Integrated electrical power and chemical production using fuel cells

Patent metadata

Field	Value
Publication number	US-10676799-B2
Application number	US-201615236958-A
Country	US
Kind code	B2
Filing date	Aug 15, 2016
Priority date	Mar 15, 2013
Publication date	Jun 9, 2020
Grant date	Jun 9, 2020

Abstract

In various aspects, systems and methods are provided for operating a molten carbonate fuel cell, such as a fuel cell assembly, with increased production of syngas while also reducing or minimizing the amount of CO2 exiting the fuel cell in the cathode exhaust stream. This can allow for improved efficiency of syngas production while also generating electrical power.

First claim

What is claimed is:

1. A system for producing electricity and synthesizing hydrocarbonaceous compounds, the system comprising:
a molten carbonate fuel cell comprising an anode and a cathode, the anode comprising an anode inlet for receiving a fuel stream comprising a reformable fuel and comprising an anode outlet from which an anode exhaust is provided, the cathode comprising a cathode inlet for receiving a stream comprising CO 2 and O 2 and comprising a cathode outlet from which a cathode exhaust is provided,
wherein a ratio of net moles of H 2 and CO in the anode exhaust to moles of CO 2 in a cathode exhaust is at least about 2.0, and wherein less than 10 vol% of the anode exhaust is directly or indirectly recycled to the cathode of the molten carbonate fuel cell.

2. The system of claim 1 , wherein the ratio of net moles of H 2 and CO in the anode exhaust to moles of CO 2 in the cathode exhaust is at least about 3.0.

3. The system of claim 2 , wherein the ratio of net moles of H 2 and CO in the anode exhaust to moles of CO 2 in the cathode exhaust is at least about 4.0.

4. The system of claim 1 , further comprising a separation stage for separating from the anode exhaust a H 2 -containing stream, a syngas-containing stream, or a combination thereof.

5. The system of claim 4 , further comprising a separation stage for separating the H 2 -containing stream from the anode exhaust upstream from the separation stage for separating the syngas-containing stream from the anode exhaust, the H 2 -containing stream containing at least about 90 vol% H 2 .

6. The system of claim 4 , wherein the syngas-containing stream has a molar ratio of H 2 to CO of about 3.0:1 to about 1.0:1.

7. The system of claim 4 , further comprising a separation stage for separating at least one of CO 2 and H 2 O from one or a combination of i) the anode exhaust, ii) the H 2 -containing stream, and iii) the syngas-containing stream.

8. The system of claim 4 , further comprising a separating stage for separating a stream containing at least about 90 vol% H 2 from the syngas-containing stream.

9. The system of claim 1 , wherein the anode exhaust has a ratio of H 2 to CO of about 1.5:1 to about 10:1.

10. The system of claim 1 , wherein the anode fuel stream comprises at least about 10 vol% inert compounds, at least about 10 vol% CO 2 , or a combination thereof.

11. The system of claim 1 , wherein less than 10 vol% of H 2 produced in the anode of the molten carbonate fuel cell in a single pass is directly or indirectly recycled to the anode of the molten carbonate fuel cell or the cathode of the molten carbonate fuel cell.

12. The system of claim 1 , wherein less than 10 vol% of the syngas-containing stream is directly or indirectly recycled to the anode of the molten carbonate fuel cell or the cathode of the molten carbonate fuel cell.

13. The system of claim 1 , wherein no portion of the anode exhaust is directly or indirectly recycled to the anode of the molten carbonate fuel cell, directly or indirectly recycled to the cathode of the molten carbonate fuel cell, or a combination thereof.

14. The system of claim 1 , further comprising a combustion-powered generator having an exhaust stream in fluid communication with the cathode inlet.

15. The system of claim 1 , wherein the molten carbonate fuel cell is operated at a voltage V A of about 0.67 Volts or less.

16. The system of claim 1 , wherein less than 5 vol% of the anode exhaust is directly or indirectly recycled to the cathode of the molten carbonate fuel cell.

17. A system for producing electricity and synthesizing hydrocarbonaceous compounds, the system comprising:
a molten carbonate fuel cell comprising an anode and a cathode, the anode comprising an anode inlet for receiving a fuel stream comprising a reformable fuel and comprising an anode outlet from which an anode exhaust is provided, the cathode comprising a cathode inlet for receiving a stream comprising CO 2 and O 2 and comprising a cathode outlet from which a cathode exhaust is provided,
wherein a ratio of net moles of H 2 and CO in the anode exhaust to moles of CO 2 in a cathode exhaust is at least about 1.5.

18. The system of claim 17 , wherein a ratio of net moles of H 2 and CO in the anode exhaust to moles of CO 2 in the cathode exhaust is at least about 3.0.

19. The system of claim 17 , wherein less than 10 vol% of the anode exhaust is directly or indirectly recycled to the cathode of the molten carbonate fuel cell.

20. The system of claim 17 , wherein no portion of the anode exhaust is directly or indirectly recycled to the anode of the molten carbonate fuel cell, directly or indirectly recycled to the cathode of the molten carbonate fuel cell, or a combination thereof.

21. The system of claim 17 , wherein the CO 2 concentration in the cathode inlet stream is about 5 vol% or less.

22. The system of claim 17 , wherein less than 5 vol% of the anode exhaust is directly or indirectly recycled to the cathode of the molten carbonate fuel cell.

Assignees

• Exxonmobil Res & Eng Co

Inventors

• Berlowitz Paul J
• Barckholtz Timothy A
• Hershkowitz Frank

Classifications

• Y02E60/563

  Cross-Sectional Technologies · mapped topic

• Y02P70/56

  Cross-Sectional Technologies · mapped topic

• H01M8/06

  Combination of fuel cells with means for production of reactants or for treatment of residues (regenerative fuel cells H01M8/18) · CPC title

• C07C29/152

  characterised by the reactor used · CPC title

• Y02P10/132

  Cross-Sectional Technologies · mapped topic