Modified atmosphere melt infiltration

Patent metadata

Field	Value
Publication number	US-10683764-B2
Application number	US-201815896557-A
Country	US
Kind code	B2
Filing date	Feb 14, 2018
Priority date	Feb 11, 2015
Publication date	Jun 16, 2020
Grant date	Jun 16, 2020

Abstract

A ceramic matrix composite component for use in a gas turbine engine and method for making the same are described herein. The component includes a body and an outer region. The body includes a silicon containing ceramic composite. The outer region is on an outer surface of the body.

First claim

What is claimed is:

1. A method comprising:
melt infiltrating a silicon metal or alloy into a ceramic preform to form a body;
cooling the body after the melt infiltrating;
adding hydrocarbon gas to an atmosphere in contact with the body during at least a portion of the melt infiltrating, the cooling or any combination thereof; and
chemically reacting the hydrocarbon gas with silicon in the body to form silicon carbide on an outer region of the body, wherein the silicon carbide comprises whiskers.

2. The method of claim 1 , further comprising wetting a silicon metal or alloy, formed from silicon of the body, to the whiskers to form the outer region, wherein the outer region has a silicon concentration greater than a silicon concentration of the body.

3. The method of claim 1 , wherein the hydrocarbon gas is selected from the group consisting of methane, propane, or a combination thereof.

4. The method of claim 3 , further comprising adding hydrogen gas to the step of adding hydrocarbon gas, wherein a ratio of hydrocarbon gas to hydrogen gas is between about 4:1 and about 1:20.

5. The method of claim 1 , further comprising depositing an environmental barrier coating along an external surface of the outer region.

6. The method of claim 5 , further comprising depositing a porous abradable on the environmental barrier coating such that the environmental barrier coating is sandwiched between the outer region and the porous abradable.

7. The method of claim 1 , further comprising adding a catalyst comprising nickel, molybdenum, cobalt, or any combination thereof to the silicon metal or alloy during the step of melt infiltration.

8. A method comprising:
melt infiltrating a silicon metal or alloy into a ceramic preform in the presence of a hydrocarbon gas in contact with the ceramic preform to form a body;
chemically reacting the hydrocarbon gas with silicon in the body to form silicon carbide on an outer region of the body;
wetting a silicon metal or alloy, formed from silicon of the body, to the silicon carbide to form the outer region, wherein the outer region has a silicon concentration greater than a silicon concentration of the body; and
cooling the body.

9. The method of claim 8 , wherein the silicon carbide on the outer region of the body comprises whiskers.

10. The method of claim 8 , wherein the hydrocarbon gas is selected from the group consisting of methane, propane, or a combination thereof.

11. The method of claim 10 , further comprising adding hydrogen gas to the step of adding hydrocarbon gas, wherein a ratio of hydrocarbon gas to hydrogen gas is between about 4:1 and about 1:20.

12. The method of claim 8 , further comprising adding a catalyst comprising nickel, molybdenum, cobalt, or any combination thereof to the silicon metal or alloy during the step of melt infiltration.

13. A method comprising:
melt infiltrating a silicon metal or alloy into a ceramic preform to form a body;
cooling the body in the presence of a hydrocarbon gas in contact with the ceramic preform;
chemically reacting the hydrocarbon gas with silicon in the body to form silicon carbide on an outer region of the body; and
wetting a silicon metal or alloy, formed from silicon of the body, to the silicon carbide to form the outer region, wherein the outer region has a silicon concentration greater than a silicon concentration of the body.

14. The method of claim 13 , wherein the silicon carbide on the outer region of the body comprises whiskers.

15. The method of claim 13 , wherein the hydrocarbon gas is selected from the group consisting of methane, propane, or a combination thereof.

16. The method of claim 15 , further comprising adding hydrogen gas to the step of adding hydrocarbon gas, wherein a ratio of hydrocarbon gas to hydrogen gas is between about 4:1 and about 1:20.

17. The method of claim 13 , further comprising adding a catalyst comprising nickel, molybdenum, cobalt, or any combination thereof to the silicon metal or alloy during the step of melt infiltration.

Assignees

• Rolls Royce High Temperature Composites Inc
• Rolls Royce Corp

Inventors

• Harris Stephen I
• Shinavski Robert J
• Kidd Richard W
• Shim Sungbo
• Lee Kang N

Classifications

• C04B35/80

  Fibres, filaments, whiskers, platelets, or the like · CPC title

• F01D11/122

  with erodable or abradable material (blades having cutting or grinding tips F01D5/20) · CPC title

• C04B41/52

  Multiple coating or impregnating {multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation} · CPC title

• F01D5/288

  Protective coatings for blades · CPC title

• C04B2235/614

  Gas infiltration of green bodies or pre-forms · CPC title