporous support, or a combination thereof.

8. The method of claim 1 , wherein the acid gas remover comprises at least one of potassium iodide (KI), potassium carbonate (K 2 CO 3 ), and sodium hydroxide (NaOH).

9. The method of claim 1 , wherein the acid gas remover comprises potassium iodide (KI) and sodium hydroxide (NaOH).

10. A method of filtering a gas comprising siloxane and ammonia, the method comprising:
providing a filter element comprising:
a first adsorbent material, wherein the first adsorbent material is impregnated with potassium iodide (KI) and sodium hydroxide (NaOH);
a second adsorbent material, wherein the second adsorbent material is impregnated with a strong acid;
a third adsorbent material, wherein the third adsorbent material has been acid-washed; and
a fourth adsorbent material, wherein the fourth adsorbent material is impregnated with a strong acid; and

passing the gas through the filter element to reduce siloxane and ammonia levels in the gas, wherein the gas passes sequentially through the first filter element, then the second filter element, then the third filter element, and then the fourth filter element.

11. The method of claim 10 , wherein each adsorbent material comprises activated carbon, silica gel, activated alumina, zeolites, or a nanoporous support, or a combination thereof, and wherein the strong acid comprises phosphoric acid, nitric acid, sulfuric acid, malonic acid, or citric acid, or a combination thereof.

12. The method of claim 10 , wherein the pH of the third adsorbent material is from 3 to 7.

13. The method of claim 10 , wherein the third adsorbent material comprises an activated carbon that has been acid-washed with nitric acid.

Assignees

• Donaldson Co Inc

Inventors

• Hoang Brian N
• Weineck Gerald
• Viswanathan Karthik
• Dallas Andrew J

Classifications

• B01D2253/25

  Coated, impregnated or composite adsorbents · CPC title

• B01D2257/553

  Compounds comprising hydrogen, e.g. silanes · CPC title

• B01D53/025

  with wetted adsorbents; Chromatography (analytical chromatography G01N30/00 - G01N30/96; for liquids B01D15/08) · CPC title

• B01D53/02 Primary

  by adsorption, e.g. preparative gas chromatography {(solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01)} · CPC title

• B01D2258/06

  Polluted air · CPC title