Conductive fluoropolymer compositions

Patent metadata

Field	Value
Publication number	US-10676591-B2
Application number	US-201615775469-A
Country	US
Kind code	B2
Filing date	Oct 21, 2016
Priority date	Nov 11, 2015
Publication date	Jun 9, 2020
Grant date	Jun 9, 2020

Abstract

A composition of solid particles comprising substantially inorganic, electronically conductive particles and fluoropolymer particles, wherein the fluoropolymer is melt-processable and has a melting point between 100° C. and 325° C. and a melt flow index at 372° C. and at 5 kg load (MFI 372/5) of at least 0.1 and up to 100 g/10 min, and wherein the fluoropolymer particles have a particle size of less than 500 nm and wherein the particles comprising the substantially inorganic, electronically conductive material is present in the form of particles having a particle size of less than 15,000 μm, and methods for producing such compositions and articles containing such compositions.

First claim

The invention claimed is:

1. A powder composition comprising perfluoropolymer particles adsorbed or deposited onto electronically conductive particles comprising at least 95% by weight inorganic material that is electronically conductive based on the total weight of the electronically conductive particles, wherein the perfluoropolymer is a copolymer of tetrafluoroethylene and at least one other perfluorinated comonomer and is melt-processable and has a melting point between 100° C. and 325° C. and a melt flow index at 372° C. and at 5 kg load of at least 0.1 and up to 100 g/10 min, and wherein the perfluoropolymer particles have a particle size of less than 500 nm and wherein, electronically conductive particles have a particle size of less than 15,000 μm, and wherein the composition is a free flowing powder and comprises less than 1,000 ppm of non-ionic emulsifiers.

2. The composition of claim 1 having an electrical conductivity according to ASTM F84 of at least 18 S/cm at 25° C.

3. The composition of claim 1 comprising from at least 5 wt.-% to no greater than 25 wt.-% of the perfluoropolymer and from at least 74 wt.-% of substantially inorganic electronically conductive material wherein the weight percentages are based on the total weight of the composition and wherein the total weight of the composition is 100%.

4. The composition of claim 1 wherein the inorganic material is selected from metals, metal alloys, and an electronically conductive form of carbon.

5. The composition of claim 1 wherein the inorganic material is selected from graphite.

6. The composition of claim 1 consisting of from 7 to 17% by weight of the perfluoropolymer, from at least 80% by weight of graphite and from 0% to less than 5% of other materials, and wherein the total amount of ingredients is 100% by weight.

7. The composition of claim 6 having an electrical conductivity according to ASTM F84 of at least 18 S/cm at 25° C.

8. The composition of claim 1 wherein the composition is obtained by subjecting an aqueous dispersion comprising the perfluoropolymer particles and the electronically conductive particles to a heat-treatment that removes water and surfactants under conditions where the perfluoropolymer does not melt.

9. The composition of claim 1 wherein the solid particles are coagulated particles.

10. A method for producing a powder composition comprising
(i) contacting substantially inorganic particles that are electronically conductive and have a particle size of less than 15,000 μm with an aqueous perfluoropolymer dispersion having perfluoropolymer particles of less than 500 nm particle size, wherein the perfluoropolymer dispersion comprises less than 1,000 ppm of non-ionic emulsifiers;
(ii) coagulating the particles, and
(iii) removing water and, if present, surfactants, to yield dry particles at conditions where the perfluoropolymer does not melt, wherein the composition is a free flowing powder comprising the perfluoropolymer particles adsorbed or deposited onto the substantially inorganic, electronically conductive material and;

wherein the perfluoropolymer is a copolymer of tetrafluoroethylene and at least one other perfluorinated comonomer and is melt-processable and has a melting point between 100° C. and 325° C. and a melt flow index at 372° C. and at 5 kg load of at least 0.1 and up to 100 g/10 min; and
wherein the substantially inorganic particles comprise at least 95% by weight inorganic material that is electronically conductive based on the total weight of the substantially inorganic particles.

11. The method of claim 10 , further comprising (iv) molding the composition into a shaped article, wherein prior to molding the composition may optionally be suspended or dispersed in an aqueous phase to provide a paste.

12. A method of providing a shaped article comprising
(i) providing a composition according to claim 1 ;
(ii) optionally, converting the composition into an aqueous paste; and
(iii) subjecting the composition to molding to yield a molded article.

13. An article comprising a component obtained from molding the composition of claim 1 .

14. The article of claim 13 , wherein the component is selected from a component of a fuel cell.

15. The article of claim 14 , wherein the article is a bipolar separator plate for a fuel cell.

16. The powder composition of claim 1 , wherein the perfluoropolymer is a copolymer of tetrafluoroethylene and hexafluoropropylene and has a melting point of at least 250° C.

17. The method of claim 10 , wherein the perfluoropolymer is a copolymer of tetrafluoroethylene and hexafluoropropylene and has a melting point of at least 250° C.

Assignees

• 3M Innovative Properties Co

Inventors

• Mitchell Michael H
• Fukushi Tatsuo
• Nawaz Muhammad Z
• Dadalas Michael C
• Hintzer Klaus
• Zipplies Tilman C
• Duchesne Denis

Classifications

• H01M8/0213

  Gas-impermeable carbon-containing materials · CPC title

• C08K3/04

  Carbon · CPC title

• C08K2201/001

  Conductive additives · CPC title

• C08K2201/005

  Additives being defined by their particle size in general · CPC title

• C08J2327/12

  containing fluorine atoms · CPC title