Process and apparatus for calcination of gypsum

Patent metadata

Field	Value
Publication number	US-10676396-B2
Application number	US-201616462016-A
Country	US
Kind code	B2
Filing date	Nov 18, 2016
Priority date	Nov 18, 2016
Publication date	Jun 9, 2020
Grant date	Jun 9, 2020

Abstract

The invention pertains to a process for modifying gypsum, wherein
a continuous feed of raw gypsum is provided; the water content of the raw gypsum is determined in the continuous feed by near infrared spectroscopy (NIR) measurement; the raw gypsum is calcined in a calcination unit at a fire rate to remove water from the raw gypsum and to obtain a continuous feed of calcined gypsum having a water content within a selected range; a water content of the calcined gypsum is determined by near infrared spectroscopy, and the fire rate is adjusted based on the water content of the raw gypsum and of the calcined gypsum.

Further, the invention pertains to an apparatus for performing said process.

First claim

The invention claimed is:

1. Process for dehydrating gypsum, wherein
a continuous feed of raw gypsum is provided;
the raw gypsum is calcined in a calcination unit at a fire rate to remove water from the raw gypsum and to obtain a continuous feed of calcined gypsum having a water content within a selected range;
a water content of the calcined gypsum is determined by near infrared spectroscopy, and
the fire rate is adjusted based on the water content of the calcined gypsum.

2. Process according to claim 1 , wherein a water content of the raw gypsum is determined in the continuous feed by near infrared spectroscopy (NIR) measurement and the fire rate is adjusted based on the water content of the raw gypsum and of the calcined gypsum.

3. Process according to claim 1 , wherein after calcination the calcined gypsum is cooled and the water content of the calcined gypsum is determined by NIR spectroscopy in a continuous feed of cooled calcined gypsum.

4. Process according to claim 1 , wherein a gypsum sample is taken from at least one of the group of continuous feed of raw gypsum, continuous feed of calcined gypsum, and continuous feed of cooled calcined gypsum for analysis by NIR spectroscopy.

5. Process according to claim 3 , wherein at least one external measuring station is provided for NIR measurement and the gypsum sample is transported to the at least one external measuring station for determination of the water content of the gypsum sample.

6. Process according to claim 4 , wherein the gypsum sample is provided at the measuring station in a standardized sample form.

7. Process according to claim 1 , wherein the adjustment of the fire rate is performed by adjustment of the feed rate of the raw gypsum to the calcination unit.

8. Process according to claim 1 , wherein a first gypsum sample is taken from the continuous feed of raw gypsum, the continuous feed of raw gypsum is calcined in the calcination unit and a second sample is taken from the continuous feed of calcined gypsum, wherein the second sample is taken from a spot within the continuous feed of calcined gypsum that corresponds to a spot of the continuous feed of raw gypsum, where the first gypsum sample has been taken.

9. Process according to claim 1 , wherein
the water content of the raw gypsum comprises a moisture content of physically bound water and a content of water of crystallization, and a content of water of crystallization C r is determined in the raw gypsum by NIR spectroscopy;
an amount Δ is defined, corresponding to an amount of water of crystallization to be removed from the raw gypsum;
a set-point for a content of water of crystallization S comprised in the calcined gypsum is determined by subtracting Δ from C r (S=C r −Δ);
the raw gypsum is fired at a fire rate to obtain calcined gypsum;
a content of water of crystallization C c of the calcined gypsum is determined by NIR spectroscopy; and
the fire rate is adjusted such that S−C c =0±δ, wherein δ is a maximum deviation.

10. Process according to claim 1 , wherein a process controller is provided and the adjustment of the fire rate is performed by the process controller.

11. Apparatus for dehydrating gypsum comprising:
a feeder for feeding a raw gypsum to a calcination unit;
a calcination unit for calcining the raw gypsum;
a discharging unit for discharging calcined gypsum from the calcination unit, and
a first NIR (Near Infrared) spectroscopy unit to determine the content of water or water of crystallization comprised in the calcined gypsum.

12. Apparatus according to claim 11 , wherein a second NIR spectroscopy unit is provided to determine the content of water or water of crystallization in the raw gypsum.

13. Apparatus according to claim 11 , characterized in that a cooling unit is provided for cooling the calcined gypsum and the first NIR spectroscopy unit is provided at a position to determine the content of water of crystallization after cooling of the calcined gypsum.

14. Apparatus according to claim 11 , characterized in that a third NIR spectroscopy unit is provided to determine the content of water of crystallization in the calcined gypsum before cooling of the calcined gypsum.

15. Apparatus according to claim 11 , characterized in that a process controller is provided for adjusting a fire rate of the calcination unit based on data determined by the first NIR spectroscopy unit and on data of at least one of the second and third NIR spectroscopy units.

Assignees

• Knauf Gips Kg

Inventors

• Johannsmann Olaf
• Schulte Rainer
• Ruiz Juan Jose

Classifications

• C04B11/0286 Primary

  Suspension heaters for flash calcining, e.g. cyclones · CPC title

• C04B11/02 Primary

  Methods and apparatus for} dehydrating gypsum {(for other purposes than cement manufacture C01F11/466) · CPC title