Advanced heat integration in sulfur recovery unit—SafarClaus

Patent metadata

Field	Value
Publication number	US-10676356-B2
Application number	US-201916443337-A
Country	US
Kind code	B2
Filing date	Jun 17, 2019
Priority date	Feb 21, 2018
Publication date	Jun 9, 2020
Grant date	Jun 9, 2020

Abstract

A method for heat integration in a sulfur recovery unit, the method comprising the steps of reacting the acid gas stream and the air stream in the reaction furnace to produce a reaction effluent, where the reaction effluent comprises elemental sulfur, reducing the temperature of the reaction effluent in the heating extension to produce an effluent stream, reducing the temperature of the reaction effluent in the waste heat boiler to produce a cooled effluent stream, reducing the temperature of the cooled effluent in the sulfur condenser to produce a liquid sulfur stream and a cooled gases stream, where the liquid sulfur stream comprises the elemental sulfur, and increasing a temperature of the cooled gases stream to produce a hot gases stream, where the heating extension is configured to capture heat from the reaction effluent and release the heat to the cooled gases stream.

First claim

That which is claimed is:

1. A method for heat integration in a sulfur recovery unit, the method comprising the steps of:
introducing an acid gas stream to a reaction furnace, where the acid gas stream comprises hydrogen sulfide;
introducing an air stream to the reaction furnace, where the air stream comprises oxygen;
reacting the acid gas stream and the air stream in the reaction furnace to produce a reaction effluent, where the reaction effluent comprises elemental sulfur, where the hydrogen sulfide and oxygen react to produce the elemental sulfur;
introducing the reaction effluent to a heating extension;
reducing the temperature of the reaction effluent in the heating extension to produce a cooled effluent stream;
introducing the cooled effluent to a sulfur condenser;
reducing the temperature of the cooled effluent in the sulfur condenser to produce a liquid sulfur stream and a cooled gases stream, where the liquid sulfur stream comprises the elemental sulfur;
introducing the cooled gases stream to the heating extension;
increasing a temperature of the cooled gases stream to produce a hot gases stream, where the heating extension is configured to capture heat from the reaction effluent and release the heat to the cooled gases stream;
introducing the hot gases stream to a first catalytic converter;
producing a first catalytic effluent in the first catalytic converter, where the first catalytic effluent comprises elemental sulfur, where the first catalytic converter comprises a catalyst;
introducing the first catalytic effluent to a first effluent condenser;
reducing the temperature of the first catalytic effluent in the first effluent condenser to produce a sulfur stream and a first non-condensed gases stream, where the sulfur stream comprises the elemental sulfur;
introducing the first non-condensed gases stream to the heating extension;
increasing a temperature of the first non-condensed gases stream to produce a first hot non-condensables stream;
introducing the first hot non-condensables stream to a second catalytic converter;
producing a second catalytic effluent in the second catalytic converter, where the second catalytic effluent comprises elemental sulfur, where the second catalytic converter comprises a catalyst;
introducing the second catalytic effluent to a second effluent condenser;
reducing the temperature of the second catalytic effluent in the second effluent condenser to produce a sulfur effluent and a second non-condensed gases stream, where the sulfur effluent comprises the elemental sulfur;
introducing the second non-condensed gases stream to the heating extension;
increasing a temperature of the second non-condensed gases stream to produce a second hot non-condensables stream;
introducing the second hot non-condensables stream to a third catalytic converter;
producing a third catalytic effluent in the third catalytic converter, where the third catalytic effluent comprises elemental sulfur, where the third catalytic converter comprises a catalyst;
introducing the third catalytic effluent to a third effluent condenser; and
reducing the temperature of the third catalytic effluent in the third effluent condenser to produce a sulfur discharge and a discharge stream, where the sulfur discharge comprises the elemental sulfur.

2. The method of claim 1 , further comprising the steps of;
introducing a pre-feed acid gas to an acid gas preheater; and
increasing the temperature of the pre-feed acid gas to produce the acid gas stream.

3. The method of claim 1 , further comprising the steps of:
introducing a pre-feed air to an air pre-heater; and
increasing the temperature of the pre-feed air to produce the air stream.

4. A method for heat integration in a sulfur recovery unit, the method comprising the steps of:
introducing an acid gas stream to a reaction furnace, where the acid gas stream comprises hydrogen sulfide;
introducing an air stream to the reaction furnace, where the air stream comprises oxygen;
reacting the acid gas stream and the air stream in the reaction furnace to produce a reaction effluent, where the reaction effluent comprises elemental sulfur, where the hydrogen sulfide and oxygen react to produce the elemental sulfur;
introducing the reaction effluent to a heating extension;
reducing the temperature of the reaction effluent in the heating extension to produce a cooled effluent stream;
introducing the cooled effluent to a sulfur condenser;
reducing the temperature of the cooled effluent in the sulfur condenser to produce a liquid sulfur stream and a cooled gases stream, where the liquid sulfur stream comprises the elemental sulfur;
introducing the cooled gases stream to the heating extension;
increasing a temperature of the cooled gases stream to produce a hot gases stream, where the heating extension is configured to capture heat from the reaction effluent and release the heat to the cooled gases stream;
introducing the hot gases stream to a first catalytic converter;
producing a first catalytic effluent in the first catalytic converter, where the first catalytic effluent comprises elemental sulfur, where the first catalytic converter comprises a catalyst;
introducing the first catalytic effluent to a first effluent condenser;
reducing the temperature of the first catalytic effluent in the first effluent condenser to produce a sulfur stream and a first non-condensed gases stream, where the sulfur stream comprises the elemental sulfur;
introducing the first non-condensed gases stream to the heating extension;
increasing a temperature of the first non-condensed gases stream to produce a first hot non-condensables stream;
introducing the first hot non-condensables stream to a second catalytic converter;
producing a second catalytic effluent in the second catalytic converter, where the second catalytic effluent comprises elemental sulfur, where the second catalytic converter comprises a catalyst;
introducing the second catalytic effluent to a second effluent condenser; and
reducing the temperature of the second catalytic effluent in the second effluent condenser to produce a sulfur effluent and a discharge stream, where the sulfur effluent comprises the elemental sulfur.

5. The method of claim 4 , further comprising the steps of;
introducing a pre-feed acid gas to an acid gas preheater; and
increasing the temperature of the pre-feed acid gas to produce the acid gas stream.

6. The method of claim 4 , further comprising the steps of:
introducing a pre-feed air to an air pre-heater; and
increasing the temperature of the pre-feed air to produce the air stream.

7. A method for heat integration in a sulfur recovery unit, the method comprising the steps of:
introducing an acid gas stream to a reaction furnace, where the acid gas stream comprises hydrogen sulfide;
introducing an air stream to the reaction furnace, where the air stream comprises oxygen;
reacting the acid gas stream and the air stream in the reaction furnace to produce a reaction effluent, where the reaction effluent comprises elemental sulfur, where the hydrogen sulfide and oxygen react to produce the elemental sulfur;
introducing the reaction effluent to a heating extension;
reducing the temperature of the reaction effluent in the heating extension to produce an effluent stream;
introducing the effluent stream to a waste heat boiler;
reducing the temperature of the reaction effluent in the waste heat boiler to produce a cooled effluent stream;
introducing the cooled effluent to a sulfur condenser;
reducing the temperature of the cooled effluent in the sulfur condenser to produce a liquid sulfur stream and a cooled gases stream, where the liquid sulfur stream comprises the elemental sulfur;
introducing

Assignees

• Saudi Arabian Oil Co

Inventors

• Alshahrani Yazeed Safar

Classifications

• C01B17/043

  Catalytic converters · CPC title

• C01B17/0417 Primary

  Combustion reactors · CPC title

• C01B17/0452

  Process control; Start-up or cooling-down procedures of the Claus process · CPC title

• Y02P20/129

  Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines · CPC title