Power producing gas separation system and method

Patent metadata

Field	Value
Publication number	US-10673084-B2
Application number	US-201715802219-A
Country	US
Kind code	B2
Filing date	Nov 2, 2017
Priority date	Feb 25, 2015
Publication date	Jun 2, 2020
Grant date	Jun 2, 2020

Abstract

A power producing system adapted to be integrated with a flue gas generating assembly, the flue gas generating assembly including one or more of a fossil fueled installation, a fossil fueled facility, a fossil fueled device, a fossil fueled power plant, a boiler, a combustor, a furnace and a kiln in a cement factory, and the power producing system utilizing flue gas containing carbon dioxide and oxygen output by the flue gas generating assembly and comprising: a fuel cell comprising an anode section and a cathode section, wherein inlet oxidant gas to the cathode section of the fuel cell contains the flue gas output from the flue gas generating assembly; and a gas separation assembly receiving anode exhaust output from the anode section of the fuel cell and including a chiller assembly for cooling the anode exhaust to a predetermined temperature so as to liquefy carbon dioxide in the anode exhaust, wherein waste heat produced by the fuel cell is utilized to drive the chiller assembly.

First claim

What is claimed is:

1. A power producing system configured to utilize a flue gas output from a flue gas generating assembly, wherein the flue gas comprises carbon dioxide and oxygen and the power producing system comprises:
a fuel cell comprising an anode section and a cathode section, the cathode section of the fuel cell being configured to receive inlet oxidant gas that contains flue gas output from the flue gas generating assembly; and
a gas separation assembly configured to receive anode exhaust output from the anode section of the fuel cell and comprising:
a shift reactor configured to convert carbon monoxide in the anode exhaust to carbon dioxide,
a chiller assembly configured to cool the anode exhaust to a predetermined temperature so as to liquefy carbon dioxide in the anode exhaust; and
a gas separation device configured to receive the anode exhaust cooled by the chiller assembly and separate the liquefied carbon dioxide from residual fuel gas;

an oxidizer configured to receive residual fuel gas separated by the gas separation device, oxidize the residual fuel gas to heat the flue gas, and output heated flue gas directly to the cathode section of the fuel cell.

2. The power producing system of claim 1 , wherein:
the gas separation assembly further comprises a heat recovery assembly configured to recover waste heat from cathode exhaust output from the cathode section of the fuel cell, and
the heat recovery assembly and the chiller assembly are configured such that said waste heat recovered by the heat recovery assembly is utilized to drive the chiller assembly.

3. The power producing system of claim 1 , wherein the cathode section of the fuel cell is configured to receive inlet oxidant gas that consists of all or part of the flue gas output by the flue gas generating assembly.

4. The power producing system of claim 1 , wherein the cathode section of the fuel cell being further configured to receive inlet oxidant gas comprising supplementary air and flue gas output by the flue gas generating assembly.

5. The power producing system of claim 1 , wherein the chiller assembly comprises one or more absorption chillers.

6. The power producing system of claim 1 , wherein the gas separation assembly further comprises
a water removal assembly configured to separate water from the anode exhaust and output water-separated anode exhaust, wherein the chiller assembly is configured to receive the water-separated anode exhaust, and
a compressor configured to compress the water-separated anode exhaust output from the water removal assembly prior to the water-separated anode exhaust being conveyed to the chiller assembly.

7. The power producing system of claim 6 , wherein the shift reactor is configured to convert carbon monoxide in the anode exhaust to carbon dioxide prior to the anode exhaust being conveyed to the water removal assembly.

8. The power producing system of claim 1 , wherein the fuel cell is an internal reforming molten carbonate fuel cell.

9. A gas separation method for use in a power producing system utilizing a flue gas output from a flue gas generating assembly, wherein the flue gas comprises carbon dioxide and oxygen and the method comprises:
operating a fuel cell having an anode section and a cathode section, wherein, during operation of the fuel cell, the anode section of the fuel cell outputs anode exhaust;
receiving the anode exhaust in a gas separation assembly that comprises a shift reactor and a chiller assembly;
converting carbon monoxide in the anode exhaust to carbon dioxide using the shift reactor;
cooling the anode exhaust to a predetermined temperature in the chiller assembly so as to liquefy the carbon dioxide in the anode exhaust;
after cooling the anode exhaust in the chiller assembly, separating the liquefied carbon dioxide from residual fuel gas in a gas separation device; and
receiving the residual fuel gas at an oxidizer, using the oxidizer to oxidize the residual fuel gas and thereby heat the flue gas output from the flue gas generating assembly, and outputting the heated flue gas from the oxidizer directly to the cathode section of the fuel cell.

10. The gas separation method of claim 9 , further comprising:
recovering waste heat from cathode exhaust output from the cathode section of the fuel cell,
wherein the step of cooling the anode exhaust to the predetermined temperature in the chiller assembly is performed while utilizing the waste heat from the cathode exhaust to drive the chiller assembly.

11. The gas separation method of claim 9 , wherein the chiller assembly comprises one or more absorption chillers.

12. The gas separation method of claim 9 , further comprising
separating water from the anode exhaust prior to cooling the anode exhaust to the predetermined temperature in the chiller assembly, and
compressing the water-separated anode exhaust prior to cooling the anode exhaust to the predetermined temperature in the chiller assembly.

13. The gas separation method of claim 9 , wherein the cathode section of the fuel cell is configured to receive inlet oxidant gas that exclusively consists of all or part of the flue gas output by the flue gas generating assembly.

14. The gas separation method of claim 9 , wherein the cathode section of the fuel cell being further configured to receive inlet oxidant gas comprising supplementary air and flue gas output by the flue gas generating assembly.

15. The gas separation method of claim 12 , wherein converting carbon monoxide in the anode exhaust to carbon dioxide using the shift reactor is performed prior to separating water from the anode exhaust.

16. A gas separation method for use in a power producing system utilizing a flue gas output from a flue gas generating assembly, wherein the flue gas comprises carbon dioxide and oxygen and the method comprises:
operating a fuel cell having an anode section and a cathode section, wherein, during operation of the fuel cell, the cathode section of the fuel cell receives inlet oxidant gas comprising supplementary air and flue gas output by the flue gas generating assembly, and the anode section of the fuel cell outputs anode exhaust;
receiving the anode exhaust in a gas separation assembly that comprises a chiller assembly;
cooling the anode exhaust to a predetermined temperature in the chiller assembly so as to liquefy the carbon dioxide in the anode exhaust
after cooling the anode exhaust in the chiller assembly, separating the liquefied carbon dioxide from residual fuel gas in a gas separation device; and
receiving the residual fuel gas at an oxidizer, using the oxidizer to oxidize the residual fuel gas and thereby heat the flue gas output from the flue gas generating assembly, and outputting the heated flue gas from the oxidizer directly to the cathode section of the fuel cell.

17. The gas separation method of claim 16 , further comprising:
recovering waste heat from cathode exhaust output from the cathode section of the fuel cell,
wherein the step of cooling the anode exhaust to the predetermined temperature in the chiller assembly is performed while utilizing the waste heat from the cathode exhaust to drive the chiller assembly.

Assignees

• Fuelcell Energy Inc

Inventors

• Ghezel-Ayagh Hossein

Classifications

• H01M8/04089

  of gaseous reactants · CPC title

• Y02P90/40

  Fuel cell technologies in production processes · CPC title

• H01M8/04022

  Heating by combustion · CPC title

• H01M8/04014 Primary

  Heat exchange using gaseous fluids; Heat exchange by combustion of reactants · CPC title

• H01M8/0675

  Removal of sulfur · CPC title