Liquid-phase hydroisomerization system and process therefor and use thereof

Patent metadata

Field	Value
Publication number	US-10683459-B2
Application number	US-201615748851-A
Country	US
Kind code	B2
Filing date	Jun 8, 2016
Priority date	Dec 18, 2015
Publication date	Jun 16, 2020
Grant date	Jun 16, 2020

Abstract

Provided are a liquid-phase hydroisomerization system and a process therefor and use thereof. The system comprises a gas-liquid mixer ( 3 ), a hydroisomerization reactor ( 4 ) and a fractionating column ( 6 ). An oil product and hydrogen are mixed as a liquid hydrogen-oil mixture, and are introduced into the hydroisomerization reactor for a hydroisomerization reaction, and after being fractionated, a target product is led out. A supplemental hydrogen-dissolving inner member is provided at least between a group of two adjacent catalyst bed layers in order to supplement hydrogen to the reactants. The process cancels a circulating hydrogen compressor, has a simple process flow, and can be applied to the production of a lubricant base oil by the hydroisomerization of a lubricant raw material or the production of a low freezing point diesel by the hydroisomerization of and the reduction in the freezing point of a diesel raw material.

First claim

The invention claimed is:

1. A liquid-phase hydroisomerization system, comprising:
a hydrogen-dissolving unit, a hydroisomerization reactor, and a fractionating column;
wherein the hydrogen-dissolving unit comprises an oil feed line, a hydrogen feed line and a hydrogen-oil-mixture line, the hydrogen-oil-mixture line is in communication with the bottom of the hydroisomerization reactor, and the top of the hydroisomerization reactor is in communication with the fractionating column;
the hydroisomerization reactor includes at least two catalyst beds, and an internal dissolved-hydrogen replenishment member is provided between at least one pair of two adjacent catalyst beds;
the internal dissolved-hydrogen replenishment member comprises a bottom sieve separating plate, a middle mixing space and a top separating plate, the top separating plate is provided with multiple liquid discharging pipes, and the middle mixing space is provided with a hydrogen inlet and a hydrogen outlet; hydrogen and oil are mixed in the middle mixing space, the liquid phase in which the hydrogen is dissolved is discharged through the liquid discharging pipes, and undissolved hydrogen gas is discharged through the hydrogen outlet.

2. The liquid-phase hydroisomerization system according to claim 1 , wherein the fractionating column comprises at least one cut fraction line in communication with the oil feed line.

3. The liquid-phase hydroisomerization system according to claim 1 , wherein in the hydroisomerization reactor, there are 2 to 5 catalyst beds.

4. The liquid-phase hydroisomerization system according to claim 1 , wherein the system further comprises a hydrofining reactor, provided before or after the hydroisomerization reactor;
if the hydrofining reactor is provided before the hydroisomerization reactor, the hydrogen-oil-mixture line is in communication with the bottom of the hydrofining reactor, the top of the hydrofining reactor is in communication with the bottom of the hydroisomerization reactor, and the top of the hydroisomerization reactor is in communication with the fractionating column;
if the hydrofining reactor is provided after the hydroisomerization reactor, the hydrogen-oil-mixture line is in communication with the bottom of the hydroisomerization reactor, the top of the hydroisomerization reactor is in communication with the bottom of the hydrofining reactor, the top of the hydrofining reactor is in communication with the fractionating column.

5. The liquid-phase hydroisomerization system according to claim 4 , wherein the hydrofining reactor comprises at least two catalyst beds, and an internal dissolved-hydrogen replenishment member is provided between two adjacent catalyst beds.

6. The liquid-phase hydroisomerization system according to claim 5 , wherein in the hydrofining reactor, there are 2 to 5 catalyst beds.

7. A liquid-phase hydroisomerization process using the system according to claim 1 , wherein the process comprises:
1) mixing oil and hydrogen in a hydrogen-dissolving unit to obtain a liquid mixture of hydrogen and oil;
2) feeding the mixture of hydrogen and oil to a subsequent hydroisomerization reactor and/or a hydrofining reactor to allow for a hydroisomerization reaction and/or a hydrofining reaction; and
3) feeding the resultant obtained in 2) to a fractionating column for fractionation, and obtaining a fractionated target product.

8. The process according to claim 7 , wherein the oil is an oil fraction having a distillation range of 65° C. to 550° C.

9. The process according to claim 8 , wherein the oil fraction includes one of, or a combination of more of, a hydrocracking tail oil, a catalytic diesel oil, a coking diesel oil, a straight-run diesel oil, a straight-run wax oil, a low-pressure oil fraction, a coking wax oil, a deasphalted oil and a synthetic oil.

10. The process according to claim 9 , wherein the oil fraction is a hydrocracking tail oil.

11. The process according to claim 7 , wherein the hydrogen dissolved in the mixture of hydrogen and oil is in a saturated state or a supersaturated state.

12. The process according to claim 7 , wherein the conditions of the hydroisomerization reaction are: a reaction pressure of 6.0 MPa to 16.0 MPa, a reaction temperature of 320° C. to 395° C., and a volume space velocity of 0.2 h −1 to 2.0 h −1 ; and
the conditions of the hydrofining reaction are: a reaction pressure of 6.0 MPa to 16.0 MPa, a reaction temperature of 220° C. to 385° C., and a volume space velocity of 0.2 h −1 to 3.0 h −1 .

13. The process according to claim 7 , wherein the process further comprises introducing one or more fractions obtained after the fractionation other than the target product into the oil.

14. The liquid-phase hydroisomerization system according to claim 2 , wherein the system further comprises a hydrofining reactor, provided before or after the hydroisomerization reactor;
if the hydrofining reactor is provided before the hydroisomerization reactor, the hydrogen-oil-mixture line is in communication with the bottom of the hydrofining reactor, the top of the hydrofining reactor is in communication with the bottom of the hydroisomerization reactor, and the top of the hydroisomerization reactor is in communication with the fractionating column;
if the hydrofining reactor is provided after the hydroisomerization reactor, the hydrogen-oil-mixture line is in communication with the bottom of the hydroisomerization reactor, the top of the hydroisomerization reactor is in communication with the bottom of the hydrofining reactor, the top of the hydrofining reactor is in communication with the fractionating column.

15. The liquid-phase hydroisomerization system according to claim 3 , wherein the system further comprises a hydrofining reactor, provided before or after the hydroisomerization reactor;
if the hydrofining reactor is provided before the hydroisomerization reactor, the hydrogen-oil-mixture line is in communication with the bottom of the hydrofining reactor, the top of the hydrofining reactor is in communication with the bottom of the hydroisomerization reactor, and the top of the hydroisomerization reactor is in communication with the fractionating column;
if the hydrofining reactor is provided after the hydroisomerization reactor, the hydrogen-oil-mixture line is in communication with the bottom of the hydroisomerization reactor, the top of the hydroisomerization reactor is in communication with the bottom of the hydrofining reactor, the top of the hydrofining reactor is in communication with the fractionating column.

16. The liquid-phase hydroisomerization system according to claim 14 , wherein the hydrofining reactor comprises at least two catalyst beds, and an internal dissolved-hydrogen replenishment member is provided between two adjacent catalyst beds.

17. The liquid-phase hydroisomerization system according to claim 16 , wherein in the hydrofining reactor, there are 2 to 5 catalyst beds.

18. The liquid-phase hydroisomerization system according to claim 15 , wherein the hydrofining reactor comprises at least two catalyst beds, and an internal dissolved-hydrogen replenishment member is provided between two adjacent catalyst beds.

19. The liquid-phase hydroisomerization system according to claim 18 , wherein in the hydrofining reactor, there are 2 to 5 catalyst beds.

Assignees

• Petrochina Co Ltd

Inventors

• Ma Shoutao
• Huang Xiaoqiao
• Sun Famin
• Ma Qingfeng
• Xie Fangming
• Duan Yongsheng
• Wu Xianjun
• Li Fengxuan
• Ge Dongmei
• Xia Endong
• Li Ruifeng
• Ji Ronglei
• Liu Liying
• Qin Lihong
• Meng Xiangbin
• Dong Chunming
• Lu Xuefeng
• Wang Rui
• Xu Tiegang
• Ni Shurong

Classifications

• Y02P30/20

  using bio-feedstock · CPC title

• C10M101/02

  Petroleum fractions · CPC title

• C10G45/72

  Controlling or regulating · CPC title

• C10G2300/1011

  Biomass · CPC title

• C10G67/02 Primary

  plural serial stages only · CPC title