Separator having a polysulfide barrier layer for lithium-sulfur cells

US10686176B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-10686176-B2
Application numberUS-201214364402-A
CountryUS
Kind codeB2
Filing dateNov 15, 2012
Priority dateDec 16, 2011
Publication dateJun 16, 2020
Grant dateJun 16, 2020

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  1. Title

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  2. Abstract

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  5. First independent claim

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Abstract

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A lithium-sulfur cell includes a lithium-containing anode, a sulfur-containing cathode and a separator arranged between the lithium-containing anode and the sulfur-containing cathode. To suppress a shuttle mechanism and to prevent a loss of active material, the separator includes a base layer and a polysulfide barrier layer. The polysulfide barrier layer is formed on the cathode side of the separator.

First claim

Opening claim text (preview).

The invention claimed is: 1. A lithium-sulfur cell, comprising: a lithium-containing anode; a sulfur-containing cathode; and a separator arranged between the lithium-containing anode and the sulfur-containing cathode, wherein the separator includes a base layer and a polysulfide barrier layer including at least one polymer having polysulfide affinity which forms a reversible ionic bond with a polysulfide and at least one polyolefin-polyether copolymer, the polysulfide barrier layer formed on a side of the separator facing the sulfur-containing cathode. 2. The lithium-sulfur cell of claim 1 , wherein the polysulfide barrier layer includes a mixture of the at least one polymer having polysulfide affinity and at least one polysulfide-tight material. 3. A lithium-sulfur cell, comprising: a lithium-containing anode; a sulfur-containing cathode; and a separator arranged between the lithium-containing anode and the sulfur-containing cathode, the separator including a base layer and a polysulfide barrier layer, the polysulfide barrier layer formed on a side of the separator facing the sulfur-containing cathode from a mixture of at least one polymer having polysulfide affinity and at least one polysulfide-tight material, wherein the polysulfide barrier layer includes at least one polyolefin-polyether copolymer, the polysulfide barrier layer is formed on a side of the separator facing the sulfur-containing cathode, and during a synthesis of the mixture of at least one polymer having polysulfide affinity and at least one polysulfide-tight material, ceramic particles are inserted into a reaction product of the synthesis.

Assignees

Inventors

Classifications

  • H01M4/581Primary

    Chalcogenides or intercalation compounds thereof · CPC title

  • comprising layers of only organic material and layers containing inorganic material · CPC title

  • Ceramics · CPC title

  • Polyolefins · CPC title

  • having a layered structure · CPC title

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What does patent US10686176B2 cover?
A lithium-sulfur cell includes a lithium-containing anode, a sulfur-containing cathode and a separator arranged between the lithium-containing anode and the sulfur-containing cathode. To suppress a shuttle mechanism and to prevent a loss of active material, the separator includes a base layer and a polysulfide barrier layer. The polysulfide barrier layer is formed on the cathode side of the sep…
Who is the assignee on this patent?
Bosch Gmbh Robert
What technology area does this patent fall under?
Primary CPC classification H01M4/581. Mapped technology areas include Electricity.
When was this patent published?
Publication date Tue Jun 16 2020 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 2 related publications on this page (citations in our corpus or others sharing the same primary CPC).