Activated hybrid zero-valent iron treatment system and methods for generation and use thereof
US-2018111855-A1 · Apr 26, 2018 · US
US10676376B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10676376-B2 |
| Application number | US-201715703028-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 13, 2017 |
| Priority date | Sep 29, 2016 |
| Publication date | Jun 9, 2020 |
| Grant date | Jun 9, 2020 |
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Methods of modification of zero-valent iron (ZVI) to improve its performance in removing contaminants from a discharge stream. In some aspects, the methods include contacting ZVI-impregnated disks with solutions containing metal cations such as Ni 2+ , Cu 2+ , Fe 2+ , or Pd 2+ . In some aspects, a wastewater stream is treated with a metal cation solution, then passed over ZVI. Compositions for treating wastewater include ZVI that is modified with a metal cation solution.
Opening claim text (preview).
The invention claimed is: 1. A method for treating a wastewater stream, the method comprising: contacting the wastewater stream with a solution containing one or more metal cations selected from the group consisting of nickel and copper to form a treated wastewater stream; contacting a ZVI with the treated wastewater stream; and separating oxidized iron and a contaminant selected from selenium, arsenic, nitrates, and any combination thereof from the wastewater stream. 2. The method of claim 1 , wherein the ZVI is bound to a solid support constructed from a material selected from ceramics, metals, polyethers, polyurethane, polyester, activated carbon, activated alumina, clays, and silica-based materials. 3. The method of claim 1 , wherein the concentration of metal cations is about 1 to about 500 ppm. 4. The method of claim 1 , wherein a pH of the wastewater stream is maintained at about 3 to about 7 at the time of contact with the ZVI. 5. The method of claim 4 , wherein the pH of the wastewater stream is maintained at about pH 6.0 at the time of contact with the ZVI.
by ion-exchange (ion-exchange in general B01J) · CPC title
using cation exchangers · CPC title
using inorganic sorbents · CPC title
Reduction by metals · CPC title
Compounds of Fe · CPC title
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