Planographic printing plate precursor and plate-making method for planographic printing plate

Patent metadata

Field	Value
Publication number	US-10675903-B2
Application number	US-201816109774-A
Country	US
Kind code	B2
Filing date	Aug 23, 2018
Priority date	Feb 29, 2016
Publication date	Jun 9, 2020
Grant date	Jun 9, 2020

Abstract

Provided are a planographic printing plate precursor including: a support; and an image recording layer provided on the support, in which the image recording layer contains an infrared absorbing agent, a polymerization initiator, a polymerizable compound containing a hydrogen bonding group, and a hard polymer particle containing at least one group selected from the group consisting of a urethane group, a urea group, an imide group, an amide group, and a sulfonamide group on the surface of the hard polymer particle, and a number average primary particle diameter of the hard polymer particle is in a range of 0.01 to 1 μm; and a plate-making method for a planographic printing plate obtained by using the planographic printing plate precursor.

First claim

What is claimed is:

1. A planographic printing plate precursor comprising:
a support; and
an image recording layer provided on the support,
wherein the image recording layer contains an infrared absorbing agent, a polymerization initiator, a polymerizable compound containing a hydrogen bonding group, and a hard polymer particle containing at least one group selected from the group consisting of a urethane group, a urea group, an imide group, an amide group, and a sulfonamide group on the surface of the hard polymer particle,
a number average primary particle diameter of the hard polymer particle is in a range of 0.01 to 1 μm,
a coating ratio of the at least one group selected from the group consisting of the urethane group, the urea group, the imide group, the amide group, and the sulfonamide group, present on the surface of the hard polymer particle, is in a range of 1% to 99%, the coating ratio being measured by a TOF-SIMS method,
a polymer constituting the hard polymer particle comprises a polymer having any one or both of a monomer unit derived from a styrene compound and a monomer unit derived from a (meth)acrylonitrile compound, and
the at least one group selected from the group consisting of a urethane group, a urea group, an imide group, an amide group, and a sulfonamide group is a group that has been grafted by polymerizing at least one monomer selected from the group consisting of a urethane (meth)acrylate compound, a (meth)acrylate compound containing a urea group, a monomer containing an imide group, a (meth)acrylamide compound, and a monomer containing a sulfonamide group, in a presence of the polymer constituting the hard polymer particle.

2. The planographic printing plate precursor according to claim 1 ,
wherein the polymer comprised in the hard polymer particle further has a monomer unit derived from a poly(ethylene glycol) alkyl ether methacrylate compound.

3. The planographic printing plate precursor according to claim 1 , which is used for on-press development.

4. The planographic printing plate precursor according to claim 1 , wherein the at least one group selected from the group consisting of a urethane group, a urea group, an imide group, an amide group, and a sulfonamide group is a group that has been grafted by polymerizing at least one monomer selected from the group consisting of a urethane (meth)acrylate compound, a (meth)acrylate compound having a urea group, a maleimide compound, a (meth)acrylamide compound, and a (meth)acrylamide compound having a sulfonamide group, in a presence of the polymer constituting the hard polymer particle.

5. A plate-making method for a planographic printing plate comprising, in order:
a step of imagewise-exposing the planographic printing plate precursor according to claim 1 ; and
a step of supplying at least one of a printing ink or dampening water and removing an unexposed portion of an image recording layer in the planographic printing plate precursor.

6. A planographic printing plate precursor comprising:
a support; and
an image recording layer provided on the support,
wherein the image recording layer contains an infrared absorbing agent, a polymerization initiator, a polymerizable compound containing a hydrogen bonding group, and a hard polymer particle containing at least one group selected from the group consisting of a urethane group, a urea group, an imide group, an amide group, and a sulfonamide group on the surface of the hard polymer particle,
a number average primary particle diameter of the hard polymer particle is in a range of 0.01 to 1 μm,
a coating ratio of the at least one group selected from the group consisting of the urethane group, the urea group, the imide group, the amide group, and the sulfonamide group, present on the surface of the hard polymer particle, is in a range of 1% to 99%, the coating ratio being measured by a TOF-SIMS method,
a polymer constituting the hard polymer particle comprises a polymer having any one or both of a monomer unit derived from a styrene compound and a monomer unit derived from a (meth)acrylonitrile compound, and
the at least one group selected from the group consisting of a urethane group, a urea group, an imide group, an amide group, and a sulfonamide group is present at a side chain of a polymer present at the surface of the hard polymer particle.

Assignees

• Fujifilm Corp

Inventors

• AIZU Kohei
• Nakamura Ryo
• Idei Hiroaki
• Ochimizu Tomoki

Classifications

• B41M1/06

  Lithographic printing · CPC title

• G03F7/033 Primary

  the binders being polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers · CPC title

• G03F7/30

  Imagewise removal using liquid means · CPC title

• G03F7/3035

  from printing plates fixed on a cylinder or on a curved surface; from printing cylinders · CPC title

• B41N1/14 Primary

  Lithographic printing foils {(B41N1/003, B41N3/03 take precedence; compositions of the image-forming layer B41C1/10)} · CPC title