Fabrication of reinforced superconducting wires

Patent metadata

Field	Value
Publication number	US-10679775-B2
Application number	US-201816037279-A
Country	US
Kind code	B2
Filing date	Jul 17, 2018
Priority date	Jul 14, 2015
Publication date	Jun 9, 2020
Grant date	Jun 9, 2020

Abstract

In various embodiments, superconducting wires feature assemblies of clad composite filaments and/or stabilized composite filaments embedded within a wire matrix. The wires may include one or more stabilizing elements for improved mechanical properties.

First claim

What is claimed is:

1. A method of forming a mechanically stabilized superconducting wire, the method comprising:
providing a plurality of monofilaments each comprising a monofilament core comprising Nb and, surrounding the core, a monofilament cladding comprising Cu;
providing a plurality of stabilizing elements each comprising a stabilizing core comprising a Ta alloy with at least one of W, C, or N, and, surrounding the stabilizing core, a stabilizing cladding comprising Cu;
fabricating a plurality of composite filaments by, for each composite filament, (i) assembling a plurality of the monofilaments and a first stabilizing element into a monofilament stack, wherein the first stabilizing element extends through an axial dimension of the monofilament stack, (ii) surrounding the monofilament stack with a composite-filament cladding comprising Cu, and (iii) reducing a diameter of the clad monofilament stack;
assembling a plurality of the composite filaments into a composite stack;
surrounding the composite stack with a wire cladding comprising Cu; and
reducing a diameter of the clad composite stack to form a wire, thereby forming a superconducting wire comprising:
a wire matrix comprising Cu; and
a plurality of composite filaments embedded within the wire matrix, wherein:
each composite filament comprises (i) only a single first stabilizing element extending through an axial dimension of the composite filament, (ii) a plurality of monofilaments radially surrounding the first stabilizing element, and (iii) a composite-filament cladding comprising Cu surrounding the plurality of monofilaments and the first stabilizing element,
each monofilament comprises a monofilament core comprising Nb and, surrounding the monofilament core, a monofilament cladding comprising Cu,
each first stabilizing element comprises a stabilizing core comprising a Ta alloy with at least one of W, C, or N, and, surrounding the stabilizing core, a stabilizing cladding comprising Cu, and
the stabilizing cladding of each first stabilizing element directly contacts only monofilament claddings of the plurality of monofilaments radially surrounding the first stabilizing element.

2. The method of claim 1 , wherein a second one or more of the stabilizing elements (i) are assembled with the plurality of composite filaments to form the composite stack and (ii) extend through an axial dimension of the composite stack.

3. The method of claim 2 , wherein the second one or more stabilizing elements are disposed substantially at a radial center of the composite stack.

4. The method of claim 2 , wherein the second one or more stabilizing elements occupy less than approximately 10% of a cross-section of the wire.

5. The method of claim 1 , wherein the first stabilizing elements are disposed substantially at a radial center of each monofilament stack.

6. The method of claim 1 , wherein less than approximately 10% of a cross-section of each of the composite filaments is occupied by the first stabilizing element.

7. The method of claim 1 , wherein each monofilament is provided by a process comprising (i) disposing a rod comprising Nb into a tube comprising Cu to form a clad rod, and (ii) reducing a diameter of the clad rod.

8. The method of claim 1 , wherein each stabilizing element is provided by a process comprising (i) disposing a rod comprising a Ta alloy with at least one of W, C, or N into a tube comprising Cu to form a clad rod, and (ii) reducing a diameter of the clad rod.

9. The method of claim 1 , wherein the core of each stabilizing element comprises Ta-3W.

10. The method of claim 1 , wherein the core of each stabilizing element consists of the Ta alloy with at least one of W, C, or N.

11. The method of claim 1 , further comprising (i) disposing Sn within or on the wire and (ii) annealing the wire to form a Nb 3 Sn phase within the wire.

12. A superconducting wire comprising:
a wire matrix comprising Cu; and
a plurality of composite filaments embedded within the wire matrix, wherein:
each composite filament comprises (i) only a single first stabilizing element extending through an axial dimension of the composite filament, (ii) a plurality of monofilaments radially surrounding the first stabilizing element, and (iii) a composite-filament cladding comprising Cu surrounding the plurality of monofilaments and the first stabilizing element,
each monofilament comprises a monofilament core comprising Nb and, surrounding the monofilament core, a monofilament cladding comprising Cu,
each first stabilizing element comprises a stabilizing core comprising a Ta alloy with at least one of W, C, or N, and, surrounding the stabilizing core, a stabilizing cladding comprising Cu, and
the stabilizing cladding of each first stabilizing element directly contacts only monofilament claddings of the plurality of monofilaments radially surrounding the first stabilizing element.

13. The wire of claim 12 , further comprising a second stabilizing element embedded within the wire matrix and surrounded by the plurality of composite filaments, wherein the second stabilizing element (i) comprises a second-stabilizing-element core comprising a Ta alloy with at least one of W, C, or N, and, surrounding the second-stabilizing-element core, a second-stabilizing-element cladding comprising Cu, and (ii) extends through an axial dimension of the wire.

14. The wire of claim 13 , wherein the second stabilizing element is disposed proximate a radial center of the wire.

15. The wire of claim 13 , wherein the second-stabilizing-element core of the second stabilizing element comprises Ta-3W.

16. The wire of claim 13 , wherein the second stabilizing element occupies less than approximately 10% of a cross-section of the wire.

17. The wire of claim 12 , wherein the monofilament core of each monofilament comprises Nb—Ti.

18. The wire of claim 12 , wherein the monofilament core of each monofilament comprises Nb 3 Sn.

19. The wire of claim 12 , wherein the stabilizing core of each first stabilizing element comprises Ta-3W.

20. The wire of claim 12 , wherein, for each composite filament, the first stabilizing element is disposed proximate a radial center of the composite filament.

21. The wire of claim 12 , wherein, for each composite filament, the first stabilizing element occupies less than approximately 10% of a cross-section of the composite filament.

Assignees

• Aimone Paul
• Dary Francois Charles
• Smathers David B
• Starck H C Inc

Inventors

• Aimone Paul
• Dary Francois-Charles
• Smathers David B

Classifications

• H01B1/026

  Alloys based on copper · CPC title

• H01L39/2409

  Electricity · mapped topic

• H01B12/10 Primary

  Multi-filaments embedded in normal conductors · CPC title

• H01B13/0036

  Details · CPC title

• H01L39/14

  Electricity · mapped topic