Poly-octavinyl polyhedral oligomeric silsesquioxane-acrylic acid nano composite auxiliary agent for leather and preparation method therefor

Patent metadata

Field	Value
Publication number	US-10676798-B2
Application number	US-201716348874-A
Country	US
Kind code	B2
Filing date	Jan 13, 2017
Priority date	Nov 14, 2016
Publication date	Jun 9, 2020
Grant date	Jun 9, 2020

Abstract

The invention relates to a poly silsesquioxane-acrylic nanocomposite auxiliary for leather process and its preparation method. By mixing octavinyl silsesquioxane, organic solvent, ammonium persulfate, distilled water and surfactant in one system, and adding acrylic acid dropwise into the mixing system, cooling to adjust pH to obtain poly silsesquioxane-acrylic nanocomposite auxiliary for leather process. The auxiliary obtained in this invention is easily to penetrate into gap of the collagen fibers, and forms nano and micro-scale combination with the leather collagen, which can further improve the multi-point combination of the acrylic polymer with the collagen. Thus, the filling property of the leather that treated by the auxiliary is improved without affect the yield of leather, and the chromium content in the waste water is significantly reduced.

First claim

What is claimed is:

1. A method for preparing a poly silsesquioxane (POSS)-acrylic nanocomposite auxiliary for leather process, comprising:
step 1: preparing a reaction mixture by adding 0.1-0.5 g of octavinyl-POSS, 1-15 g of organic solvent, 0.4-1 g of ammonium persulfate, 35-40 g of deionized water and 0.05-0.4 g of surfactant into a three-neck-flask that is equipped with a digital agitator and a reflux condenser;
step 2: adding 8-16 g of acrylic acid dropwise into said reaction mixture for 30-60 min while heating up gradually to 60° C. in a water bath, reacting for 6-8 hours;
step 3: cooling the polymer solution to room temperature, and adjusting pH of the polymer solution to 5.0 to obtain the poly silsesquioxane-acrylic nanocomposite auxiliary for leather process.

2. The method according to claim 1 , wherein the organic solvent is selected from the group consisting of dichloromethane, dimethyl sulfoxide and dimethylformamide.

3. The method according to claim 1 , wherein the surfactant is selected from the group consisting of sodium dodecyl sulfate and sodium dodecyl benzene sulfonate.

Assignees

• Shaanxi Univ Of Science & Technology
• Ma Jianzhong
• Jia Lu
• Gao Dangge
• Lv Bin

Inventors

• Ma Jianzhong
• Jia Lu
• Gao Dangge
• Lv Bin

Classifications

• B82Y35/00

  Methods or apparatus for measurement or analysis of nanostructures · CPC title

• C08G77/045

  containing less than 25 silicon atoms · CPC title

• C08F230/08 Primary

  containing silicon · CPC title

• C08F220/06

  Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

• C08F8/44

  Preparation of metal salts or ammonium salts · CPC title