Solid-state battery positive electrode material, production method for solid-state battery positive electrode material, all-solid-state lithium-sulfur battery using solid-state battery positive electrode material, and production method for all-solid-state lithium-sulfur battery using solid-state battery positive electrode material

Patent metadata

Field	Value
Publication number	US-10686186-B2
Application number	US-201716082413-A
Country	US
Kind code	B2
Filing date	Mar 9, 2017
Priority date	Mar 11, 2016
Publication date	Jun 16, 2020
Grant date	Jun 16, 2020

Abstract

(Problem to be Solved)
The present application is to provide: a positive electrode material for producing a lithium-sulfur solid-state battery that does not experience degradation of battery performance from charging/discharging cycling, does not present the fire risk of liquid electrolytes, and thereby makes battery performance compatible with safety; an all-solid-state lithium-sulfur battery that uses the positive electrode material; and a production method.
(Means for Solution)
The present application relate to a lithium-sulfur solid-state battery positive electrode material that contains: sulfur; a conductive material; a binder; and an ionic liquid or a solvate ionic liquid, and an all-solid-state lithium-sulfur battery that includes: a positive electrode that comprises the positive electrode material; a negative electrode; and an oxide solid electrolyte. The positive electrode material is manufactured by means of a method wherein a slurry obtained by adding an organic solvent to the sulfur, the conductive material, the binder, and the ionic liquid or solvate ionic liquid is applied to one surface of an oxide solid electrolyte formation body and dried to remove the organic solvent.

First claim

The invention claimed is:

1. A solid-state lithium-sulfur battery positive electrode material comprising
sulfur, a conductive material,
a binder, and
an ionic liquid or a solvated ionic liquid,
wherein a percentage of each component in the positive electrode material is 45 to 60% by mass, 20 to 35% by mass, 0.1 to 10% by mass, and 10 to 20% by mass for the sulfur, the conductive material, the binder, and the ionic liquid or the solvated ionic liquid, respectively.

2. The solid-state lithium-sulfur battery positive electrode material according to claim 1 , wherein the ionic liquid contains a lithium salt.

3. The solid-state lithium-sulfur battery positive electrode material according to claim 1 , wherein the solvated ionic liquid comprises a lithium salt and glyme.

4. The solid-state lithium-sulfur battery positive electrode material according to claim 3 , wherein the lithium salt is at least one selected from lithium-bis(fluorosulfonyl)imide and lithium-bis(trifluoromethane sulfonyl)imide, and the glyme is at least one selected from triglyme and tetraglyme.

5. The solid-state lithium-sulfur battery positive electrode material according to claim 1 , wherein the conductive material is conductive carbon black.

6. The solid-state lithium-sulfur battery positive electrode material according to claim 1 , wherein the binder is polyvinylidene fluoride.

Assignees

• Tokyo Electric Power Co Holdings Inc
• Univ Tokyo Metropolitan

Inventors

• Michibata Hideo
• Kanamura Kiyoshi
• SHOJI Mao

Classifications

• Y02P70/50

  Manufacturing or production processes characterised by the final manufactured product · CPC title

• H01M10/052 Primary

  Li-accumulators · CPC title

• H01M4/13 Primary

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/623

  fluorinated polymers · CPC title