Process for preparing a spray-dried laundry detergent particle

Patent metadata

Field	Value
Publication number	US-10676703-B2
Application number	US-201715723212-A
Country	US
Kind code	B2
Filing date	Oct 3, 2017
Priority date	Oct 3, 2016
Publication date	Jun 9, 2020
Grant date	Jun 9, 2020

Abstract

The present invention relates to a process for preparing a spray-dried laundry detergent particle, wherein the process includes the step of contacting zeolite to monomeric organic carboxylic acid in an aqueous mixture, wherein the aqueous mixture has a pH of 4.2 or less, wherein the aqueous mixture includes detersive surfactant, wherein the aqueous mixture is substantially free of silicate salt, and wherein the aqueous mixture is substantially free of carbonate salt, wherein the zeolite reacts with the monomeric organic carboxylic acid to form silica, wherein the aqueous mixture is spray-dried to form a spray-dried laundry detergent particle, wherein the particle includes: detersive surfactant; monomeric organic carboxylic acid; and silica, wherein the particle is substantially free of silicate salt, and wherein the particle is substantially free of carbonate salt.

First claim

What is claimed is:

1. A process for preparing a spray-dried laundry detergent particle,
wherein the process comprises the step of contacting zeolite to monomeric organic carboxylic acid in an aqueous mixture,
wherein the aqueous mixture has a pH of 4.2 or less,
wherein the aqueous mixture comprises detersive surfactant, wherein the aqueous mixture is substantially free of silicate salt, and wherein the aqueous mixture is substantially free of carbonate salt,
wherein the zeolite reacts with the monomeric organic carboxylic acid to form silica, wherein after the zeolite has reacted with the monomeric organic carboxylic acid, the aqueous mixture comprises from about 7.2 wt % to about 24 wt % detersive surfactant,
wherein the aqueous mixture is spray-dried to form a spray-dried laundry detergent particle,
wherein the particle comprises: detersive surfactant; monomeric organic carboxylic acid; and silica,
wherein the particle is substantially free of silicate salt, wherein the particle is substantially free of carbonate salt and wherein the particle has a pH of 6.0 or less, upon dissolution in de-ionized water at a concentration of 10 wt % and a temperature of 25° C.

2. A process according claim 1 , wherein the aqueous mixture has a pH of about 3.5 or less.

3. A process according to claim 1 , wherein the particle has a pH of 5.0 or less, upon dissolution in de-ionized water at a concentration of 10 wt % and a temperature of 25° C.

4. A process according to claim 1 , wherein the particle has a pH of about 4.2 or less, upon dissolution in de-ionized water at a concentration of 10 wt % and a temperature of 20° C.

5. A process according to claim 1 , wherein the particle has a pH of about 3.5 or less, upon dissolution in de-ionized water at a concentration of 10 wt % and a temperature of 20° C.

6. A process according to claim 1 , wherein the monomeric organic carboxylic acid is a monomeric organic polycarboxylic acid.

7. A process according to claim 6 , wherein the monomeric organic polycarboxylic acid is citric acid.

8. A process according to claim 1 , wherein the detersive surfactant is alkyl benzene sulphonate.

9. A process according to claim 1 , wherein the weight ratio of monomeric organic carboxylic acid to zeolite present in the aqueous mixture is at least about 1.6.

10. A process according to claim 1 , wherein the aqueous mixture comprises magnesium sulphate, and wherein the particle comprises magnesium sulphate in amorphous form.

11. A process according to claim 1 , wherein the aqueous mixture comprises carboxylate polymer, and wherein the particle comprises carboxylate polymer.

12. A process according to claim 1 , wherein the aqueous mixture further comprises magnesium sulphate, polymer, and sodium sulphate, wherein the particle comprises:
(a) from about 12 wt % to about 30 wt % detersive surfactant;
(b) from about 4 wt % to about 10 wt % monomeric organic carboxylic acid;
(c) from about 0.5 wt % to about 3 wt % silica;
(d) from about 2 wt % to about 10 wt % magnesium sulphate;
(e) from about 0.5 wt % to about 5 wt % polymer;
(f) from about 35 wt % to about 80 wt % sodium sulphate; and
(g) from above 0 wt % to about 6 wt % water.

13. A process according to claim 1 , wherein the aqueous mixture further comprises magnesium sulphate, polymer, and sodium sulphate, wherein after the zeolite has reacted with the monomeric organic carboxylic acid, the aqueous mixture comprises:
(a) from about 20 wt % to about 40 wt % water;
(b) from about 7.2 wt % to about 24 wt % detersive surfactant;
(c) from about 2.4 wt % to about 8 wt % monomeric organic carboxylic acid;
(d) from about 0.3 wt % to about 2.4 wt % silica;
(e) from about 1.2 wt % to about 8 wt % magnesium sulphate;
(f) from about 0.3 wt % to about 4 wt % polymer; and
(g) from about 21 wt % to about 64 wt % sodium sulphate.

Assignees

• Procter & Gamble

Inventors

• Tantawy Hossam Hassan
• Caragay Jose Rodel Mabilangan
• Robles Eric San Jose

Classifications

• C11D3/3418

  Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates · CPC title

• C11D1/12

  Sulfonic acids or sulfuric acid esters; Salts thereof · CPC title

• C11D11/0017

  Chemistry & Metallurgy · mapped topic

• C11D17/06 Primary

  Powder; Flakes; Free-flowing mixtures; Sheets · CPC title

• C11D3/3746

  Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title