Electrode material, electrode of redox flow battery, and redox flow battery

Patent metadata

Field	Value
Publication number	US-10680248-B2
Application number	US-201615563013-A
Country	US
Kind code	B2
Filing date	Apr 1, 2016
Priority date	Apr 1, 2015
Publication date	Jun 9, 2020
Grant date	Jun 9, 2020

Abstract

An electrode material including a conductive sheet containing carbon nanotubes having an average fiber diameter of 1 μm or less; a liquid inflow member that is formed on a first surface of the conductive sheet such that an electrolyte solution that is passed therethrough flows into the conductive sheet; and a liquid outflow member that is formed on a second surface of the conductive sheet and out of which flows the electrolyte solution that has passed through the conductive sheet; wherein, when using a sheet surface of the conductive sheet as a reference plane, the Darcy permeability, in an in-plane direction, inside the liquid inflow member, is at least 100 times the Darcy permeability, in a normal direction, through the conductive sheet.

First claim

The invention claimed is:

1. An electrode material comprising:
a conductive sheet containing carbon nanotubes having an average fiber diameter of 1 μm or less;
a liquid inflow member that is formed on a first surface of the conductive sheet such that an electrolyte solution that is passed therethrough flows into the conductive sheet; and
a liquid outflow member that is formed on a second surface of the conductive sheet and out of which flows the electrolyte solution that has passed through the conductive sheet;
wherein, when using a sheet surface of the conductive sheet as a reference plane, the Darcy permeability, in an in-plane direction, inside the liquid outflow member, is at least 50 times the Darcy permeability, in a normal direction, through the conductive sheet.

2. The electrode material as claimed in claim 1 , wherein the Darcy permeability, in the in-plane direction, inside the liquid inflow member, is at least 100 times the Darcy permeability, in the normal direction, through the conductive sheet.

3. The electrode material as claimed in claim 1 , wherein the liquid outflow member is a first porous sheet.

4. The electrode material as claimed in claim 3 , wherein the first porous sheet is conductive.

5. The electrode material as claimed in claim 3 , wherein the first porous sheet is not susceptible to corrosion by the electrolyte solution.

6. The electrode material as claimed in claim 1 , wherein the liquid inflow member comprises a support member that supports the conductive sheet.

7. The electrode material as claimed in claim 6 , wherein the support member is arranged so as to form:
a first flow passage through which the electrolyte solution passes from a liquid inflow port formed on one end of the liquid inflow member to another end thereof; and
a second flow passage, connected to the first flow passage, through which the electrolyte solution flows in a direction intersecting with the first flow passage.

8. The electrode material as claimed in claim 1 , wherein two or more liquid inflow members are connected to the conductive sheet.

9. The electrode material as claimed in claim 1 , comprising a second porous sheet between the liquid inflow member and the conductive sheet.

10. The electrode material as claimed in claim 1 , comprising a third porous sheet inside the liquid inflow member.

11. A redox flow battery electrode that uses an electrode material as claimed in claim 1 .

12. The redox flow battery electrode as claimed in claim 11 , wherein the liquid inflow member of the electrode material is provided on a side towards a bipolar plate, and the liquid outflow member is provided on a side towards an ion exchange membrane.

13. The redox flow battery electrode as claimed in claim 11 , wherein the liquid inflow member of the electrode material is fitted into a recess portion formed on the surface on a side of the bipolar plate towards the ion exchange membrane.

14. A redox flow battery comprising a redox flow battery electrode as claimed in claim 11 .

15. The electrode material as claimed in claim 1 , wherein the carbon nanotubes having an average fiber diameter of 1 μm or less is a mixture of first carbon nanotubes and second carbon nanotubes;
the first carbon nanotubes have an average fiber diameter of 100 to 1000 nm;
the second carbon nanotubes have an average fiber diameter of 30 nm or less; and
a content of the second carbon nanotubes is 0.05 to 30 parts by mass with respect to a total of 100 parts by mass of the first carbon nanotubes and the second carbon nanotubes.

16. The electrode material as claimed in claim 1 , wherein the conductive sheet further contains one or more conductive materials selected from the group consisting of conductive polymers, graphite and conductive carbon fibers;
a combined content of the carbon nanotubes and the one or more conductive materials contained in the conductive sheet is 80 mass % or more;
the conductive sheet contains conductive carbon fibers;
the conductive carbon fibers have an average fiber diameter greater than 1 μm; and
a content of the carbon fibers is 2 to 95 parts by mass with respect to a total of 100 parts by mass of the carbon nanotubes and the conductive carbon fibers.

17. An electrode material comprising:
a conductive sheet containing carbon nanotubes having an average fiber diameter of 1 μm or less;
a liquid inflow member that is formed on a first surface of the conductive sheet such that an electrolyte solution that is passed therethrough flows into the conductive sheet; and
a liquid outflow member that is formed on a second surface of the conductive sheet and out of which flows the electrolyte solution that has passed through the conductive sheet;
wherein, when using a sheet surface of the conductive sheet as a reference plane, the Darcy permeability, in an in-plane direction, inside the liquid inflow member, is at least 100 times the Darcy permeability, in a normal direction, through the conductive sheet.

18. The electrode material as claimed in claim 17 , wherein the Darcy permeability, in the in-plane direction, inside the liquid outflow member, is at least 50 times the Darcy permeability, in the normal direction, through the conductive sheet.

19. A redox flow battery electrode that is used in a redox flow battery, comprising:
a conductive sheet containing carbon nanotubes having an average fiber diameter of 1 μm or less;
a bipolar plate that is arranged in parallel with the conductive sheet and that comprises a liquid inflow portion such that an electrolyte solution that is passed therethrough flows into the conductive sheet; and
a liquid outflow member that is arranged on the side of the conductive sheet opposite to the bipolar plate and out of which flows the electrolyte solution that has passed through the conductive sheet;
wherein, when using a sheet surface of the conductive sheet as a reference plane, the Darcy permeability, in an in-plane direction, inside the liquid outflow member, is at least 50 times the Darcy permeability, in a normal direction, through the conductive sheet.

20. A redox flow battery electrode that is used in a redox flow battery, comprising:
a conductive sheet containing carbon nanotubes having an average fiber diameter of 1 μm or less;
a bipolar plate that is arranged in parallel with the conductive sheet and that comprises a liquid inflow portion such that an electrolyte solution that is passed therethrough flows into the conductive sheet; and
a liquid outflow member that is arranged on the side of the conductive sheet opposite to the bipolar plate and out of which flows the electrolyte solution that has passed through the conductive sheet;
wherein, when using a sheet surface of the conductive sheet as a reference plane, the Darcy permeability, in an in-plane direction, inside the liquid inflow member, is at least 100 times the Darcy permeability, in a normal direction, through the conductive sheet.

Assignees

• Showa Denko Kk

Inventors

• Ichikawa Masatoshi
• ISEKI Keizo
• Oriji Gaku
• Hanawa Kenzo

Classifications

• H01M4/368

  Liquid depolarisers · CPC title

• H01M4/86

  Inert electrodes with catalytic activity, e.g. for fuel cells · CPC title

• H01M8/18

  Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells · CPC title

• H01M8/188 Primary

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• H01M4/663

  containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres · CPC title