Fabric softener composition having improved detergent scavenger compatibility

Patent metadata

Field	Value
Publication number	US-10676694-B2
Application number	US-201715838394-A
Country	US
Kind code	B2
Filing date	Dec 12, 2017
Priority date	Dec 22, 2016
Publication date	Jun 9, 2020
Grant date	Jun 9, 2020

Abstract

The present invention relates to fabric softener compositions as well as the methods of making and using same. Such liquid fabric softener compositions comprise a quaternary ammonium ester fabric softening active, cellulose fibers and a hydrotrope. Such fabric softener compositions exhibit improved viscosity stability after addition of a hydrotrope while also delivering the softening benefits that are desired by consumers.

First claim

What is claimed is:

1. A liquid fabric softener composition comprising:
a) from about 3.0% to about 25.0% by weight of the composition of a quaternary ammonium ester softening active
b) from about 0.005% to about 1.0% by weight of the composition of a cationic hydrotrope, wherein the cationic hydrotrope has the general structure:

wherein:
each R 1 , R 2 , R 3 , R 4 is independently selected from alkyl, C 1 to C 4 hydroxyalkyl, or C 2 -C 4 alkoxy alcohol; and
A − is independently selected from the group consisting of chloride, methyl sulfate, and ethyl sulfate;

with the proviso that the cationic hydrotrope comprises at least about 6 to about 8 carbon atoms in total; and

c) cellulose fibers.

2. The liquid fabric softener composition according to claim 1 wherein the cationic hydrotrope is selected from the group consisting of bis (2-hydroxyethyl) dimethylammonium chloride, bis (2-hydroxyethyl) dimethylammonium methylsulfate, tris(2-hydroxyethyl) methylammonium chloride, tris(2-hydroxyethyl) methylammonium methylsulfate, bis (2-hydroxypropyl) dimethylammonium chloride, bis (2-hydroxypropyl) dimethylammonium methylsulfate, bis (1-methyl-2-hydroxyethyl) dimethylammonium chloride, bis (1-methyl-2-hydroxyethyl) dimethylammonium methylsulfate.

3. The liquid fabric softener composition according to claim 1 , wherein the quaternary ammonium ester softening active has the following formula:
{R 2 (4-m) —N+-[X—Y—R 1 ] m }A −

wherein:
m is 1, 2 or 3 with proviso that the value of each m is identical;
each R 1 is independently hydrocarbyl, or branched hydrocarbyl group;
each R 2 is independently a C 1 -C 3 alkyl or hydroxyalkyl group;
each X is independently (CH 2 )n, CH 2 —CH(CH 3 )— or CH—(CH 3 )—CH 2 —;
each n is independently 1, 2, 3 or 4;
each Y is independently —O—(O)C— or —C(O)—O—; and
A − is independently selected from the group consisting of chloride, methyl sulfate, and ethyl sulfate;

with the proviso that the sum of carbons in each R 1 , when Y is —O—(O)C—, is from about 13 to about 21.

4. The liquid fabric softener composition according to claim 1 , wherein the iodine value of the parent fatty acid compound from which the quaternary ammonium ester softening active is formed is from about 15 to about 45.

5. The liquid fabric softener composition according to claim 1 , wherein the quaternary ammonium ester softening active is present at a level of from about 7.0% to about 12% by weight of the composition.

6. The liquid fabric softener composition according to claim 1 , wherein the cellulose fiber is present at a level of from about 0.1% to about 0.75% by weight of the composition.

7. The liquid fabric softener composition according to claim 1 , wherein the cellulose fiber is microfibrous cellulose.

8. The liquid fabric softener composition according to claim 1 , wherein the cellulose fibers have an average diameter from about 50 nm to about 200 nm.

9. The liquid fabric softener composition according to claim 1 , wherein the composition has a viscosity between about 150 mPa·s and about 500 mPa·s as measured with a rotational viscometer, using spindle 2 for viscosities between about 50 mPa·s and about 400 mPa·s, and using spindle 3 for viscosities between about 400 mPa·s and about 800 mPa·s, at about 60 rpm, at about 21° C.

10. The liquid fabric softener composition according to claim 1 , wherein the composition has a dynamic yield stress at about 20° C. between about 0.01 Pa and about 0.5 Pa.

11. The liquid fabric softener composition according to claim 1 , comprising a dispersed perfume, wherein the perfume is present at a level of about 0.5% to about 5.0% by weight of the composition.

12. The liquid fabric softener composition according to claim 1 , comprising from about 0.05% to about 2.0% by weight of encapsulated benefit agent, said encapsulated benefit agent is encapsulated in capsules wherein said capsules comprise a capsule wall, said capsule wall comprising wall material selected from the group consisting of melamine, polyacrylamide, silicones, silica, polystyrene, polyurea, polyurethanes, polyacrylate based materials, polyacrylate esters based materials, gelatin, styrene malic anhydride, polyamides, aromatic alcohols, polyvinyl alcohol, resorcinol-based materials, poly-isocyanate-based materials, acetals, starch, cellulose acetate phthalate and mixtures thereof.

Assignees

• Procter & Gamble

Inventors

• Saveyn Pieter Jan Maria
• Fernandez Prieto Susana
• Vaes Dries
• Van Hecke Evelyne Johanna Lutgarde
• Orlandini Laura
• Hodgdon Travis Kyle

Classifications

• C11D3/30

  Amines; Substituted amines {; Quaternized amines} · CPC title

• C11D3/222

  Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin · CPC title

• C11D3/0015 Primary

  liquid · CPC title

• C11D1/62

  Quaternary ammonium compounds · CPC title