Method for separating a hydrocarbon mixture containing hydrogen, separating device, and olefin plant

Patent metadata

Field	Value
Publication number	US-10677525-B2
Application number	US-201415109960-A
Country	US
Kind code	B2
Filing date	Dec 17, 2014
Priority date	Jan 7, 2014
Publication date	Jun 9, 2020
Grant date	Jun 9, 2020

Abstract

A method for separating a hydrogen-containing hydrocarbon mixture (C2minus), which in addition to the hydrogen essentially contains hydrocarbons with two carbon atoms and methane, using a distillation column (10). Fluid (a, c, e) of the hydrocarbon mixture (C2minus) is cooled stepwise at a first pressure level, during which time first condensates (b, d) are separated from the fluid (a, c, e). Fluid (e) from the hydrocarbon mixture (C2minus) which remains gaseous after this is fed at the first pressure level into a C2 absorber (7), to which a liquid reflux (r) is added at the top, while a second condensate (f) is drawn off from the sump of the C2 absorber (7) and a gaseous top stream (g) containing predominantly methane and hydrogen is drawn off at the top of the C2 absorber (7). Fluid of the above-mentioned gaseous top stream (g) from the top of the C2 absorber (7) is cooled to a third temperature level and transferred at the first pressure level into a hydrogen separator (8) in which a methane-rich third condensate (i) is separated from the fluid of the gaseous top stream (g), leaving behind a gaseous, hydrogen-rich stream (h). Fluid of the first condensates (b, d) and fluid of the second condensate (f) is depressurized from the first pressure level to a second pressure level below the first pressure level and fed into the distillation column (10) which is operated at the second pressure level. Fluid (e) of the third condensate (i) which is separated in the hydrogen separator (8) from the fluid of the gaseous top stream (g) from the top of the C2 absorber is used as the reflux (r) added at the top of the C2 absorber (7) and transferred from the hydrogen separator to the C2 absorber solely by gravity. The invention also relates to a corresponding separating unit and a corresponding olefin apparatus.

First claim

The invention claimed is:

1. Method for separating a hydrogen-containing hydrocarbon mixture (C2minus), which in addition to the hydrogen essentially contains hydrocarbons with two carbon atoms and methane, using a distillation column ( 10 ), wherein
the hydrocarbon mixture (C2minus) or a part of the hydrocarbon mixture (C2minus) is cooled stepwise, at a first pressure level, from a first temperature level, via two or more intermediate temperature levels, to a second temperature level, first condensates (b, d) being separated from the hydrocarbon mixture (C2minus) or said part of the hydrocarbon mixture (C2minus) at each of the intermediate temperature levels,
a part of the hydrocarbon mixture (C2minus) or said part of the hydrocarbon mixture (C2minus) which remains gaseous at the second temperature level and which is not obtained in the form of the first condensates (b, d) is fed at the first pressure level into a C2 absorber ( 7 ), to which a liquid reflux (r) is added at a top, wherein a second condensate (f) is drawn off from a sump of the C2 absorber ( 7 ) and a gaseous top stream (g) comprising predominantly methane and hydrogen is drawn off at the top of the C2 absorber ( 7 ),
the gaseous top stream (g) from the top of the C2 absorber ( 7 ) or a part of the gaseous top stream (g) is cooled to a third temperature level and transferred at the first pressure level into a hydrogen separator ( 8 ) in which a methane-rich third condensate (i) is separated from the gaseous top stream (g) or said part of the gaseous top stream (g), leaving behind a gaseous, hydrogen-rich stream (h), and
the first condensates (b, d) or a part of the first condensates (b, d) and the second condensate (f) or a part of the second condensate (f) is depressurized from the first pressure level to a second pressure level below the first pressure level and fed into the distillation column ( 10 ) which is operated at the second pressure level, wherein in the distillation column ( 10 ) at least a liquid stream (o) essentially consisting of hydrocarbons with two carbon atoms, and a liquid stream (m) essentially consisting of methane are obtained and drawn off from the distillation column ( 10 ),

characterised in that the reflux (r) added at the top of the C2 absorber is formed from fluid of the methane-rich third condensate (i) which is separated in the hydrogen separator ( 8 ) from the gaseous top stream (g) from the top of the C2 absorber ( 7 ) and transferred from the hydrogen separator ( 8 ) into the C2 absorber ( 7 ) solely by the effect of gravity, wherein the C2 absorber is an absorption column not comprising a sump evaporator or an absorption column comprising a sump evaporator which is not operated, and the C2 absorber comprises installments provided for a stepwise or a constant phase contact.

2. The method according to claim 1 , wherein a quantity of the fluid of the third condensate (i) used as reflux (r) is selected so as to be approximately equivalent to a quantity of the liquid stream (m), consisting essentially of methane, which is drawn off from the distillation column ( 10 ).

3. The method according to claim 1 , wherein fluid from the liquid stream (m) which is drawn off from the distillation column ( 10 ) is used at least to cool the fluid (a, c, e) of the hydrocarbon mixture (C2minus) from the first temperature level, via the intermediate temperature levels, to the second temperature level.

4. The method according to claim 1 , wherein fluid from the gaseous, hydrogen-rich stream (h) from the hydrogen separator ( 8 ) is used to cool the fluid (a, c, e) of the hydrocarbon mixture (C2minus) from the first temperature level, via the intermediate temperature levels, to the second temperature level, and to cool the fluid of the gaseous top stream (g) from the top of the C2 absorber ( 7 ) to the third temperature level.

5. The method according to claim 1 , wherein the hydrocarbon mixture (C2minus) is obtained from a cracked gas obtained by means of a steam cracking process ( 50 ).

6. Separating unit ( 100 ) which is designed to separate a hydrogen-containing hydrocarbon mixture (C2minus), which in addition to hydrogen essentially contains hydrocarbons with two carbon atoms and methane, and comprises at least one distillation column ( 10 ), a C2 absorber ( 7 ) and a hydrogen separator ( 8 ), as well as a steam cracking process designed
to cool the hydrocarbon mixture (C2minus) or a part of the hydrocarbon mixture (C2minus), at a first pressure level, stepwise from a first temperature level, via two or more intermediate temperature levels, to a second temperature level and to separate first condensates (b, d) from the hydrocarbon mixture (C2minus) or said part of the hydrocarbon mixture (C2minus) at each of the intermediate temperature levels,
to feed, at the first pressure level, a part of the hydrocarbon mixture (C2minus) or said part of the hydrocarbon mixture (C2minus) which remains gaseous at the second temperature level and which is not obtained in the form of the first condensates (b, d) into the C2 absorber ( 7 ), to add a liquid reflux (r) to the C2 absorber at a top, and to draw off a second condensate (f) from a sump of the C2 absorber ( 7 ) and a gaseous top stream (g), predominantly containing methane and hydrogen, at the top of the C2 absorber ( 7 ),
to cool the gaseous top stream (g) from the top of the C2 absorber ( 7 ) or a part of the gaseous top stream (g) to a third temperature level and transfer the gaseous top stream (g) or said part of the gaseous top stream (g), at the first pressure level, into the hydrogen separator ( 8 ) and therein to separate off a methane-rich third condensate (i) from the gaseous top stream (g) or said part of the gaseous top stream (g), leaving behind a gaseous, hydrogen-rich stream (h), and
to depressurize the first condensates (b, d) or a part of the first condensates (b, d) and the second condensate (f) or a part of the second condensate (f) from the first pressure level to a second pressure level below the first pressure level and to fed it into the distillation column ( 10 ), to operate the distillation column ( 10 ) at the second pressure level, and to obtain in, and to draw off from, the distillation column ( 10 ) at least a liquid stream (o) essentially consisting of hydrocarbons with two carbon atoms, and a liquid stream (m) essentially consisting of methane,
characterised in that fluid communication is provided which is designed to form the reflux (r) added at the top of the C2 absorber from fluid (e) of the methane-rich third condensate (i) which is separated in the hydrogen separator ( 8 ) from the gaseous top stream (g) from the top of the C2 absorber ( 7 ) and is transferred from the hydrogen separator ( 8 ) into the C2 absorber ( 7 ) solely by the effect of gravity

wherein the C2 absorber is an absorption column not comprising a sump evaporator or an absorption column comprising a sump evaporator which is not operated, and the C2 absorber comprises installments provided for a stepwise or a constant phase contact.

7. The separating unit ( 100 ) according to claim 6 , which is designed for carrying out the method according to claim 1 .

8. Olefin apparatus which is designed to carry out a steam cracking process ( 50 ) using at least one cracking furnace ( 51 - 53 ), wherein the steam cracking process ( 50 ) is designed to recover a hydrocarbon mixture (C2minus) consisting essentially of hydrocarbons with two carbon atoms as well as methane and hydrogen, from fluid of a cracked gas (C) of the at least one steam cracking process ( 50 ), characterised by at least one separating unit ( 100 ) according to claim 6 , which is designed to separate the hydrocarbon mixture (C2minus).

Assignees

• Linde Ag

Inventors

• Fritz Helmut
• Höfel Torben

Classifications

• F25J2215/60

  Methane · CPC title

• B01D53/145

  Pretreatment by separation of solid or liquid material · CPC title

• F25J2205/04

  in the feed line, i.e. upstream of the fractionation step · CPC title

• B01D3/143

  by two or more of a fractionation, separation or rectification step · CPC title

• C07C9/04

  Methane (production by treatment of sewage C02F11/04; natural gas, synthetic natural gas C10L3/06) · CPC title